Two- and three-dimensional Zn(ii) coordination polymers constructed from mixed ligand systems: interpenetration, structural transformation and sensing behavior

CrystEngComm ◽  
2016 ◽  
Vol 18 (23) ◽  
pp. 4349-4358 ◽  
Author(s):  
Min Kyung Park ◽  
Kwang Soo Lim ◽  
Ji Hey Park ◽  
Jeong Hwa Song ◽  
Dong Won Kang ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Mixed Ligand

Three-Dimensional Mixed-Ligand Coordination Polymers with Ferromagnetically Coupled Cyclic Tetranuclear Copper(II) Units Bonded by Weak Interactions

2011 ◽  
Vol 11 (10) ◽  
pp. 4344-4352 ◽  
Author(s):  
Susana Balboa ◽  
Joaquín Borrás ◽  
Pilar Brandi ◽  
Rosa Carballo ◽  
Alfonso Castiñeiras ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Weak Interactions ◽  
Three Dimensional ◽  
Mixed Ligand ◽  
Ligand Coordination

scholarly journals Two mixed-ligand coordination polymers based on 2,5-thiophenedicarboxylic acid and flexible N-donor ligands: the protective effect on periodontitis via reducing the release of IL-1β and TNF-α

2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang
Keyword(s):  
Coordination Polymers ◽  
Gingival Crevicular Fluid ◽  
Mixed Ligand ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Functional Studies ◽  
Tnf Α ◽  
Mucosal Cells ◽  
Ligand Coordination ◽  
Crevicular Fluid

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.

Humidity-Induced Structural Transformation in Pseudopolymorph Coordination Polymers

2021 ◽  
Author(s):  
Behrouz Notash ◽  
Mona Farhadi Rodbari ◽  
Gianpiero Gallo ◽  
Robert Dinnebier
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers
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