Fine-tuning metal–organic framework performances by spatially-differentiated postsynthetic modification

2018 ◽  
Vol 6 (10) ◽  
pp. 4260-4265 ◽  
Author(s):  
Hai-Feng Zhang ◽  
Mian Li ◽  
Xue-Zhi Wang ◽  
Dong Luo ◽  
Yi-Fang Zhao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Fine Tuning ◽  
Size Mismatch ◽  
Postsynthetic Modification ◽  
Selective Functionalization ◽  
Diffusion Controlled ◽  
Metal Organic ◽  
Organic Framework ◽  
Spatially Differentiated

In contrast to the regular postsynthetic modification (PSM) approach which is global and random in principle, a diffusion-controlled PSM strategy utilizing size mismatch between pores and reactants has been developed to target selective functionalization and fine-tuning of material performance.

Fluorocarbon-Functionalized Superhydrophobic Metal–Organic Framework: Enhanced CO2 Uptake via Photoinduced Postsynthetic Modification

2021 ◽  
Author(s):  
Arpan Hazra ◽  
Satyanarayana Bonakala ◽  
Stephen Adie Adalikwu ◽  
Sundaram Balasubramanian ◽  
Tapas Kumar Maji
Keyword(s):  
Metal Organic Framework ◽  
Co2 Uptake ◽  
Postsynthetic Modification ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal–Organic Framework via Ozonolysis

2018 ◽  
Vol 140 (6) ◽  
pp. 2028-2031 ◽  
Author(s):  
Jorge Albalad ◽  
Heng Xu ◽  
Felipe Gándara ◽  
Mohamed Haouas ◽  
Charlotte Martineau-Corcos ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Postsynthetic Modification ◽  
Metal Organic ◽  
Organic Framework

Postsynthetic Modification of a Metal-Organic Framework (MOF) Structure for Enantioselective Catalytic Epoxidation

ChemPlusChem ◽  
2013 ◽  
Vol 78 (5) ◽  
pp. 443-450 ◽  
Author(s):  
Natalia Candu ◽  
Mădălina Tudorache ◽  
Mihaela Florea ◽  
Elena Ilyes ◽  
Florin Vasiliu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Postsynthetic Modification ◽  
Catalytic Epoxidation ◽  
Metal Organic ◽  
Organic Framework

Fine-Tuning a Robust Metal–Organic Framework toward Enhanced Clean Energy Gas Storage

2021 ◽  
Author(s):  
Zhijie Chen ◽  
Mohammad Rasel Mian ◽  
Seung-Joon Lee ◽  
Haoyuan Chen ◽  
Xuan Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Clean Energy ◽  
Gas Storage ◽  
Fine Tuning ◽  
Metal Organic ◽  
Organic Framework

Development of a novel Brønsted acid UiO-66 metal–organic framework catalyst by postsynthetic modification and its application in catalysis

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 67226-67231 ◽  
Author(s):  
Zongcheng Miao ◽  
Chao Qi ◽  
Allison M. Wensley ◽  
Yi Luan
Keyword(s):  
Metal Organic Framework ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Postsynthetic Modification ◽  
Brönsted Acid ◽  
Metal Organic ◽  
Mbh Reaction ◽  
Organic Framework

A novel Brønsted acid UiO-66 metal–organic framework catalyst has been developed and utilized for efficient acetalization and MBH reaction.

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