Spontaneous resolution of a coordination polymer containing stereogenic five-coordinate Zn(ii) centers and achiral ligands with axially chiral conformation

CrystEngComm ◽  
2012 ◽  
Vol 14 (19) ◽  
pp. 6241 ◽  
Author(s):  
Sheng-Run Zheng ◽  
Song-Liang Cai ◽  
Jing-Bo Tan ◽  
Jun Fan ◽  
Wei-Guang Zhang
Keyword(s):  
Coordination Polymer ◽  
Spontaneous Resolution ◽  
Axially Chiral

Spontaneous chiral resolution of a rare 3D self-penetration coordination polymer for sensitive aqueous-phase detection of picric acid

2015 ◽  
Vol 44 (42) ◽  
pp. 18386-18394 ◽  
Author(s):  
Bai-Qiao Song ◽  
Chao Qin ◽  
Yu-Teng Zhang ◽  
Xue-Song Wu ◽  
Liu Yang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Aqueous Phase ◽  
Picric Acid ◽  
Spontaneous Resolution ◽  
Chiral Resolution ◽  
Sensitive Detection ◽  
Phase Detection

A chiral, fluorescent and self-penetration coordination polymer was synthesized through spontaneous resolution, which showed sensitive detection of picric acid in the aqueous phase.

scholarly journals A structurally versatile coordination polymer: demonstrating spontaneous resolution, conformational polymorphism and gel formation

CrystEngComm ◽  
2013 ◽  
Vol 15 (33) ◽  
pp. 6602 ◽  
Author(s):  
Savarimuthu Philip Anthony ◽  
Longsheng Wang ◽  
Sunil Varughese ◽  
Sylvia M. Draper
Keyword(s):  
Coordination Polymer ◽  
Spontaneous Resolution ◽  
Gel Formation ◽  
Conformational Polymorphism

scholarly journals Crystal structure of catena-poly[[diiodidomercury(II)]-μ-2,2′-dithiobis(pyridine N-oxide)-κ2 O:O′]

2018 ◽  
Vol 74 (4) ◽  
pp. 433-435
Author(s):  
Rüdiger W. Seidel ◽  
Iris M. Oppel
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Coordination Sphere ◽  
Title Compound ◽  
Aromatic Rings ◽  
One Dimensional ◽  
Axially Chiral

The title compound, [HgI2(C10H8N2O2S2)] n , a one-dimensional coordination polymer with HgI2 units and 2,2′-dithiobis(pyridine N-oxide) spacer ligands in an alternating fashion, forms helical chains running along the b axis in the crystal. Within a single coordination polymer strand, the axially chiral 2,2′-dithiobis(pyridine N-oxide) ligands are homochiral, but the enantiomeric conformation is present in adjacent strands. Within a coordination polymer strand, the iodido ligands point towards the centroids of the aromatic rings of the pyridine N-oxide moieties in the coordination sphere of HgII. Moreover, intra-strand C—H...O and C—H...I interactions, and inter-strand short S...I and S...O contacts are observed.

A Zn-oxalate helix linked by a water helix: spontaneous chiral resolution of a Zn helical coordination polymer

2015 ◽  
Vol 39 (3) ◽  
pp. 2075-2080 ◽  
Author(s):  
Hong-Xin Mei ◽  
Ting Zhang ◽  
Dan-Feng Wang ◽  
Rong-Bin Huang ◽  
Lan-Sun Zheng
Keyword(s):  
Coordination Polymer ◽  
Spontaneous Resolution ◽  
Chiral Resolution

Two enantiomers of a Zn helical coordination polymer have been obtained from spontaneous resolution. In this compound, homochiral Zn-oxalate helices are linked by water helices comprising coordinated and guest water.

Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

CrystEngComm ◽  
2012 ◽  
Vol 14 (1) ◽  
pp. 63-66 ◽  
Author(s):  
Xin Tan ◽  
Jixian Zhan ◽  
Jianyong Zhang ◽  
Long Jiang ◽  
Mei Pan ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Spontaneous Resolution ◽  
Axially Chiral ◽  
Metal Organic ◽  
Dicarboxylate Ligand
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