EXPERIMENTAL INVESTIGATION OF THE INFLUENCE OF MULTI-RECYCLING ON THE FRACTURE BEHAVIOR OF POST CONSUMER HIGH IMPACT POLYSTYRENE FROM DISPOSABLE CUPS EVALUATED BY THE J-INTEGRAL APPROACH.

The aim of the present paper is to study the effect of multi-recycling on the fracture behavior of high impact polystyrene from disposable cups. After collecting and washing the material, it was subjected to six cycles of recycling. After each cycle, it was subjected to tensile tests to determine the R-curves. The theory of the J-integral contour has been used for the development of a characterization method of the fracture strength appropriate to the case of this non-linear elastoplastic polymer material. To this end, the method of multiple specimens (Single edge notch tension SENT) of thin thickness was used, by introducing cracks of the same lengths to several identical test pieces. The results suggested a slight decrease in crack resistance of recycled high impact polystyrene, especially during the first cycle, demonstrated by a comparison of JIC values related to initiation of crack propagation. The fracture energy absorbed as a function of the cycles suggested a weakening within the material. ABSTRAK: Tujuan kajian ini adalah bagi mengkaji kesan tindak balas pada pelbagai peringkat-kitar semula ke atas kerapuhan polisterin berimpak tinggi pada cawan pakai buang. Selepas mengumpul dan membasuh cawan ini, terdapat enam peringkat kitar semula. Pada setiap peringkat, ianya akan melalui ujian tegangan bagi mendapatkan lengkung-R. Teori kamiran-J kontur telah digunakan bagi mencipta kaedah khas bagi mengkaji kekuatan retakan bersesuaian bagi kes bahan polimer elastoplastik yang tidak-linear. Sehingga kini, kaedah Regangan Tepi Takuk Tunggal (SENT) telah digunakan pada spesimen berketebalan rendah, dengan menghasilkan keretakan sama panjang di permulaan kajian di buat pada pelbagai bahan uji yang serupa. Dapatan kajian menunjukkan rintangan pada retakan telah berkurang sedikit pada polisterin kitar semula berimpak tinggi, terutama pada kitaran pertama, yang ditunjukkan pada nilai JIC pada permukaan rambatan retakan awal. Tenaga kerapuhan yang meresap pada setiap kitaran menunjukkan bahan telah melemah dari dalam.

Analysis and Optimization of Dimensional Accuracy and Porosity of High Impact Polystyrene Material Printed by FDM Process: PSO, JAYA, Rao, and Bald Eagle Search Algorithms

High impact polystyrene (HIPS) material is widely used for low-strength structural applications. To ensure proper function, dimensional accuracy and porosity are at the forefront of industrial relevance. The dimensional accuracy cylindricity error (CE) and porosity of printed parts are influenced mainly by the control variables (layer thickness, shell thickness, infill density, print speed of the fused deposition modeling (FDM) process). In this study, a central composite design (CCD) matrix was used to perform experiments and analyze the complete insight information of the process (control variables influence on CE and porosity of FDM parts). Shell thickness for CE and infill density for porosity were identified as the most significant factors. Layer thickness interaction with shell thickness, infill density (except for CE), and print speed were found to be significant for both outputs. The interaction factors, i.e., shell thickness and infill density, were insignificant (negligible effect) for both outputs. The models developed produced a better fit for regression with an R2 equal to 94.56% for CE, and 99.10% for porosity, respectively. Four algorithms (bald eagle search optimization (BES), particle swarm optimization (PSO), RAO-3, and JAYA) were applied to determine optimal FDM conditions while examining six case studies (sets of weights assigned for porosity and CE) focused on minimizing both CE and porosity. BES and RAO-3 algorithms determined optimal conditions (layer thickness: 0.22 mm; shell thickness: 2 mm; infill density: 100%; print speed: 30 mm/s) at a reduced computation time equal to 0.007 s, differing from JAYA and PSO, which resulted in an experimental CE of 0.1215 mm and 2.5% of porosity in printed parts. Consequently, BES and RAO-3 algorithms are efficient tools for the optimization of FDM parts.

High-Impact Polystyrene Reinforced with Reduced Graphene Oxide as a Filament for Fused Filament Fabrication 3D Printing

Graphene and its derivatives, such as graphene oxide (GO) or reduced graphene oxide (rGO), due to their properties, have been enjoying great interest for over two decades, particularly in the context of additive manufacturing (AM) applications in recent years. High-impact polystyrene (HIPS) is a polymer used in 3D printing technology due to its high dimensional stability, low cost, and ease of processing. However, the ongoing development of AM creates the need to produce modern feedstock materials with better properties and functionality. This can be achieved by introducing reduced graphene oxide into the polymer matrix. In this study, printable composite filaments were prepared and characterized in terms of morphology and thermal and mechanical properties. Among the obtained HIPS/rGO composites, the filament containing 0.5 wt% of reduced graphene oxide had the best mechanical properties. Its tensile strength increased from 19.84 to 22.45 MPa, for pure HIPS and HIPS-0.5, respectively. Furthermore, when using the HIPS-0.5 filament in the printing process, no clogging of the nozzle was observed, which may indicate good dispersion of the rGO in the polymer matrix.

Investigation of mechanical properties and biodegradability of compatibilized thermoplastic starch/ high impact polystyrene blends reinforced by organophilic montmorillonite

This work consists of preparation and characterization of composites produced from thermoplastic starch (TPS) and high impact polystyrene (HIPS). Due to the immiscibility of the system (TPS/HIPS), it was necessary to incorporate concentrations of 1, 2 and 3% of an organophilic montmorillonite (MMT) to improve the properties of the mixtures, in particular their rigidity. The composites thus prepared were characterized using XRD, FTIR, mechanical test, degree of swelling in water and biodegradability. The results show that the addition of MMT improves the mechanical properties of the mixtures such as the tensile strength and the Young’s modulus by 5% and 10%, respectively. In contrast, the resilience of the system has significantly decreased. Moreover, for 3% of MMT, the composites biodegradability is enhanced by 15% when compared to the TPS/HIPS mixture without MMT.