Electronic and infrared spectral study of chromium (III) derivatives of the type [Cr(NCS)4.(ligand)2]-

1967 ◽  
Vol 6 (9) ◽  
pp. 1625-1631 ◽  
Author(s):  
Martin Arthur Bennett ◽  
Robin J. H. Clark ◽  
Arthur D. J. Goodwin
1976 ◽  
Vol 32 (3) ◽  
pp. 553-557 ◽  
Author(s):  
M.J.M Campbell ◽  
R. Grzeskowiak ◽  
R. Thomas ◽  
M. Goldstein

1971 ◽  
Vol 36 (21) ◽  
pp. 3091-3095 ◽  
Author(s):  
Manfred G. Reinecke ◽  
John F. Sebastian ◽  
Harry W. Johnson ◽  
Chongsuh Pyun

2011 ◽  
Vol 8 (s1) ◽  
pp. S271-S281
Author(s):  
B. Venkateswara Rao ◽  
D. M. Puri

Polynuclear copper(II) derivatives of 1-hydroxyethylidenediphosphonic acid (HEDP), 1-aminoethylidenediphosphonic acid (AEDP, H4L),α-aminobenzylidene diphosphonic acid (ABDP, H4L), 1-amino-2-carboxyethane- 1,1-diphosphonic acid (ACEDP, H5L), 1,3 diaminopropane-1,1,3,3-tetra-phosphonic acid (DAPTP, H8L), Ethylenediamine-N,N'-bis (dimethyl-methylenephosphonic) acid (EDBDMPO, H4L),o-phenylene-diamine-N,N'-bis (dimethylmethylenephosphonic) acid (PDBDMPO, H4L), diethylene triamine –N,N,N',N',N"N-penta (methylene phosphonic) acid (DETAPMPO, H10L) and diethylene triamine –N,N"-bis (dimethyl methylene phosphonic) acid (DETBDMPO, H4L) have been prepared in aqueous medium. The general formula of derivatives from elemental analysis was found to be Cu2L.XH2O (in case of AEDP, ABDP, EDBDMPO, PDBDMPO, DETBDMPO), Cu5L2.XH2O (in case of ACEDP) Cu4L.XH2O, Cu2H4L. XH2O (in case of DAPTP) and Cu5L.XH2O (in case of DETAPMPO). The electronic spectra have shown them to be six coordinated with slight distortion from octahedral geometry. Antiferromagnetism was inferred from magnetic moment data. Infrared spectral studies were carried out to determine coordination sites. EPR (Electron Paramagnetic Resonance) spectra that supports the presence of tetragonal distortion and antiferromagnetic behaviour, have also been studied.


2006 ◽  
Vol 86 (3) ◽  
pp. 605-608 ◽  
Author(s):  
Reema A. Porob ◽  
Sitara Z. Khan ◽  
S. C. Mojumdar ◽  
V. M. S. Verenkar

1997 ◽  
Vol 30 (3) ◽  
pp. 527-534
Author(s):  
B. I. El-Eswed ◽  
M. B. Zughul ◽  
G. A.W. Derwish

2011 ◽  
Vol 17 (3) ◽  
pp. 227-235
Author(s):  
Beata Jasiewicz ◽  
Marzena Wojciechowska-Nowak ◽  
Władysław Boczoń ◽  
Elzbieta Wyrzykiewicz

1974 ◽  
Vol 3 (3) ◽  
pp. 161-174 ◽  
Author(s):  
Tien-chung Godfrey Chang ◽  
Donald E. Irish

1970 ◽  
Vol 12 (1) ◽  
pp. 67-70
Author(s):  
K. V. Nel'son ◽  
I. V. Ikonitskii ◽  
V. A. Ryzhkov

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