NMR spectral study of some organometallic derivatives of indoles

1971 ◽  
Vol 36 (21) ◽  
pp. 3091-3095 ◽  
Author(s):  
Manfred G. Reinecke ◽  
John F. Sebastian ◽  
Harry W. Johnson ◽  
Chongsuh Pyun
1967 ◽  
Vol 6 (9) ◽  
pp. 1625-1631 ◽  
Author(s):  
Martin Arthur Bennett ◽  
Robin J. H. Clark ◽  
Arthur D. J. Goodwin

2011 ◽  
Vol 17 (3) ◽  
pp. 227-235
Author(s):  
Beata Jasiewicz ◽  
Marzena Wojciechowska-Nowak ◽  
Władysław Boczoń ◽  
Elzbieta Wyrzykiewicz

1977 ◽  
Vol 17 (3) ◽  
pp. 375-379 ◽  
Author(s):  
G. N. Dolenko ◽  
L. I. Nasonova ◽  
L. N. Mazalov ◽  
G. G. Furin ◽  
G. G. Yakobson

1976 ◽  
Vol 3 (4) ◽  
pp. 155-160 ◽  
Author(s):  
F. Compernolle ◽  
N. Blanckaert ◽  
K. P. M. Heirwegh

1979 ◽  
Vol 57 (15) ◽  
pp. 1949-1957 ◽  
Author(s):  
J. F. Bagli ◽  
T. Bogri ◽  
B. Palameta ◽  
M. St-Jacques

The 13C nmr spectra of several isomeric monosubstituted derivatives of 2-methoxytropone together with some dibromo derivatives have been obtained and analysed. Substituent parameters were defined and shown to exhibit additivity. Differences with corresponding parameters for monosubstituted benzene analogs suggest proximity interactions between the 3-substituents and the 2-OCH3 group as well as between 7-substituents and the adjacent carbonyl group. The data indicates that the OCH3 group is a convenient probe to investigate the orientation of mesomeric electronic charge transfer to the various carbons of the tropone seven-membered ring. Finally, it is demonstrated that 13C nmr is quite useful to distinguish between the various substituted 2-methoxytropones.


2008 ◽  
Vol 5 (s2) ◽  
pp. 1154-1158
Author(s):  
Pradeep Yadav ◽  
Y. C. Joshi

Reaction of [1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(1-piperazinyl)-quinolone-3-carboxylic acid (norfloxacin) with thiazole / benzothiazole diazonium chloride to get new piperazine substituted norfloxacin derivative. These norfloxacin derivatives were further condensed with variousβ-diketone to get novel acid derivatives of 1-Ethyl-6-fluoro-4-oxo-7- [4 (thiazol-2-yldiazenyl)-piperzin-1-yl]-1,4-dihydro-quinoline-3-carboxylic acid (6a-e) and 7-(4-(benzo[d]thiazol-2-yldiazenyl)piperazin-1-yl)-1-ethyl-6-fluoro-4-oxo-1, 4-dihydroquinoline-3-carboxylic acid (6 f-j). Structures of these compounds were established on the basis of spectral studies viz. IR,1H NMRetc.


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