A Numerical Exercise To Teach Electrochemical Impedance Using Electric Circuit Simulation Software

2013 ◽  
Vol 90 (12) ◽  
pp. 1699-1700 ◽  
Author(s):  
Antonio A. Moya
Aerospace ◽  
2020 ◽  
Vol 7 (7) ◽  
pp. 91
Author(s):  
Benjamin St. Peter ◽  
Rainer A. Dressler ◽  
Yu-hui Chiu ◽  
Timothy Fedkiw

We report on the development of a software tool, the Electrospray Propulsion Engineering Toolkit (ESPET), that is currently being shared as a web application with the purpose to accelerate the development of electrospray thruster arrays for space propulsion. ESPET can be regarded as a database of microfluidic properties and electrohydrodynamic scaling models that are combined into a performance estimation tool. The multiscale model integrates experimental high-level physics characterization of microfluidic components in a full-scale electrospray propulsion (ESP) microfluidic network performance solution. ESPET takes an engineering model approach that breaks the ESP system down into multiple microfluidic components or domains that can be described by either analytical microfluidic or reduced order numerical solutions. ESPET can be divided into three parts: a central database of critical microfluidic properties, a microfluidic domain modeler, and a microfluidic network solver. Two options exist for the network solution, a detailed multi-domain solver and a QuickSolver designed for rapid design and testing of simple three-domain reservoir-feed-emitter arrays. The multi-domain network solver exploits the Hagen–Poiseuille/Ohm’s law analogy by using the publicly available SPICE (Simulation Program with Integrated Circuit Emphasis) electric circuit simulation software to solve the flow properties of the microfluidic network. Both the multi-domain and QuickSolver solutions offer Monte Carlo analysis of arrays based on user supplied tolerances on design parameters. Benchmarking demonstration examples are provided for experimental work in the literature, as well as recent experimental work conducted at Busek Co. The demonstration examples include ionic liquid propelled systems using active and passive capillary emitters, externally wetted emitter needles, and porous glass emitters, as well as a liquid metal system based on an externally wetted emitter needle.


2019 ◽  
Vol 66 (1) ◽  
pp. 121-126 ◽  
Author(s):  
Walid Belmaghraoui ◽  
Aimad Mazkour ◽  
Hicham Harhar ◽  
Mourad Harir ◽  
Souad El Hajjaji

Purpose This study aims to investigate the corrosion inhibition effect of extracted oil from Ziziphus lotus fruit on corrosion of C38 carbon steel in 5.5 M H3PO4 solution using potentiodynamic polarization and impedance techniques. Design/methodology/approach Oil composition was determined using gas chromatography, and the results showed that oleic and palmitic acids present approximately 84.0 per cent of its total chemical content. Electrochemical impedance spectroscopy (EIS) data were analyzed by adapting it to a well-developed electric circuit model. The inhibition efficiency of Z. lotus oil was calculated and compared using Tafel polarization and EIS. Findings Accordingly, the oil extract was found to act as an anodic type inhibitor. Furthermore, inhibition efficiency of Z. lotus oil extract increase with oil concentrations and achieve approximately 70.5 per cent at 3 g/L solution of Z. lotus oil. Originality/value The results obtained from different tested methods were in line, and the oil was able to reduce significantly the kinetics of the corrosion process of C38 carbon steel.


Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4583
Author(s):  
Shailendra Rajput ◽  
Alon Kuperman ◽  
Asher Yahalom ◽  
Moshe Averbukh

The specific power storage capabilities of double-layer ultracapacitors are receiving significant attention from engineers and scientific researchers. Nevertheless, their dynamic behavior should be studied to improve the performance and for efficient applications in electrical devices. This article presents an infinite resistor–capacitor (r–C) chain-based mathematical model for the analysis of double layer ultracapacitors. The internal resistance and capacitance were measured for repetitive charging and discharging cycles. The magnitudes of internal resistance and capacitance showed approximately ±10% changes for charge-discharge processes. Electrochemical impedance spectroscopy investigations revealed that the impedance of a double-layer ultracapacitor does not change significantly in the temperature range of (−30 °C to +30 °C) and voltage range of (0.3376–2.736 V). The analysis of impedance data using the proposed mathematical model showed good agreement between the experimental and theoretical data. The dynamic behavior of the ultracapacitor was successfully represented by utilizing the proposed infinite r–C chains equivalent circuit, and the reverse Fourier transform analysis. The r–C electrical equivalent circuit was also analyzed using the PSIM simulation software to study the dynamic behavior of ultracapacitor parameters. The simulation study yields an excellent agreement between the experimental and calculated voltage characteristics for repetitive charging-discharging processes.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 77 ◽  
Author(s):  
Johnatan M. Rodríguez-Serna ◽  
Ricardo Albarracín-Sánchez ◽  
Ming Dong ◽  
Ming Ren

Epoxy resin is one of the most common polymers used as part of the insulation system in key electrical assets such as power transformers and hydrogenerators. Thus, it is necessary to know their main characteristics and to evaluate their condition when subjected to High Voltage (HV). A brief review of epoxy resins’ applications as insulating materials is made, their main characteristics as insulating media are given, the improvements with nano-fillers are summarized and the main electric properties required for Partial Discharges (PD) modelling are listed. In addition, the theoretical background and state-of-the-art of the three-capacitance and analytical models for simulating PD in solid dielectrics, such as epoxy resins, are reviewed in detail. Besides, their main advantages and disadvantages are presented, some critical arguments to the modelling procedure and assumptions are made and some improvements are proposed, taking into account conclusions made from other authors using models related to the PD development process. Finally, a case study was simulated using a modified three-capacitance model and the analytical model. The PD rate, q-φ-n diagrams and the minimum, mean and maximum PD electric charge are compared with measurements reported in the literature. Simulation results are in reasonable agreement with measured values. Capacitance models can be implemented in general purpose electric circuit simulation packages; however, its simulation is computationally expensive. Additional to this, although the modified three-capacitance model is not as accurate as finite elements or analytical models, results are also in agreement with real data.


Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3413 ◽  
Author(s):  
Pengcheng Zhao ◽  
Jingang Wang ◽  
Qian Wang ◽  
Qianbo Xiao ◽  
Ruiqiang Zhang ◽  
...  

Accurate measurement of overvoltage in power grids is of great significance to study the characteristics of overvoltage and design of insulation coordination. Based on the research of D-dot voltage sensor, we designed a Dual-Differential D-dot overvoltage sensor. In order to quantify the structural parameters of the sensor, improve the performance and measurement accuracy of the sensor. The Field-Circuit Coupling method was proposed to be used in the parameter design of D-dot overvoltage sensor. The joint simulation of space electromagnetic field model and equivalent circuit model of the Dual-Differential D-dot overvoltage sensor was established with the finite element simulation software Ansoft Maxwell and circuit simulation software Simplorer. Finally, the actual sensor was manufactured. A test platform was built to verify the steady-state and transient performance of the sensor. The results show that the Dual-Differential D-dot sensor has excellent steady-state and transient performance, the error of phase and amplitude are small, and the sensor can achieve the non-contact measurement of power transmission line. Simultaneously, the rationality of the Field-Circuit Coupling method was further verified.


2011 ◽  
Vol 183 ◽  
pp. 143-148 ◽  
Author(s):  
M. Pochrząst ◽  
Jan Marciniak ◽  
K. Wróbel ◽  
Bohdan Bączkowski

The aim of the work was evaluation of electrochemical properties of Co-based alloys (Remanium GM 800+ and Biosil F) and Ni-based alloys (Heraenium NA and Remanium G-Soft) commonly used on frameworks for porcelain faced cast partial dentures. First stage of the work was evaluation of surface roughness by means of direct linear contact measurement (SURTRONIC 3+ profiler, Taylor/Hobson) of samples after casting and surface treatment. Electrochemical properties of surface were assessed by means of potentiodynamic and impedance methods. In potentiodynamic tests, in order to evaluate pitting corrosion resistance of the analyzed alloys, anodic polarization curves were recorded. The VoltaLab® PGP 201 system was applied in corrosion tests. Moreover, in order to evaluate structure and properties of the surface layer the electrochemical impedance spectroscopy (EIS) was applied. Selection of this method enabled to determine the impedance of the material – surface layer – solution interface with the use of approximation of impedance data by means of equivalent electric circuit model. The EIS tests were carried out with the use of the AutoLab PGSTAT 302N system equipped with the FRA2 Faraday impedance module. Electrochemical tests were carried out in artificial saliva at the temperature of 37°C and pH = 7,0±0,1.


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