Magnetic exchange interactions in some novel .mu.-azido-bridged copper(II) dimers. Crystal structures of [L2Cu2(.mu.-N3)(N3)2](ClO4).cntdot.H2O, LCu(N3)2, [L2Cu2(.mu.-N3)2(ClO4)2], and L'Cu(N3)2 (L = N,N',N"-trimethyl-1,4,7-triazacyclononane and L' = 1,4,7-triazacyclononane)

1986 ◽  
Vol 25 (16) ◽  
pp. 2818-2824 ◽  
Author(s):  
Phalguni Chaudhuri ◽  
Karen Oder ◽  
Karl Wieghardt ◽  
Bernhard Nuber ◽  
Johannes Weiss
Keyword(s):  
Crystal Structures ◽  
Exchange Interactions ◽  
Magnetic Exchange

Probing the magnetic and magnetothermal properties of M(ii)–Ln(iii) complexes (where M(ii) = Ni or Zn; Ln(iii) = La or Pr or Gd)

2014 ◽  
Vol 43 (46) ◽  
pp. 17375-17384 ◽  
Author(s):  
Naushad Ahmed ◽  
Chinmoy Das ◽  
Shefali Vaidya ◽  
Anant Kumar Srivastava ◽  
Stuart K. Langley ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Exchange Interactions ◽  
Magnetic Characterization ◽  
Magnetic Exchange

We report the crystal structures of Ni(ii)–Ln(iii) (where Ln = Gd or Pr) complexes and their suitably substituted diamagnetic analogues. Magnetic characterization revealed the nature of the magnetic exchange interactions and the magnetothermal properties.

A new 1-1-4 pattern of magnetic exchange interactions in a cubane core tetranuclear copper (II) complex

Polyhedron ◽  
2021 ◽  
Vol 199 ◽  
pp. 115088
Author(s):  
Azadeh Mehrani ◽  
Maurice G. Sorolla ◽  
Tatyana Makarenko ◽  
Allan J. Jacobson
Keyword(s):  
Exchange Interactions ◽  
Magnetic Exchange

scholarly journals Isotropic Nature of the Metallic Kagome Ferromagnet Fe3Sn2 at High Temperatures

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 307
Author(s):  
Rebecca L. Dally ◽  
Daniel Phelan ◽  
Nicholas Bishop ◽  
Nirmal J. Ghimire ◽  
Jeffrey W. Lynn
Keyword(s):  
Elevated Temperatures ◽  
Magnetocrystalline Anisotropy ◽  
Inelastic Neutron Scattering ◽  
Exchange Interactions ◽  
Inelastic Neutron ◽  
Temperature Threshold ◽  
Magnetic Exchange ◽  
Spatial Anisotropy ◽  
Isotropic Exchange ◽  
State Spin

Anisotropy and competing exchange interactions have emerged as two central ingredients needed for centrosymmetric materials to exhibit topological spin textures. Fe3Sn2 is thought to have these ingredients as well, as it has recently been discovered to host room temperature skyrmionic bubbles with an accompanying topological Hall effect. We present small-angle inelastic neutron scattering measurements that unambiguously show that Fe3Sn2 is an isotropic ferromagnet below TC≈660 K to at least 480 K—the lower temperature threshold of our experimental configuration. Fe3Sn2 is known to have competing magnetic exchange interactions, correlated electron behavior, weak magnetocrystalline anisotropy, and lattice (spatial) anisotropy; all of these features are thought to play a role in stabilizing skyrmions in centrosymmetric systems. Our results reveal that at the elevated temperatures measured, there is an absence of significant magnetocrystalline anisotropy and that the system behaves as a nearly ideal isotropic exchange interaction ferromagnet, with a spin stiffness D(T=480 K)=168 meV Å2, which extrapolates to a ground state spin stiffness D(T=0 K)=231 meV Å2.

scholarly journals Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M4L6 tetrahedral cages

2021 ◽  
Vol 12 (14) ◽  
pp. 5134-5142 ◽  
Author(s):  
Aaron J. Scott ◽  
Julia Vallejo ◽  
Arup Sarkar ◽  
Lucy Smythe ◽  
E. Regincós Martí ◽  
...  
Keyword(s):  
Exchange Interactions ◽  
Magnetic Interactions ◽  
Magnetic Exchange ◽  
Guest Chemistry

The tetrahedral [NiII4L6]8+ cage can reversibly bind paramagnetic MX41/2− guests, inducing magnetic exchange interactions between host and guest.

scholarly journals Magnetic exchange interactions in the van der Waals layered antiferromagnet MnPSe3

2021 ◽  
Vol 103 (2) ◽  
Author(s):  
S. Calder ◽  
A. V. Haglund ◽  
A. I. Kolesnikov ◽  
D. Mandrus
Keyword(s):  
Van Der Waals ◽  
Exchange Interactions ◽  
Magnetic Exchange

scholarly journals Analysis of the Magnetic Exchange Interactions in Yttrium(III) Complexes Containing Nitronyl Nitroxide Radicals

2017 ◽  
Vol 56 (12) ◽  
pp. 6788-6801 ◽  
Author(s):  
Julie Jung ◽  
Marin Puget ◽  
Olivier Cador ◽  
Kevin Bernot ◽  
Carmen J. Calzado ◽  
...  
Keyword(s):  
Exchange Interactions ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Magnetic Exchange
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