OXIDATION STATES OF MANGANESE IN FUSED ALKALI NITRATES

Ruth M. Bennett; Owen G. Holmes

doi:10.1139/v63-013

OXIDATION STATES OF MANGANESE IN FUSED ALKALI NITRATES

Canadian Journal of Chemistry ◽

10.1139/v63-013 ◽

1963 ◽

Vol 41 (1) ◽

pp. 108-111 ◽

Cited By ~ 14

Author(s):

Ruth M. Bennett ◽

Owen G. Holmes

Keyword(s):

Aqueous Solution ◽

Oxidation States ◽

Great Similarity ◽

Hydroxide Ion ◽

Alkaline Aqueous Solution

When dissolved in fused alkali nitrate, manganese (II) is oxidized to MnO2. In the same solvent MnO4− decomposes to MnO2. Peroxide ion arrests the decomposition at MnO42−, while the presence of hydroxide ion results in the formation of MnO43−. The spectra of MnO42− and MnO43− in molten nitrate show great similarity to their spectra in alkaline aqueous solution.

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Oxidation States of Manganese Methyl Phæophorbide a in Aqueous Solution

Nature ◽

10.1038/202343a0 ◽

1964 ◽

Vol 202 (4930) ◽

pp. 343-345 ◽

Cited By ~ 15

Author(s):

PAUL A. LOACH ◽

MELVIN CALVIN

Keyword(s):

Aqueous Solution ◽

Oxidation States

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Analysis of dissolution kinetics of narrow polydispersity poly(4-hydroxystyrene) in alkaline aqueous solution using machine learning

Japanese Journal of Applied Physics ◽

10.35848/1347-4065/ac016d ◽

2021 ◽

Author(s):

Naoki Tanaka ◽

Kyoko Watanabe ◽

Kyoko Matsuoka ◽

Kazuki Azumagawa ◽

Takahiro KOZAWA ◽

...

Keyword(s):

Machine Learning ◽

Aqueous Solution ◽

Dissolution Kinetics ◽

Alkaline Aqueous Solution ◽

Kinetics Of

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Silent Discharge Reactions in Aqueous Solutions. VII. Alkaline Aqueous Solution of Potassium Ferricyanide in Atmospheres of Helium and Argon

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.40.2507 ◽

1967 ◽

Vol 40 (11) ◽

pp. 2507-2511 ◽

Cited By ~ 4

Author(s):

Akira Yokohata ◽

Satoru Tsuda

Keyword(s):

Aqueous Solution ◽

Aqueous Solutions ◽

Potassium Ferricyanide ◽

Silent Discharge ◽

Alkaline Aqueous Solution

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Transition effect of under- and over-potentially deposited hydrogen and negative resistance at a poly-Rh/alkaline aqueous solution interface

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2019.11.027 ◽

2020 ◽

Vol 45 (3) ◽

pp. 1429-1434

Author(s):

Jinyoung Chun ◽

Jang H. Chun

Keyword(s):

Aqueous Solution ◽

Negative Resistance ◽

Transition Effect ◽

Solution Interface ◽

Alkaline Aqueous Solution

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Determination of the Frumkin and Temkin Adsorption Isotherms of Hydrogen at Nickel/Acidic and Alkaline Aqueous Solution Interfaces Using the Phase-Shift Method and Correlation Constants

Journal of the Korean Electrochemical Society ◽

10.5229/jkes.2012.15.1.054 ◽

2012 ◽

Vol 15 (1) ◽

pp. 54-66 ◽

Cited By ~ 1

Author(s):

Jang-H. Chun

Keyword(s):

Aqueous Solution ◽

Phase Shift ◽

Adsorption Isotherms ◽

Shift Method ◽

Alkaline Aqueous Solution ◽

Phase Shift Method

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Ruthenium catalysed oxidation of cyclohexanol

Australian Journal of Chemistry ◽

10.1071/ch9821245 ◽

1982 ◽

Vol 35 (6) ◽

pp. 1245 ◽

Cited By ~ 6

Author(s):

P Becker ◽

JK Beattie

Keyword(s):

Aqueous Solution ◽

Isotope Effect ◽

Phosphate Buffer ◽

Hydride Transfer ◽

Deuterium Isotope Effect ◽

Rate Law ◽

Alkaline Aqueous Solution ◽

Catalysed Oxidation

The oxidation of cyclohexanol by ferricyanide in alkaline aqueous solution is catalysed by micromolar concentrations of K3RuCl6. The rate law at 25.0�C in pH 11.9 phosphate buffer containing 0.50 M NaCl is -d[FeIII]/dt = [Ru](2klk2[alcohol][FeIII])/(2kl[alcohol] + k2[FeIII]) with kl 12 � 2 mol-1 1. s-1 and k2 (2.5 � 0.2) × 102 mol-1 1. s-1. A deuterium isotope effect of about 4 is observed when (D12)cyclohexanol is used. A mechanism consistent with these observations involves reduction of the RuIII catalyst by hydride transfer from the alcohol followed by reoxidation by ferricyanide to the original RulIII state.

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Synthesis, crystal structure and investigation of mononuclear copper(II) and zinc(II) complexes of a new carboxylate rich tripodal ligand and their interaction with carbohydrates in alkaline aqueous solution

Journal of Inorganic Biochemistry ◽

10.1016/j.jinorgbio.2015.04.012 ◽

2015 ◽

Vol 149 ◽

pp. 25-38 ◽

Cited By ~ 8

Author(s):

Christopher D. Stewart ◽

Mayra Pedraza ◽

Hadi Arman ◽

Hua-Jun Fan ◽

Eduardo Luiz Schilling ◽

...

Keyword(s):

Crystal Structure ◽

Aqueous Solution ◽

Tripodal Ligand ◽

Alkaline Aqueous Solution

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The anation of the aquahydroxotetraamminecobalt(III) ion by thiocyanate in alkaline aqueous solution

Journal of Inorganic and Nuclear Chemistry ◽

10.1016/0022-1902(76)80208-4 ◽

1976 ◽

Vol 38 (12) ◽

pp. 2265-2269 ◽

Cited By ~ 7

Author(s):

E.G.A.M. Bohte ◽

S. Balt

Keyword(s):

Aqueous Solution ◽

Alkaline Aqueous Solution

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Decomposition kinetics of n-chloro-alanines in alkaline aqueous solution

Journal of Clinical Toxicology ◽

10.4172/2161-0495.c1.019 ◽

2016 ◽

Vol 06 (05) ◽

Author(s):

Maria Szabo

Keyword(s):

Aqueous Solution ◽

Decomposition Kinetics ◽

Alkaline Aqueous Solution ◽

Kinetics Of

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Oxidation States of Manganese Hematoporphyrin IX in Aqueous Solution*

Biochemistry ◽

10.1021/bi00902a032 ◽

1963 ◽

Vol 2 (2) ◽

pp. 361-371 ◽

Cited By ~ 88

Author(s):

Paul A. Loach ◽

Melvin Calvin

Keyword(s):

Aqueous Solution ◽

Oxidation States ◽

Hematoporphyrin Ix

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