Methane Activation by Iron-Carbide Cluster Anions FeC6–

2015 ◽  
Vol 6 (12) ◽  
pp. 2287-2291 ◽  
Author(s):  
Hai-Fang Li ◽  
Zi-Yu Li ◽  
Qing-Yu Liu ◽  
Xiao-Na Li ◽  
Yan-Xia Zhao ◽  
...  
Keyword(s):  
Iron Carbide ◽  
Methane Activation ◽  
Cluster Anions ◽  
Carbide Cluster

Methane Activation by Tantalum Carbide Cluster Anions Ta2C4–

2017 ◽  
Vol 8 (3) ◽  
pp. 605-610 ◽  
Author(s):  
Hai-Fang Li ◽  
Yan-Xia Zhao ◽  
Zhen Yuan ◽  
Qing-Yu Liu ◽  
Zi-Yu Li ◽  
...  
Keyword(s):  
Tantalum Carbide ◽  
Methane Activation ◽  
Cluster Anions ◽  
Carbide Cluster

Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3 − under High-Temperature Conditions

2018 ◽  
Vol 130 (10) ◽  
pp. 2692-2696 ◽  
Author(s):  
Hai-Fang Li ◽  
Li-Xue Jiang ◽  
Yan-Xia Zhao ◽  
Qing-Yu Liu ◽  
Ting Zhang ◽  
...  
Keyword(s):  
High Temperature ◽  
Iron Carbide ◽  
Cluster Anions ◽  
Temperature Conditions ◽  
Carbide Cluster

Formation of Acetylene in the Reaction of Methane with Iron Carbide Cluster Anions FeC3 − under High-Temperature Conditions

2018 ◽  
Vol 57 (10) ◽  
pp. 2662-2666 ◽  
Author(s):  
Hai-Fang Li ◽  
Li-Xue Jiang ◽  
Yan-Xia Zhao ◽  
Qing-Yu Liu ◽  
Ting Zhang ◽  
...  
Keyword(s):  
High Temperature ◽  
Iron Carbide ◽  
Cluster Anions ◽  
Temperature Conditions ◽  
Carbide Cluster

Thermal Methane Activation by La6O10−Cluster Anions

2014 ◽  
Vol 20 (19) ◽  
pp. 5580-5583 ◽  
Author(s):  
Jing-Heng Meng ◽  
Xiao-Jiao Deng ◽  
Zi-Yu Li ◽  
Sheng-Gui He ◽  
Wei-Jun Zheng
Keyword(s):  
Methane Activation ◽  
Cluster Anions

scholarly journals Methane activation by gold-doped titanium oxide cluster anions with closed-shell electronic structures

2016 ◽  
Vol 7 (7) ◽  
pp. 4730-4735 ◽  
Author(s):  
Yan-Xia Zhao ◽  
Xiao-Na Li ◽  
Zhen Yuan ◽  
Qing-Yu Liu ◽  
Qiang Shi ◽  
...  
Keyword(s):  
Titanium Oxide ◽  
Electronic Structures ◽  
Active Sites ◽  
Closed Shell ◽  
Methane Activation ◽  
Cluster Anions ◽  
Oxide Cluster

The complementary active sites of Au+ and O2− ions on gold-doped titanium oxide clusters activate methane under thermal collision conditions.

A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V3C4–

2020 ◽  
Vol 142 (24) ◽  
pp. 10747-10754 ◽  
Author(s):  
Zi-Yu Li ◽  
Yao Li ◽  
Li-Hui Mou ◽  
Jiao-Jiao Chen ◽  
Qing-Yu Liu ◽  
...  
Keyword(s):  
Vanadium Carbide ◽  
Bond Cleavage ◽  
Metal Center ◽  
Cluster Anions ◽  
Carbide Cluster

Consecutive Methane Activation Mediated by Single Metal Boride Cluster Anions NbB4−

2021 ◽  
Author(s):  
Ying Li ◽  
Ming Wang ◽  
Yongqi Ding ◽  
Chongyang Zhao ◽  
Jia-Bi Ma
Keyword(s):  
Mass Spectrometry ◽  
Gas Phase ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Room Temperature ◽  
Methane Activation ◽  
Cluster Ions ◽  
Metal Boride ◽  
Cluster Anions ◽  
Phase Cluster

Cleavage all C−H bonds in two methane molecules by gas-phase cluster ions at room temperature is a challenging task. Herein, mass spectrometry and quantum chemical calculations have been used to...

scholarly journals Construction of Synthetic Models for Nitrogenase-Relevant NifB Biogenesis Intermediates and Iron-Carbide-Sulfide Clusters

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1317
Author(s):  
Chris Joseph ◽  
John Patrick Shupp ◽  
Caitlyn R. Cobb ◽  
Michael J. Rose
Keyword(s):  
Iron Carbide ◽  
Research Groups ◽  
Iron Sulfur Clusters ◽  
Iron Sulfur ◽  
The Family ◽  
Primary Obstacle ◽  
Carbide Cluster ◽  
Sulfide Clusters ◽  
Synthetic Models ◽  
Critical Interest

The family of nitrogenase enzymes catalyzes the reduction of atmospheric dinitrogen (N2) to ammonia under remarkably benign conditions of temperature, pressure, and pH. Therefore, the development of synthetic complexes or materials that can similarly perform this reaction is of critical interest. The primary obstacle for obtaining realistic synthetic models of the active site iron-sulfur-carbide cluster (e.g., FeMoco) is the incorporation of a truly inorganic carbide. This review summarizes the present state of knowledge regarding biological and chemical (synthetic) incorporation of carbide into iron-sulfur clusters. This includes the Nif cluster of proteins and associated biochemistry involved in the endogenous biogenesis of FeMoco. We focus on the chemical (synthetic) incorporation portion of our own efforts to incorporate and modify C1 units in iron/sulfur clusters. We also highlight recent contributions from other research groups in the area toward C1 and/or inorganic carbide insertion.

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