Hydroxide ion: an effective one-electron reducing agent?

1988 ◽  
Vol 21 (12) ◽  
pp. 469-476 ◽  
Author(s):  
Donald T. Sawyer ◽  
Julian L. Roberts
Keyword(s):  
Reducing Agent ◽  
Hydroxide Ion

ChemInform Abstract: Hydroxide Ion: An Effective One-Electron Reducing Agent?

ChemInform ◽  
1989 ◽  
Vol 20 (14) ◽  
Author(s):  
D. T. SAWYER ◽  
J. L. JUN. ROBERTS
Keyword(s):  
Reducing Agent ◽  
Hydroxide Ion

Carbon Monoxide Related Reductions

INEOS OPEN ◽  
2020 ◽  
Vol 3 ◽  
Author(s):  
O. I. Afanasyev ◽  
◽  
D. Chusov ◽  
Keyword(s):  
Organic Chemistry ◽  
Carbon Monoxide ◽  
Reducing Agent ◽  
Current Development ◽  
Efficient Route ◽  
Development Prospects

Carbon monoxide is a unique reducing agent that is only gaining popularity in organic chemistry. This review highlights the main approaches to the application of CO as a reducing agent, summarizes and critically analyzes the key trends in this field, and describes the current development prospects. Potentially the most selective and efficient route for the realization of these processes is demonstrated.

OESTRADIOL, A REDUCING AGENT FOR ANDROGENS IN LIVERTISSUE

1967 ◽  
Vol 56 (1_Suppl) ◽  
pp. S62
Author(s):  
M. Wenzel ◽  
K. Pollow
Keyword(s):  
Reducing Agent

Photochemical and Electrochemical Reduction of Carbon Dioxide Catalyzed by a Polyoxometalate-Organic Photosensitizer Complex

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Voltammetry ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Mass Spectroscopy ◽  
Photochemical Reactions ◽  
Reducing Agent ◽  
Covalent Attachment ◽  
Hybrid Complex ◽  
Open Face

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>

Rheological Behaviour of Diutan Gum and Its Effects as a Drag Reducing Agent

2019 ◽  
Author(s):  
Walber Ronconi dos Santos ◽  
Edson Soares ◽  
Renato Siqueira
Keyword(s):  
Rheological Behaviour ◽  
Reducing Agent
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