Use of Ultrafast Time-Resolved Spectroscopy to Demonstrate the Effect of Annealing on the Performance of P3HT:PCBM Solar Cells

2015 ◽  
Vol 7 (8) ◽  
pp. 4457-4462 ◽  
Author(s):  
Yu-Ting Wang ◽  
Mei-Hsin Chen ◽  
Chao-Ting Lin ◽  
Jian-Jhih Fang ◽  
Che-Jui Chang ◽  
...  
2015 ◽  
Author(s):  
Marina Gerhard ◽  
Andreas Arndt ◽  
Aina Quintilla ◽  
Arash Rahimi-Iman ◽  
Uli Lemmer ◽  
...  

2017 ◽  
Vol 19 (31) ◽  
pp. 20463-20473 ◽  
Author(s):  
Mateusz Gierszewski ◽  
Iwona Grądzka ◽  
Adam Glinka ◽  
Marcin Ziółek

An important limitation in the photocurrent of solar cells sensitized with Ru dyes and filled with cobalt electrolyte is electron recombination between titania conduction band (CB) and oxidized dyes, which occurs on the sub-ns time scale.


2016 ◽  
Vol 4 (38) ◽  
pp. 9021-9026 ◽  
Author(s):  
Susana Gómez-Salces ◽  
Jose Antonio Barreda-Argüeso ◽  
Rafael Valiente ◽  
Fernando Rodríguez

This work investigates the energy transfer from Ce3+ to Mn2+ in high transmission glass (HTG) doped with CeO2 and MnO through time-resolved spectroscopy to transform the solar spectrum into a more efficient red-enhanced spectrum for traditional Si-based solar cells.


2020 ◽  
Vol 11 (33) ◽  
pp. 8757-8770
Author(s):  
Benedetta Carlotti ◽  
Ifeanyi K. Madu ◽  
Hyungjun Kim ◽  
Zhengxu. Cai ◽  
Hanjie Jiang ◽  
...  

We show via time resolved spectroscopy that triplet formation proceeds via intersystem crossing in a rigid-bridged perylene diimide trimer and via efficient and fast intramolecular singlet exciton fission in the analogous flexible-bridged trimer.


Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2512
Author(s):  
Daming Zheng ◽  
Changheng Tong ◽  
Tao Zhu ◽  
Yaoguang Rong ◽  
Thierry Pauporté

During the past decade, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has risen rapidly, and it now approaches the record for single crystal silicon solar cells. However, these devices still suffer from a problem of stability. To improve PSC stability, two approaches have been notably developed: the use of additives and/or post-treatments that can strengthen perovskite structures and the use of a nontypical architecture where three mesoporous layers, including a porous carbon backcontact without hole transporting layer, are employed. This paper focuses on 5-ammonium valeric acid iodide (5-AVAI or AVA) as an additive in methylammonium lead iodide (MAPI). By combining scanning electron microscopy (SEM), X-ray diffraction (XRD), time-resolved photoluminescence (TRPL), current–voltage measurements, ideality factor determination, and in-depth electrical impedance spectroscopy (EIS) investigations on various layers stacks structures, we discriminated the effects of a mesoscopic scaffold and an AVA additive. The AVA additive was found to decrease the bulk defects in perovskite (PVK) and boost the PVK resistance to moisture. The triple mesoporous structure was detrimental for the defects, but it improved the stability against humidity. On standard architecture, the PCE is 16.9% with the AVA additive instead of 18.1% for the control. A high stability of TiO2/ZrO2/carbon/perovskite cells was found due to both AVA and the protection by the all-inorganic scaffold. These cells achieved a PCE of 14.4% in the present work.


RSC Advances ◽  
2020 ◽  
Vol 10 (71) ◽  
pp. 43459-43471
Author(s):  
Hussain A. Z. Sabek ◽  
Ahmed M. M. Alazaly ◽  
Dina Salah ◽  
Hesham S. Abdel-Samad ◽  
Mohamed A. Ismail ◽  
...  

Solvation-dependent photophysical properties of two push–pull thiophene-based compounds with donor–π–acceptor (D–π–A) structures were investigated using absorption, fluorescence emission and time resolved spectroscopy, and supported by different solvation models.


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