Intermetal Oxygen Atom Transfer Reactions of Titanium Porphyrins:  Complete vs Incomplete Atom Transfer. X-ray Structure of (μ-Oxo)bis[(meso-tetra-p-tolylporphyrinato)titanium(III)]

1996 ◽  
Vol 35 (26) ◽  
pp. 7601-7607 ◽  
Author(s):  
J. Alan Hays ◽  
Catherine L. Day ◽  
Victor G. Young ◽  
L. Keith Woo
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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