Comparative kinetic study of oxygen atom transfer reactions of oxohydroxodiperoxomolybdenum(VI) and oxo(oxalato)diperoxomolybdenum(VI) in aqueous solution

1989 ◽  
Vol 28 (19) ◽  
pp. 3647-3650 ◽  
Author(s):  
Arlene F. Ghiron ◽  
Richard C. Thompson
Keyword(s):  
Aqueous Solution ◽  
Oxygen Atom ◽  
Kinetic Study ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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