Spontaneous Resolution of a Mixed-Ligand Nickel(II) Coordination Polymer with Achiral Precursors

2012 ◽  
Vol 51 (18) ◽  
pp. 9577-9579 ◽  
Author(s):  
Kamal Kumar Bisht ◽  
Eringathodi Suresh
Keyword(s):  
Coordination Polymer ◽  
Mixed Ligand ◽  
Spontaneous Resolution

Synthesis, characterization and fluorescence properties of mixed-ligand cobalt(II), copper(II), zinc(II) and cadmium(II) coordination polymer complexes involving 4,4’-bipyridine and 2,5-pyridinedicarboxylic acid

2021 ◽  
Vol 25 (7) ◽  
pp. 147-156
Author(s):  
Ajeet Kumar Maurya ◽  
Ashish Kumar Srivastava ◽  
Krishna Srivastava ◽  
Jagdish Prasad
Keyword(s):  
Coordination Polymer ◽  
Thermal Analyses ◽  
Mixed Ligand ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Polymer Complexes ◽  
Pyridinedicarboxylic Acid ◽  
Elemental Analyses ◽  
Ligand Coordination ◽  
Ft Ir

Four mixed-ligand coordination polymer complexes of cobalt(II), copper(II), zinc(II), and cadmium(II) were synthesized by solvothermal method in 1:1:1 metal: 4,4’-bipy: 2,5-pdc molar ratio using 2,5-pyridinedicarboxylic acid (2,5-pdc) and 4,4’-bipyridine (4,4’-bipy). These complexes are viz; 1. [Co2(4,4'-bipy)(2,5-pdc)2(H2O)4]n 2. [Cu2(4,4'-bipy) (2,5-pdc)2]n 3. [Zn2(4,4'-bipy)(2,5-pdc)2(H2O)4]n and 4. [Cd3(4,4'-bipy)(2,5-pdc)2(OOCCH3)2(H2O)4]n.. All these complexes (1-4) have been characterized by elemental analyses (C,H,N), FT-IR-spectra, thermal analyses (TGA/DTA/DTG), fluorescence spectra and powder X-ray diffraction (PXRD) analyses to arrive at conclusion regarding their geometrical structure.

Spontaneous chiral resolution of a rare 3D self-penetration coordination polymer for sensitive aqueous-phase detection of picric acid

2015 ◽  
Vol 44 (42) ◽  
pp. 18386-18394 ◽  
Author(s):  
Bai-Qiao Song ◽  
Chao Qin ◽  
Yu-Teng Zhang ◽  
Xue-Song Wu ◽  
Liu Yang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Aqueous Phase ◽  
Picric Acid ◽  
Spontaneous Resolution ◽  
Chiral Resolution ◽  
Sensitive Detection ◽  
Phase Detection

A chiral, fluorescent and self-penetration coordination polymer was synthesized through spontaneous resolution, which showed sensitive detection of picric acid in the aqueous phase.

Spontaneous resolution of a coordination polymer containing stereogenic five-coordinate Zn(ii) centers and achiral ligands with axially chiral conformation

CrystEngComm ◽  
2012 ◽  
Vol 14 (19) ◽  
pp. 6241 ◽  
Author(s):  
Sheng-Run Zheng ◽  
Song-Liang Cai ◽  
Jing-Bo Tan ◽  
Jun Fan ◽  
Wei-Guang Zhang
Keyword(s):  
Coordination Polymer ◽  
Spontaneous Resolution ◽  
Axially Chiral
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