Autothermal Catalytic Partial Oxidation of Bio-Oil Functional Groups: Esters and Acids

2008 ◽  
Vol 22 (2) ◽  
pp. 1318-1327 ◽  
Author(s):  
David C. Rennard ◽  
Paul J. Dauenhauer ◽  
Sarah A. Tupy ◽  
Lanny D. Schmidt
Keyword(s):  
Functional Groups ◽  
Partial Oxidation ◽  
Catalytic Partial Oxidation ◽  
Bio Oil

Effect of Functional Groups on Autothermal Partial Oxidation of Bio-oil. Part 2: Role of Homogeneous and Support-Mediated Reactions

2011 ◽  
Vol 25 (7) ◽  
pp. 3172-3185 ◽  
Author(s):  
Jacob S. Kruger ◽  
David C. Rennard ◽  
Tyler R. Josephson ◽  
Lanny D. Schmidt
Keyword(s):  
Functional Groups ◽  
Partial Oxidation ◽  
Bio Oil

Non-catalytic partial oxidation of bio-oil to synthesis gas for distributed hydrogen production

2009 ◽  
Vol 34 (20) ◽  
pp. 8519-8534 ◽  
Author(s):  
Jonathan R. Marda ◽  
Joelle DiBenedetto ◽  
Shannon McKibben ◽  
Robert J. Evans ◽  
Stefan Czernik ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Partial Oxidation ◽  
Synthesis Gas ◽  
Catalytic Partial Oxidation ◽  
Bio Oil

Effect of Functional Groups on Autothermal Partial Oxidation of Bio-oil. Part 1: Role of Catalyst Surface and Molecular Oxygen

2011 ◽  
Vol 25 (7) ◽  
pp. 3157-3171 ◽  
Author(s):  
Jacob S. Kruger ◽  
David C. Rennard ◽  
Tyler R. Josephson ◽  
Lanny D. Schmidt
Keyword(s):  
Molecular Oxygen ◽  
Functional Groups ◽  
Partial Oxidation ◽  
Catalyst Surface ◽  
Bio Oil

scholarly journals Oscillatory Behaviour of Ni Supported on ZrO2 in the Catalytic Partial Oxidation of Methane as Determined by Activation Procedure

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2495
Author(s):  
Daniela Pietrogiacomi ◽  
Maria Cristina Campa ◽  
Ida Pettiti ◽  
Simonetta Tuti ◽  
Giulia Luccisano ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Partial Oxidation ◽  
Active Sites ◽  
Direct Reduction ◽  
Partial Oxidation Of Methane ◽  
Catalytic Partial Oxidation ◽  
Oxidation Of Methane ◽  
Short Contact Time ◽  
Oxidation Reduction ◽  
Ni Species

Ni/ZrO2 catalysts, active and selective for the catalytic partial oxidation of methane to syngas (CH4-CPO), were prepared by the dry impregnation of zirconium oxyhydroxide (Zhy) or monoclinic ZrO2 (Zm), calcination at 1173 K and activation by different procedures: oxidation-reduction (ox-red) or direct reduction (red). The characterization included XRD, FESEM, in situ FTIR and Raman spectroscopies, TPR, and specific surface area measurements. Catalytic activity experiments were carried out in a flow apparatus with a mixture of CH4:O2 = 2:1 in a short contact time. Compared to Zm, Zhy favoured the formation of smaller NiO particles, implying a higher number of Ni sites strongly interacting with the support. In all the activated Ni/ZrO2 catalysts, the Ni–ZrO2 interaction was strong enough to limit Ni aggregation during the catalytic runs. The catalytic activity depended on the activation procedures; the ox-red treatment yielded very active and stable catalysts, whereas the red treatment yielded catalysts with oscillating activity, ascribed to the formation of Niδ+ carbide-like species. The results suggested that Ni dispersion was not the main factor affecting the activity, and that active sites for CH4-CPO could be Ni species at the boundary of the metal particles in a specific configuration and nuclearity.

Non-Premixed Reactive Volatilization Reactor for Catalytic Partial Oxidation of Low Volatility Fuels at a Short Contact Time

2021 ◽  
Author(s):  
Ying Lin ◽  
Xuesong Li ◽  
Martyn Twigg ◽  
William F Northrop
Keyword(s):  
Partial Oxidation ◽  
Contact Time ◽  
Catalytic Partial Oxidation ◽  
Liquid Hydrocarbons ◽  
Short Contact ◽  
Short Contact Time ◽  
Opposed Flow

This work presents a novel non-premixed opposed-flow reactive volatilization reactor that simultaneously vaporizes and partially oxidizes low volatility liquid hydrocarbons at a short contact time (<12 ms). In the reactor,...

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