Fine-Tuning and Selective-Binding within an Anion-Functionalized Ultramicroporous Metal–Organic Framework for Efficient Olefin/Paraffin Separation

2020 ◽  
Vol 12 (36) ◽  
pp. 40229-40235 ◽  
Author(s):  
Zhaoqiang Zhang ◽  
Qi Ding ◽  
Xili Cui ◽  
Xiao-Ming Jiang ◽  
Huabin Xing
Keyword(s):  
Metal Organic Framework ◽  
Fine Tuning ◽  
Selective Binding ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Selective Binding of O2over N2in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites

2011 ◽  
Vol 133 (37) ◽  
pp. 14814-14822 ◽  
Author(s):  
Eric D. Bloch ◽  
Leslie J. Murray ◽  
Wendy L. Queen ◽  
Sachin Chavan ◽  
Sergey N. Maximoff ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Selective Binding ◽  
Coordination Sites ◽  
Redox Active ◽  
Active Metal ◽  
Metal Organic ◽  
Redox Active Metal ◽  
Organic Framework

Fine-Tuning a Robust Metal–Organic Framework toward Enhanced Clean Energy Gas Storage

2021 ◽  
Author(s):  
Zhijie Chen ◽  
Mohammad Rasel Mian ◽  
Seung-Joon Lee ◽  
Haoyuan Chen ◽  
Xuan Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Clean Energy ◽  
Gas Storage ◽  
Fine Tuning ◽  
Metal Organic ◽  
Organic Framework

Fine-tuning metal–organic framework performances by spatially-differentiated postsynthetic modification

2018 ◽  
Vol 6 (10) ◽  
pp. 4260-4265 ◽  
Author(s):  
Hai-Feng Zhang ◽  
Mian Li ◽  
Xue-Zhi Wang ◽  
Dong Luo ◽  
Yi-Fang Zhao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Fine Tuning ◽  
Size Mismatch ◽  
Postsynthetic Modification ◽  
Selective Functionalization ◽  
Diffusion Controlled ◽  
Metal Organic ◽  
Organic Framework ◽  
Spatially Differentiated

In contrast to the regular postsynthetic modification (PSM) approach which is global and random in principle, a diffusion-controlled PSM strategy utilizing size mismatch between pores and reactants has been developed to target selective functionalization and fine-tuning of material performance.

Reversing C2H2–CO2 adsorption selectivity in an ultramicroporous metal–organic framework platform

2019 ◽  
Vol 55 (76) ◽  
pp. 11354-11357 ◽  
Author(s):  
Hui-Min Wen ◽  
Caijun Liao ◽  
Libo Li ◽  
Ling Yang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Binding Sites ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Fine Tuning ◽  
Adsorption Selectivity ◽  
Pore Sizes ◽  
Metal Organic ◽  
Co2 Adsorption Selectivity ◽  
At Will ◽  
Organic Framework

Fine-tuning the pore sizes, metrics, and binding sites within a MOF platform can reverse the adsorption selectivity between C2H2 and CO2 at will.

Fine tuning of the metal–organic framework Cu3(BTC)2 HKUST-1 crystal size in the 100 nm to 5 micron range

2012 ◽  
Vol 22 (27) ◽  
pp. 13742 ◽  
Author(s):  
Lik H. Wee ◽  
Martin R. Lohe ◽  
Nikki Janssens ◽  
Stefan Kaskel ◽  
Johan A. Martens
Keyword(s):  
Crystal Size ◽  
Metal Organic Framework ◽  
Fine Tuning ◽  
Metal Organic ◽  
Organic Framework

Selective binding and removal of guests in a microporous metal–organic framework

Nature ◽  
1995 ◽  
Vol 378 (6558) ◽  
pp. 703-706 ◽  
Author(s):  
O. M. Yaghi ◽  
Guangming Li ◽  
Hailian Li
Keyword(s):  
Metal Organic Framework ◽  
Selective Binding ◽  
Metal Organic ◽  
Organic Framework

Fine-tuning of nano-traps in a stable metal–organic framework for highly efficient removal of propyne from propylene

2018 ◽  
Vol 6 (16) ◽  
pp. 6931-6937 ◽  
Author(s):  
Hui-Min Wen ◽  
Libo Li ◽  
Rui-Biao Lin ◽  
Bin Li ◽  
Bin Hu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Fine Tuning ◽  
Efficient Removal ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A stable MOF material (ZJUT-1) with fine-tuned nanocages, exhibiting the desired size, shape, and functionalities for trapping a single C3H4molecule, can efficiently separate trace amounts of C3H4from a 1/99 C3H4/C3H6mixture.

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