Biomass-Based Composites from Poly(lactic acid) and Wood Flour by Vapor-Phase Assisted Surface Polymerization

2010 ◽  
Vol 3 (2) ◽  
pp. 385-391 ◽  
Author(s):  
Donghee Kim ◽  
Yoshito Andou ◽  
Yoshihito Shirai ◽  
Haruo Nishida
Keyword(s):  
Lactic Acid ◽  
Vapor Phase ◽  
Wood Flour ◽  
Poly Lactic Acid ◽  
Surface Polymerization

scholarly journals Silane Modified Wood Flour Blended with Poly(lactic acid) and its Effects on Composite Performance

BioResources ◽  
2015 ◽  
Vol 10 (3) ◽  
Author(s):  
Shanshan Lv ◽  
Haiyan Tan ◽  
Jiyou Gu ◽  
Yanhua Zhang
Keyword(s):  
Lactic Acid ◽  
Wood Flour ◽  
Poly Lactic Acid ◽  
Modified Wood

scholarly journals Styrene-Assisted Maleic Anhydride Grafted Poly(lactic acid) as an Effective Compatibilizer for Wood Flour/Poly(lactic acid) Bio-Composites

Polymers ◽  
2017 ◽  
Vol 9 (11) ◽  
pp. 623 ◽  
Author(s):  
Jun Du ◽  
Youyong Wang ◽  
Xinfeng Xie ◽  
Min Xu ◽  
Yongming Song
Keyword(s):  
Lactic Acid ◽  
Maleic Anhydride ◽  
Wood Flour ◽  
Poly Lactic Acid

Mechanical properties of wood flour/poly (lactic acid) composites coupled with waterborne silane-polyacrylate copolymer emulsion

Holzforschung ◽  
2016 ◽  
Vol 70 (5) ◽  
pp. 439-447 ◽  
Author(s):  
Ru Liu ◽  
Shupin Luo ◽  
Jinzhen Cao ◽  
Yu Chen
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
High Performance ◽  
Coupling Effect ◽  
Wood Flour ◽  
Flexural Modulus ◽  
Coupling Agents ◽  
Poly Lactic Acid ◽  
Effective Coupling ◽  
Methacryloxypropyl Trimethoxysilane

Abstract Wood flour/polylactic acid (WF/PLA) composites were produced with a WF content of 50% based on three types of waterborne polyacrylate (PA) emulsions including a PA homopolymer emulsion and two types of silane-PA copolymer emulsions as coupling agents. Two silanes were in focus, namely, γ-methacryloxypropyl- trimethoxysilane (silane-1) and vinyltrimethoxysilane (silane-2). The emulsions and the modified WFs were characterized, and the effects were investigated in terms of emulsion type and their loading levels on the mechanical properties of WF/PLA composites. (1) Both types of silanes could be successfully copolymerized with PA to form stable emulsions. (2) With increasing PA loading, the mechanical properties (except for flexural modulus) of the composites increased at first before reaching the maximum values at 4% PA loading and then the properties worsened. However, these values were larger than those of pure composites, especially in cases when PA-silane emulsions were applied. (3) PA modified with silane-1 showed the best coupling effect among all the three PA emulsions. The results can be interpreted that PA emulsions are effective coupling agents for the preparation of high-performance WPCs.

scholarly journals Rheology of Wood Flour Filled Poly(lactic acid)

2017 ◽  
Vol 200 ◽  
pp. 61-67 ◽  
Author(s):  
Valentina Mazzanti ◽  
Francesco Mollica
Keyword(s):  
Lactic Acid ◽  
Wood Flour ◽  
Poly Lactic Acid

scholarly journals Feasibility of Reprocessing Natural Fiber Filled Poly(lactic acid) Composites: An In-Depth Investigation

2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Sujal Bhattacharjee ◽  
Dilpreet S. Bajwa
Keyword(s):  
Lactic Acid ◽  
Natural Fiber ◽  
Environmental Concern ◽  
Wood Flour ◽  
Gel Permeation Chromatography ◽  
Thermomechanical Properties ◽  
Poly Lactic Acid ◽  
Filler Concentration ◽  
Scanning Calorimetry ◽  
Abrupt Decrease

Poly(lactic acid) (PLA) based composites are biodegradable; their disposal after single use may be needless and uneconomical. Prodigal disposal of these composites could also create an environmental concern and additional demand for biobased feedstock. Under these circumstances, recycling could be an effective solution, since it will widen the composite service life and prevent the excessive use of natural resources. This research investigates an in-depth impact of recycling on the mechanical and thermomechanical properties of oak wood flour based PLA composites. Two composite formulations (30 and 50 wt% filler), each with 3 wt% coupling agent (PLA-g-MA), were produced and reprocessed six times by extrusion followed by injection molding. Measurements of fiber length and molecular weight of polymer were, respectively, carried out by gel permeation chromatography (GPC). Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR) tools were used to study morphological and molecular alterations. With consecutive recycling, PLA composites showed a gradual decrease in strength and stiffness properties and an increase in strain properties. The 50% and 30% filler concentration of fibers in the composite showed an abrupt decrease in strength properties after six and two reprocessing cycles, respectively.

scholarly journals Effects of wood flour and MA-EPDM on the properties of fused deposition modeling 3D-printed poly lactic acid composites

BioResources ◽  
2021 ◽  
Vol 16 (4) ◽  
pp. 7122-7138
Author(s):  
Sang-U Bae ◽  
Young-Rok Seo ◽  
Birm-June Kim ◽  
Min Lee
Keyword(s):  
Lactic Acid ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Wood Flour ◽  
Poly Lactic Acid ◽  
Common System ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
3D Printed ◽  
Material Composite

Fused deposition modeling (FDM) 3D printing technology is the most common system for polymer additive manufacturing (AM). Recent studies have been conducted to expand both the range of materials that can be used for FDM and their applications. As a filler, wood flour was incorporated into poly lactic acid (PLA) polymer to develop a biocomposite material. Composite filaments were manufactured with various wood flour contents and then successfully used for 3D printing. Morphological, mechanical, and biodegradation properties of FDM 3D-printed PLA composites were investigated. To mitigate brittleness, 5 phr of maleic anhydride grafted ethylene propylene diene monomer (MA-EPDM) was added to the composite blends, and microstructural properties of the composites were examined by scanning electron microscopy (SEM). Mechanical strength tests demonstrated that elasticity was imparted to the composites. Additionally, test results showed that the addition of wood flour to the PLA matrix promoted pore generation and further influenced the mechanical and biodegradation properties of the 3D-printed composites. An excellent effect of wood flour on the biodegradation properties of FDM 3D-printed PLA composites was observed.

Use of Magnesium Hydroxide as Flame Retardant in Poly(Lactic Acid)/High Impact Polystyrene/Wood Flour Composites

2018 ◽  
Vol 773 ◽  
pp. 311-315
Author(s):  
Nuttaburut Kongkraireug ◽  
Saowaroj Chuayjuljit ◽  
Phasawat Chaiwutthinan ◽  
Amnouy Larpkasemsuk ◽  
Anyaporn Boonmahitthisud
Keyword(s):  
Lactic Acid ◽  
Flame Retardant ◽  
Magnesium Hydroxide ◽  
Wood Flour ◽  
High Impact ◽  
Poly Lactic Acid ◽  
Flame Resistance ◽  
High Impact Polystyrene ◽  
Twin Screw ◽  
Effective Role

This work aimed to use magnesium hydroxide (MH) as a flame retardant in poly(lactic acid) (PLA)/high impact polystyrene (HIPS)/wood flour (WF) composite. The 80/20/20 PLA/HIPS/WF composite was melt mixed with three loadings (20, 30 and 40 phr) of MH on a twin screw extruder, followed by an injection molding. The prepared wood-plastic composites (WPCs) were investigated for their impact strength (IS), tensile strength (TS), Young’s modulus (E), elongation at break (EB), flammability and morphology. The results showed that the 80/20/20 PLA/HIPS/WF composite exhibited higher IS, TS and E than the neat PLA, but at the expense of reducing the EB. It was also found that the WPCs filled with MH at all loadings provided much higher flame resistance and E over the neat PLA, HIPS, PLA/HIPS blend and PLA/HIPS/WF composite. Therefore, the MH could play an effective role as flame retardant in the WPCs.

Sign in / Sign up

Export Citation Format

Share Document