Time-resolved spectroscopy of charge transfer phenomena in organic solar cells

2015 ◽  
Author(s):  
Marina Gerhard ◽  
Andreas Arndt ◽  
Aina Quintilla ◽  
Arash Rahimi-Iman ◽  
Uli Lemmer ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Organic Solar Cells ◽  
Time Resolved ◽  
Time Resolved Spectroscopy

scholarly journals Dissociation of Charge Transfer States and Carrier Separation in Bilayer Organic Solar Cells: A Time-Resolved Electroabsorption Spectroscopy Study

2015 ◽  
Vol 137 (25) ◽  
pp. 8192-8198 ◽  
Author(s):  
Andrius Devižis ◽  
Jelissa De Jonghe-Risse ◽  
Roland Hany ◽  
Frank Nüesch ◽  
Sandra Jenatsch ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Organic Solar Cells ◽  
Spectroscopy Study ◽  
Time Resolved ◽  
Electroabsorption Spectroscopy ◽  
Carrier Separation

scholarly journals Long-lived and disorder-free charge transfer states enable endothermic charge separation in efficient non-fullerene organic solar cells

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Ture F. Hinrichsen ◽  
Christopher C. S. Chan ◽  
Chao Ma ◽  
David Paleček ◽  
Alexander Gillett ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Organic Solar Cells ◽  
Charge Separation ◽  
Free Charge ◽  
Charge Generation ◽  
Time Resolved ◽  
Thermodynamic Conditions ◽  
Donor Acceptor ◽  
Interfacial Charge

Abstract Organic solar cells based on non-fullerene acceptors can show high charge generation yields despite near-zero donor–acceptor energy offsets to drive charge separation and overcome the mutual Coulomb attraction between electron and hole. Here, we use time-resolved optical spectroscopy to show that free charges in these systems are generated by thermally activated dissociation of interfacial charge-transfer states that occurs over hundreds of picoseconds at room temperature, three orders of magnitude slower than comparable fullerene-based systems. Upon free electron–hole encounters at later times, both charge-transfer states and emissive excitons are regenerated, thus setting up an equilibrium between excitons, charge-transfer states and free charges. Our results suggest that the formation of long-lived and disorder-free charge-transfer states in these systems enables them to operate closely to quasi-thermodynamic conditions with no requirement for energy offsets to drive interfacial charge separation and achieve suppressed non-radiative recombination.

Time-Resolved Charge-Transfer State Emission in Organic Solar Cells: Temperature and Blend Composition Dependences of Interfacial Traps

2015 ◽  
Vol 119 (24) ◽  
pp. 13516-13523 ◽  
Author(s):  
Andreas P. Arndt ◽  
Marina Gerhard ◽  
Aina Quintilla ◽  
Ian A. Howard ◽  
Martin Koch ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Organic Solar Cells ◽  
Charge Transfer State ◽  
Time Resolved ◽  
Blend Composition ◽  
Transfer State

scholarly journals Photophysical Properties of the PVK-MEH-PPV/PCBM Composite for Organic Solar Cells Application: Synthesis, Characterization and Computational Study

Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2902
Author(s):  
Faten Abbassi ◽  
Mohamed Mbarek ◽  
Maha Almoneef ◽  
Kamel Alimi
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Organic Solar Cells ◽  
Density Functional ◽  
Computational Study ◽  
Photophysical Properties ◽  
Chemical Properties ◽  
Acid Methyl Ester ◽  
Time Resolved ◽  
Donor And Acceptor

The physical and chemical properties of a new organic composite including PVK-MEH-PPV bi-block copolymer and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) were recorded. The functionalization and the charge transfer that occurs between donor and acceptor were examined and computed. In fact, the stationary and time-resolved photoluminescence properties were used to examine the effect of the PCBM on the optical properties of the PVK-MEH-PPV matrix. The photoluminescence quenching accompanied by faster PL decay confirmed the charge transfer and interaction process. The electrical and optoelectronic properties and the charge carriers’ injection in the resulting composite were examined. The experimental conclusion was corroborated and confirmed by a calculation based on density functional theory (DFT). Hence, the combination of experimental and theoretical results indicated that the result composite can be applied as an active layer for organic solar cells.

scholarly journals Activating intramolecular singlet exciton fission by altering π-bridge flexibility in perylene diimide trimers for organic solar cells

2020 ◽  
Vol 11 (33) ◽  
pp. 8757-8770
Author(s):  
Benedetta Carlotti ◽  
Ifeanyi K. Madu ◽  
Hyungjun Kim ◽  
Zhengxu. Cai ◽  
Hanjie Jiang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Solar Cells ◽  
Perylene Diimide ◽  
Intersystem Crossing ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Singlet Exciton ◽  
Singlet Exciton Fission ◽  
Triplet Formation

We show via time resolved spectroscopy that triplet formation proceeds via intersystem crossing in a rigid-bridged perylene diimide trimer and via efficient and fast intramolecular singlet exciton fission in the analogous flexible-bridged trimer.

Uphill and downhill charge generation from charge transfer to charge separated states in organic solar cells

2021 ◽  
Author(s):  
Shahidul Alam ◽  
Vojtech Nádaždy ◽  
Tomáš Váry ◽  
Christian Friebe ◽  
Rico Meitzner ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Solar Cells ◽  
Charge Transfer ◽  
Energy Level ◽  
Density Of States ◽  
Organic Solar Cells ◽  
Joint Density ◽  
Charge Generation ◽  
Donor Acceptor

Energy level alignments at the organic donor–acceptor interface cannot be predicted from cyclic voltammetry. Onsets for joint density of states and charge generation, reveal cases of energy uphill and – newly observed – downhill charge generation.

Synthesis and photophysical properties of extended π conjugated naphthalimides

2017 ◽  
Vol 16 (4) ◽  
pp. 539-546 ◽  
Author(s):  
C. Rémy ◽  
C. Allain ◽  
I. Leray
Keyword(s):  
Charge Transfer ◽  
Dft Calculations ◽  
Photophysical Properties ◽  
Photoinduced Charge Transfer ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Td Dft ◽  
Photoinduced Charge

A series of π conjugated naphthalimide derivatives were prepared. Compounds display efficient photoinduced charge transfer in solution which was rationalized by time-resolved spectroscopy and modelled by TD-DFT calculations.

scholarly journals Experimental Evidence Relating Charge-Transfer-State Kinetics and Strongly Reduced Bimolecular Recombination in Organic Solar Cells

2020 ◽  
Vol 11 (24) ◽  
pp. 10519-10525
Author(s):  
Nasim Zarrabi ◽  
Oskar J. Sandberg ◽  
Christina Kaiser ◽  
Jegadesan Subbiah ◽  
David J. Jones ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Experimental Evidence ◽  
Organic Solar Cells ◽  
Charge Transfer State ◽  
Bimolecular Recombination ◽  
Transfer State
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