Methane Activation by Tantalum Carbide Cluster Anions Ta2C4–

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The complementary active sites of Au+ and O2− ions on gold-doped titanium oxide clusters activate methane under thermal collision conditions.


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Cleavage all C−H bonds in two methane molecules by gas-phase cluster ions at room temperature is a challenging task. Herein, mass spectrometry and quantum chemical calculations have been used to...


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