[Fe(C6H14N2)2][Sb6S10] - Using a Transition Metal Complex Acting as a Pillar for the Generation of a Three-dimensional Thioantimonate(III) Network

2009 ◽  
Vol 635 (6-7) ◽  
pp. 988-994 ◽  
Author(s):  
Ragnar Kiebach ◽  
Ralph Warratz ◽  
Christian Näther ◽  
Wolfgang Bensch
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional

A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound

2003 ◽  
Vol 6 (9) ◽  
pp. 1224-1227 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko Garcı́a-Couceiro ◽  
Juan P. Garcı́a-Teran ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Bridging Ligands

Incorporating a Transition Metal Complex into Polymeric Iodoplumbate: Structure Characterization, Properties and Theoretical Study of a Unprecedented Hybrid Semiconductor: {[Cu(en)2][Pb2I6]}n

2008 ◽  
Vol 61 (5) ◽  
pp. 391 ◽  
Author(s):  
Hao-Hong Li ◽  
Ling-Guo Sun ◽  
Zhi-Rong Chen ◽  
Yun-Jie Wang ◽  
Jun-Qian Li
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Density Functional ◽  
Transition Metal Complex ◽  
Density Functional Theory Calculation ◽  
Three Dimensional ◽  
Hybrid Structure ◽  
Structure Characterization ◽  
Dimensional Network ◽  
Theory Calculation

A hybrid semiconductor {[Cu(en)2][Pb2I6]}n (1) (en = ethylenediamine) templated by a transition metal complex was synthesized and structurally characterized. The title compound consists of discrete structure-directing molecules (transition metal complex) and an inorganic iodoplumbate polymer. The iodoplumbate polymer could be described as a three-dimensional network constructed from a [Pb2I8]n4– double chain bridged by iodine. [Cu(en)2]2+ structure-directing cations are discrete, and interact with the inorganic moiety by strong static attraction and the H-bond of N–H···I to give a so-called hybrid structure. Experimental and theoretical optical property investigations indicate that 1 possesses semiconductor properties. A density functional theory calculation was executed to probe the regulation effect on the introduction of a second metal.

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