scholarly journals Tetranuclear [Rh4(μ-PyS2)2(diolefin)4] Complexes as Building Blocks for New Inorganic Architectures:  Synthesis of Coordination Polymers and Heteropolynuclear Complexes with Electrophilic d8and d10Metal Fragments

2004 ◽  
Vol 43 (4) ◽  
pp. 1558-1567 ◽  
Author(s):  
Miguel A. Casado ◽  
Jesús J. Pérez-Torrente ◽  
Miguel A. Ciriano ◽  
Fernando J. Lahoz ◽  
Luis A. Oro
Keyword(s):  
Coordination Polymers ◽  
Building Blocks ◽  
Heteropolynuclear Complexes

Spin Crossover in a Series of Non-Hofmann-Type Fe(II) Coordination Polymers Based on [Hg(SeCN)3]− or [Hg(SeCN)4]2– Building Blocks

2021 ◽  
Author(s):  
Tong Cao ◽  
Francisco Javier Valverde-Muñoz ◽  
Xiaoyi Duan ◽  
Mingjian Zhang ◽  
Ping Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Spin Crossover ◽  
Building Blocks

A threefold interpenetrated two-dimensional zinc(II) supramolecular architecture based on 3-nitrobenzoic acid and 4,4′-bipyridine

2016 ◽  
Vol 72 (2) ◽  
pp. 128-132 ◽  
Author(s):  
Long Tang ◽  
Ji-Jiang Wang ◽  
Feng Fu ◽  
Sheng-Wen Wang ◽  
Qi-Rui Liu
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Critical Factor ◽  
Building Blocks ◽  
Zigzag Chain ◽  
Great Success ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Hydrothermal Conditions ◽  
Nitrobenzoic Acid

With regard to crystal engineering, building block or modular assembly methodologies have shown great success in the design and construction of metal–organic coordination polymers. The critical factor for the construction of coordination polymers is the rational choice of the organic building blocks and the metal centre. The reaction of Zn(OAc)2·2H2O (OAc is acetate) with 3-nitrobenzoic acid (HNBA) and 4,4′-bipyridine (4,4′-bipy) under hydrothermal conditions produced a two-dimensional zinc(II) supramolecular architecture,catena-poly[[bis(3-nitrobenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′], [Zn(C7H4NO4)2(C10H8N2)]nor [Zn(NBA)2(4,4′-bipy)]n, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction analysis. The ZnIIions are connected by the 4,4′-bipy ligands to form a one-dimensional zigzag chain and the chains are decorated with anionic NBA ligands which interact further through aromatic π–π stacking interactions, expanding the structure into a threefold interpenetrated two-dimensional supramolecular architecture. The solid-state fluorescence analysis indicates a slight blue shift compared with pure 4,4′-bipyridine and HNBA.

Coordination polymers based on building blocks of dimethyltin(IV) Chloride iso-thiocyanate and dimethyltin(IV) di-iso-thiocyanate with pyrazine-2-carboxylate and 4, 4′-bipyridine

2011 ◽  
Vol 22 (6) ◽  
pp. 699-706 ◽  
Author(s):  
Ezzatollah Najafi ◽  
Mostafa M. Amini ◽  
Omid Sadeghi ◽  
Hamid Reza Khavasi ◽  
Seik Weng Ng
Keyword(s):  
Coordination Polymers ◽  
Building Blocks

Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

CrystEngComm ◽  
2014 ◽  
Vol 16 (35) ◽  
pp. 8224-8231 ◽  
Author(s):  
J. Troyano ◽  
J. Perles ◽  
P. Amo-Ochoa ◽  
J. I. Martínez ◽  
F. Zamora ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Direct Synthesis ◽  
Three Dimensional ◽  
Building Blocks ◽  
Recrystallization Process

Three-dimensional [CuX(TAA)]n (X = Br (1), I (2)) and bi-dimensional [AgX(TAA)]n (X = Cl (3), Br (4)) coordination polymers have been isolated by the direct synthesis from copper(i) and silver(i) halides and thioacetamide (TAA).

Binuclear complexes as tectons in designing supramolecular solid-state architectures

2005 ◽  
Vol 77 (10) ◽  
pp. 1685-1706 ◽  
Author(s):  
Marius Andruh
Keyword(s):  
Solid State ◽  
Metal Ions ◽  
Coordination Polymers ◽  
Building Blocks ◽  
Heterometallic Complexes ◽  
Binuclear Complexes ◽  
Rich Variety ◽  
Network Topologies ◽  
The One

Oligonuclear complexes as well as coordination polymers with various network topologies can be obtained by using homo- or heterobinuclear complexes as starting materials. These building blocks are stable complexes, where the metal ions are held together by compartmental ligands, or alkoxo-bridged Cu(II) species. The binuclear nodes can be connected through appropriate exo-dentate ligands, or through metal-containing anions (e.g., [M(CN)6]3-, M = CrIII, FeIII, CoIII). A rich variety of 3d-3d and 3d-4f heterometallic complexes, with interesting architectures and topologies of the spin carriers, has been obtained. A particular case is the one concerning the 3d-4f binuclear nodes. Following this strategy, we were able to obtain coordination polymers containing three different spin carriers (2p-3d-4f; 3d-3d'-4f).

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