Ion Transport in Porous Electrodes Obtained by Impedance Using a Symmetric Cell with Predictable Low-Temperature Battery Performance

2019 ◽  
Vol 10 (17) ◽  
pp. 5013-5018 ◽  
Author(s):  
Nobuhiro Ogihara ◽  
Yuichi Itou ◽  
Shigehiro Kawauchi
2019 ◽  
Vol 2019 ◽  
pp. 1-14
Author(s):  
Changyong Liu ◽  
Junda Tong ◽  
Jun Ma ◽  
Daming Wang ◽  
Feng Xu ◽  
...  

Low-temperature deposition manufacturing (LTDM) is a technology that combines material extrusion-based 3D printing and thermally induced phase separation (TIPS) into one process. With this feature, both the merits of 3D printing and TIPS can be incorporated including complex geometries with tailorable ordered macroporous features facilitated by 3D printing and microporous/nanoporous features endowed by TIPS. These macroporous/microporous/nanoporous combined structures are important to some important applications such as tissue engineering scaffolds, porous electrodes for electrochemical energy storage, purification, and filtering applications. However, the unique advantages and potential applications of LTDM have not been fully recognized and exploited yet. In this review, we will discuss the origin, principle, advantages, processes, and machine setup of LTDM technology with an emphasis on its unique advantages in fabricating porous materials. Then, current applications of LTDM including porous tissue engineering scaffolds and emerging porous electrodes for electrochemical storage will be described. The versatility of LTDM including its capability of processing a wide range of materials, multimaterial and gradient structures, and core-shell structures will be introduced. Finally, we will conclude with a perspective and outlook on the future development and applications of LTDM technology.


2021 ◽  
Vol 505 ◽  
pp. 229917
Author(s):  
Jiwon Yu ◽  
Myungsuk Lee ◽  
Yeonseo Kim ◽  
Hyung-Kyu Lim ◽  
Jonghyun Chae ◽  
...  

Author(s):  
P Rama ◽  
R Chen ◽  
R Thring

With the emerging realization that low temperature, low pressure polymer electrolyte membrane fuel cell (PEMFC) technologies can realistically serve for power-generation of any scale, the value of comprehensive simulation models becomes equally evident. Many models have been successfully developed over the last two decades. One of the fundamental limitations among these models is that up to only three constituent species have been considered in the dry pre-humidified anode and cathode inlet gases, namely oxygen and nitrogen for the cathode and hydrogen, carbon dioxide, and carbon monoxide for the anode. In order to extend the potential of theoretical study and to bring the simulation closer towards reality, in this research, a 1D steady-state, low temperature, isothermal, isobaric PEMFC model has been developed. The model accommodates multi-component diffusion in the porous electrodes and therefore offers the potential to further investigate the effects of contaminants such as carbon monoxide on cell performance. The simulated model polarizations agree well with published experimental data. It opens a wider scope to address the remaining limitations in the future with further developments.


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