A kinetic study of the Diels-Alder reaction: An experiment illustrating simple second-order reaction kinetics

1989 ◽  
Vol 66 (8) ◽  
pp. 690 ◽  
Author(s):  
Michael G. Silvestri ◽  
Charles E. Dills
Keyword(s):  
Kinetic Study ◽  
Reaction Kinetics ◽  
Alder Reaction ◽  
Order Reaction ◽  
Second Order ◽  
Diels Alder ◽  
Second Order Reaction ◽  
Diels Alder Reaction

Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo
Keyword(s):  
Kinetic Study ◽  
Reaction Temperature ◽  
Atmospheric Pressure ◽  
Arrhenius Equation ◽  
Alder Reaction ◽  
Diels Alder ◽  
Influence Of Temperature ◽  
Diels Alder Reaction ◽  
Influence Of Temperature On ◽  
Kinetics Of

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.

Kinetic study of Diels–Alder reaction involving in maleimide–furan compounds and linear polyurethane

2013 ◽  
Vol 70 (8) ◽  
pp. 2319-2335 ◽  
Author(s):  
Xuanxuan Liu ◽  
Pengfei Du ◽  
Li Liu ◽  
Zhen Zheng ◽  
Xinling Wang ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Infrared spectrometry to study second order reaction kinetics

1964 ◽  
Vol 41 (11) ◽  
pp. 613
Author(s):  
B. Gastambide ◽  
J. Blanc ◽  
Y. Allamagny
Keyword(s):  
Reaction Kinetics ◽  
Order Reaction ◽  
Second Order ◽  
Infrared Spectrometry ◽  
Second Order Reaction

Monochromophoric iridium(iii) pyridyl–tetrazine complexes as a unique design strategy for bioorthogonal probes with luminogenic behavior

2017 ◽  
Vol 53 (23) ◽  
pp. 3299-3302 ◽  
Author(s):  
Tommy Siu-Ming Tang ◽  
Hua-Wei Liu ◽  
Kenneth Kam-Wing Lo
Keyword(s):  
Reaction Kinetics ◽  
Design Strategy ◽  
Alder Reaction ◽  
Diels Alder ◽  
Metal Coordination ◽  
Coordination Property ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

This is the first reported use of the metal-coordination property of tetrazine in the construction of luminogenic bioorthogonal probes and modulation of the inverse electron-demand Diels–Alder reaction kinetics.

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