Stabilization of high-temperature antimony oxide with molybdenum incorporation. Structure of molybdenum-doped antimony oxide (Sb2O4) by powder neutron diffraction and extended x-ray absorption fine structure spectroscopy

1985 ◽  
Vol 24 (21) ◽  
pp. 3370-3375 ◽  
Author(s):  
Raymond G. Teller ◽  
Mark R. Antonio ◽  
James F. Brazdil ◽  
M. Mehicic ◽  
Robert K. Grasselli
1999 ◽  
Vol 35 (5) ◽  
pp. 3286-3288 ◽  
Author(s):  
V.G. Harris ◽  
Q. Huang ◽  
V.R. Shah ◽  
G. Markandeyulu ◽  
K.V.S. Rama Rao ◽  
...  

2013 ◽  
Vol 68 (9) ◽  
pp. 2007-2011 ◽  
Author(s):  
Chang-Yu Liao ◽  
Fang-Chih Chang ◽  
H. Paul Wang ◽  
Yu-Ling Wei ◽  
Chih-Ju G. Jou

Toxic arsenics in an AsH3 scrubber sludge were thermally stabilized in the temperature range of 973–1,373 K. To better understand how the high-temperature treatments can stabilize arsenics in the sludge, their synchrotron X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectra of arsenics were determined. It is found that the reduced arsenic leachability may be associated with the formation of As2O5 (51–59%) and embedded As(V) within the Ca3(PO4)2 matrix (41–49%) in the stabilized sludge. In addition, the As-O bond distances in the stabilized As2O5 are much less than that of normal As2O5 by 0.05–0.07 Å. The shorter As-O bond distances accompanied with the higher bonding energy also have a contribution to the thermal stabilization of arsenics.


2014 ◽  
Vol 118 (45) ◽  
pp. 26292-26303 ◽  
Author(s):  
Francisco J. Espinosa-Faller ◽  
Dylan R. Conradson ◽  
Shannon C. Riha ◽  
Mary B. Martucci ◽  
Sarah J. Fredrick ◽  
...  

1996 ◽  
Vol 79 (12) ◽  
pp. 9037-9042 ◽  
Author(s):  
C. Revenant‐Brizard ◽  
J. R. Regnard ◽  
S. Solmi ◽  
A. Armigliato ◽  
S. Valmorri ◽  
...  

2008 ◽  
Vol 79 (1) ◽  
pp. 014101 ◽  
Author(s):  
Toshihide Kawai ◽  
Wang-Jae Chun ◽  
Kiyotaka Asakura ◽  
Yuichiro Koike ◽  
Masaharu Nomura ◽  
...  

1997 ◽  
Vol 68 (2) ◽  
pp. 536-539 ◽  
Author(s):  
I. Nakai ◽  
K. Takahashi ◽  
Y. Shiraishi ◽  
T. Nakagome ◽  
F. Izumi ◽  
...  

Author(s):  
Jaen Ocadiz-Flores ◽  
Aimen E. Gheribi ◽  
John Vlieland ◽  
Dick de Haas ◽  
Kathy Dardenne ◽  
...  

The short-range structures of LiF-ThF4, NaF-AnF4, KF-AnF4, and Cs-AnF4 (An = Th, U), were probed using in situ high temperature Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Signally, the EXAFS...


2015 ◽  
Vol 86 (3) ◽  
pp. 034102 ◽  
Author(s):  
Naoyoshi Murata ◽  
Makoto Kobayashi ◽  
Yukari Okada ◽  
Takuya Suzuki ◽  
Hiroaki Nitani ◽  
...  

2012 ◽  
Vol 24 (33) ◽  
pp. 336005 ◽  
Author(s):  
V Raghavendra Reddy ◽  
Carlo Meneghini ◽  
Deepti Kothari ◽  
Ajay Gupta ◽  
Giuliana Aquilanti

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