Comparative kinetic study of oxygen atom transfer reactions of diperoxo and monoperoxo complexes of oxovanadium(V) in aqueous solution

1990 ◽  
Vol 29 (22) ◽  
pp. 4457-4461 ◽  
Author(s):  
Arlene F. Ghiron ◽  
Richard C. Thompson
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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