Hydroxide ion as a reducing agent for cations containing three ruthenium atoms in nonintegral oxidation states

Joseph E. Earley; Terence Fealey

doi:10.1021/ic50120a016

Hydroxide ion as a reducing agent for cations containing three ruthenium atoms in nonintegral oxidation states

Inorganic Chemistry ◽

10.1021/ic50120a016 ◽

1973 ◽

Vol 12 (2) ◽

pp. 323-327 ◽

Cited By ~ 40

Author(s):

Joseph E. Earley ◽

Terence Fealey

Keyword(s):

Reducing Agent ◽

Oxidation States ◽

Hydroxide Ion

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Hydroxide ion as a reducing agent for mixed-valence ruthenium trimers

Journal of the Chemical Society D Chemical Communications ◽

10.1039/c2971000331a ◽

1971 ◽

pp. 331a ◽

Cited By ~ 5

Author(s):

Joseph. E. Earley ◽

Terence Fealey

Keyword(s):

Mixed Valence ◽

Reducing Agent ◽

Hydroxide Ion

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OXIDATION STATES OF MANGANESE IN FUSED ALKALI NITRATES

Canadian Journal of Chemistry ◽

10.1139/v63-013 ◽

1963 ◽

Vol 41 (1) ◽

pp. 108-111 ◽

Cited By ~ 14

Author(s):

Ruth M. Bennett ◽

Owen G. Holmes

Keyword(s):

Aqueous Solution ◽

Oxidation States ◽

Great Similarity ◽

Hydroxide Ion ◽

Alkaline Aqueous Solution

When dissolved in fused alkali nitrate, manganese (II) is oxidized to MnO2. In the same solvent MnO4− decomposes to MnO2. Peroxide ion arrests the decomposition at MnO42−, while the presence of hydroxide ion results in the formation of MnO43−. The spectra of MnO42− and MnO43− in molten nitrate show great similarity to their spectra in alkaline aqueous solution.

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Hydroxide ion: an effective one-electron reducing agent?

Accounts of Chemical Research ◽

10.1021/ar00156a006 ◽

1988 ◽

Vol 21 (12) ◽

pp. 469-476 ◽

Cited By ~ 102

Author(s):

Donald T. Sawyer ◽

Julian L. Roberts

Keyword(s):

Reducing Agent ◽

Hydroxide Ion

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Reaction of hydroxide ion with manganese(III) tetramesitylporphyrin and the oxidation states of manganese tetramesitylporphyrins

Inorganic Chemistry ◽

10.1021/ic00332a028 ◽

1990 ◽

Vol 29 (7) ◽

pp. 1422-1427 ◽

Cited By ~ 35

Author(s):

Ramesh D. Arasasingham ◽

Thomas C. Bruice

Keyword(s):

Oxidation States ◽

Hydroxide Ion

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ChemInform Abstract: Hydroxide Ion: An Effective One-Electron Reducing Agent?

ChemInform ◽

10.1002/chin.198914363 ◽

1989 ◽

Vol 20 (14) ◽

Author(s):

D. T. SAWYER ◽

J. L. JUN. ROBERTS

Keyword(s):

Reducing Agent ◽

Hydroxide Ion

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MicroEXAFS study into the oxidation states of copper coloured Hispano-Moresque lustre decorations

Journal de Physique IV (Proceedings) ◽

10.1051/jp4:20030136 ◽

2003 ◽

Vol 104 ◽

pp. 519-522 ◽

Cited By ~ 8

Author(s):

A. D. Smith ◽

T. Pradell ◽

J. Molera ◽

M. Vendrell ◽

M. A. Marcus ◽

...

Keyword(s):

Oxidation States

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Tensio-gravimetric determination of the activity of methanol in the sodium methoxide/methanol system, and the solvation of the aqueous hydroxide ion and the methanolic methoxide ion

Journal of Biochemical Toxicology ◽

10.1002/jbt.2570150404 ◽

1965 ◽

Vol 15 (4) ◽

pp. 179-182

Author(s):

G. F. Freeguard ◽

R. B. Moodie ◽

D. J. G. Smith

Keyword(s):

Sodium Methoxide ◽

Hydroxide Ion ◽

Gravimetric Determination ◽

Methoxide Ion ◽

Methanol System

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Carbon Monoxide Related Reductions

INEOS OPEN ◽

10.32931/io2017r ◽

2020 ◽

Vol 3 ◽

Author(s):

O. I. Afanasyev ◽

◽

D. Chusov ◽

Keyword(s):

Organic Chemistry ◽

Carbon Monoxide ◽

Reducing Agent ◽

Current Development ◽

Efficient Route ◽

Development Prospects

Carbon monoxide is a unique reducing agent that is only gaining popularity in organic chemistry. This review highlights the main approaches to the application of CO as a reducing agent, summarizes and critically analyzes the key trends in this field, and describes the current development prospects. Potentially the most selective and efficient route for the realization of these processes is demonstrated.

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