Solid-state and solution properties of (N,N'-ethylenebis(salicylideneaminato))(nitrato)iron(III) and related complexes

1985 ◽  
Vol 24 (19) ◽  
pp. 2884-2889 ◽  
Author(s):  
James C. Fanning ◽  
James L. Resce ◽  
Gary C. Lickfield ◽  
Margaret E. Kotun
Keyword(s):  
Solid State ◽  
Solution Properties

Ordered Structures of Styrene Butadiene Block Copolymers

1967 ◽  
Vol 40 (5) ◽  
pp. 1526-1528
Author(s):  
Ed Vanzo
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
Mechanical Deformation ◽  
Solution Properties ◽  
Two Dimensional ◽  
Ordered Structure ◽  
Ordered Structures ◽  
Polymer Molecules ◽  
Cast Films ◽  
Styrene Butadiene

Abstract Anionically prepared block copolymers of butadiene and styrene exhibit solution properties which result from a two dimensional ordering of the polymer molecules. The most notable of these properties is the iridescent colors of toluene solutions which are dependent on concentration and abruptly change on mechanical deformation. Electron micrographs of the surface of cast films indicate that the ordered structure is retained to some degree in the solid state.

Composition and solution properties of fluorinated block copolymers and their surface structures in the solid state

2009 ◽  
Vol 52 (2) ◽  
pp. 203-211 ◽  
Author(s):  
HuaGang Ni ◽  
DongWu Xue ◽  
XiaoFang Wang ◽  
Wei Zhang ◽  
XinPing Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
Surface Structures ◽  
Solution Properties

Solid-State and Solution Properties of Cationic Lanthanide Complexes of a New Neutral Heptadentate N4O3 Tripodal Ligand

2003 ◽  
Vol 42 (24) ◽  
pp. 7978-7989 ◽  
Author(s):  
Florence Bravard ◽  
Yann Bretonnière ◽  
Raphaël Wietzke ◽  
Christelle Gateau ◽  
Marinella Mazzanti ◽  
...  
Keyword(s):  
Solid State ◽  
Lanthanide Complexes ◽  
Solution Properties ◽  
Tripodal Ligand

Synthesis and Characterization of FunctionalizedN,N‘-Diphenylformamidinate Silver(I) Dimers:  Solid-State Structures and Solution Properties

1999 ◽  
Vol 38 (24) ◽  
pp. 5571-5578 ◽  
Author(s):  
Stephen J. Archibald ◽  
Nathaniel W. Alcock ◽  
Daryle H. Busch ◽  
David R. Whitcomb
Keyword(s):  
Solid State ◽  
Synthesis And Characterization ◽  
Solution Properties ◽  
Solid State Structures

Solid State and Solution Properties of OctylD-Glucopyranosides

1988 ◽  
Vol 40 (11) ◽  
pp. 438-440 ◽  
Author(s):  
A. J. J. Straathof ◽  
H. van Bekkum ◽  
A. P. G. Kieboom
Keyword(s):  
Solid State ◽  
Solution Properties

Lanthanide Complexes of the Hexadentate N-Donor Podand Tris[3-(2-pyridyl)pyrazolyl]hydroborate:  Solid-State and Solution Properties

1997 ◽  
Vol 36 (1) ◽  
pp. 10-18 ◽  
Author(s):  
Peter L. Jones ◽  
Angelo J. Amoroso ◽  
John C. Jeffery ◽  
Jon A. McCleverty ◽  
Elefteria Psillakis ◽  
...  
Keyword(s):  
Solid State ◽  
Lanthanide Complexes ◽  
Solution Properties

scholarly journals Alexdrandrite Effects and Pseudosymmetry in Aluminum Oxalates

2014 ◽  
Vol 70 (a1) ◽  
pp. C1017-C1017
Author(s):  
Ruthairat Nimthong ◽  
Matthias Zeller ◽  
Patimaporn Sungnoi ◽  
Sumpun Wongnawa ◽  
Chaveng Pakawatchai
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Color Change ◽  
Analysis Data ◽  
Tetragonal Symmetry ◽  
Potassium Ions ◽  
Solution Properties ◽  
Cubic Symmetry ◽  
Change Effect ◽  
Sodium And Potassium

Three chromium doped potassium aluminum oxalates, (K3[Al0.95Cr0.05(C2O4)3]·3H2O) "Blue", (K2/3Na7/3[Al0.95Cr0.05(C2O4)3]·4H2O) "RedCubic", and (K18{Na[Al0.964Cr0.036(C2O4)3]6}Cl·18H2O) "Red-Hexagonal" were prepared from aqueous solutions of K3[Cr(C2O4)3]·3H2O, K3[Al(C2O4)3]·3H2O and NaCl, and their solid state and solution properties were rationalized from their crystal structures, analysis data and solid state and solution UV-vis spectra. Crystals of "RedCubic" are characterized by a metrically cubic I-centered unit cell, but do have actual tetragonal symmetry derived by ordering of sodium and potassium ions not compatible with the apparent cubic symmetry. Results of 13C-NMR, EPMA/EDX, SC-XRD, and UV-Vis spectroscopies are discussed in relation to the compound's structures and color behavior. In aqueous solution RedCubic and Blue show the same greenish purple color and identical electronic absorption peaks. In the solid state, they have different colors and show slightly different absorption peaks. Their color behavior as well as the Alexandrite color-change effect observed in the two Red crystals are rationalized based on the compounds' absorption peaks.

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