Hexagonal Boron Nitride with Designed Nanopores as a High-Efficiency Membrane for Separating Gaseous Hydrogen from Methane

2015 ◽  
Vol 119 (34) ◽  
pp. 19826-19831 ◽  
Author(s):  
Yadong Zhang ◽  
Qi Shi ◽  
Yuzhen Liu ◽  
Yunhui Wang ◽  
Zhaoshun Meng ◽  
...  
2020 ◽  
Vol 116 (14) ◽  
pp. 142102 ◽  
Author(s):  
A. Maity ◽  
S. J. Grenadier ◽  
J. Li ◽  
J. Y. Lin ◽  
H. X. Jiang

2020 ◽  
Vol 10 (5) ◽  
pp. 1248-1255 ◽  
Author(s):  
Lei Wang ◽  
Yang Wang ◽  
Chang-Wu Zhang ◽  
Jing Wen ◽  
Xuefei Weng ◽  
...  

Here, we report a great promotion in platinum utilization efficiency and catalytic performance for the dehydrogenation of propane using a hexagonal boron nitride nanosheet-supported Pt/Cu cluster catalyst.


2022 ◽  
Author(s):  
Xuewen Zheng ◽  
Haifeng Cong ◽  
Ting Yang ◽  
Kemeng Ji ◽  
Chengyang Wang ◽  
...  

Abstract Two-dimensional (2D) materials with mono or few layers have wide application prospects, including electronic, optoelectronic, and interface functional coatings in addition to energy conversion and storage applications. However, the exfoliation of such materials is still challenging due to their low yield, high cost, and poor ecological safety in preparation. Herein, a safe and efficient solid suspension-improving method was proposed to exfoliate hexagonal boron nitride nanosheets (hBNNSs) in a large yield. The method entails adding a permeation barrier layer in the solvothermal kettle, thus prolonging the contact time between the solvent and hexagonal boron nitride (hBN) nanosheetand improving the stripping efficiency without the need for mechanical agitation. In addition, the proposed method selectively utilizes a matching solvent that can reduce the stripping energy of the material and employs a high-temperature steam shearing process. Compared with other methods, the exfoliating yield of hBNNSs is up to 42.3% at 150°C for 12 h, and the strategy is applicable to other 2D materials. In application, the ionic conductivity of a PEO/hBNNSs composite electrolytes reached 2.18×10−4 S cm−1 at 60°C. Overall, a versatile and effective method for stripping 2D materials in addition to a new safe energy management strategy were provided.


Nanoscale ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 2703-2709 ◽  
Author(s):  
Xiangdong Guo ◽  
Hai Hu ◽  
Debo Hu ◽  
Baoxin Liao ◽  
Ke Chen ◽  
...  

Two-dimensional van der Waals (vdW) materials have a full set of highly confined polariton modes, such as low-loss phonon polaritons and dynamically tunable graphene plasmons, which provide a solution for integrated nanophotonic devices by combining the unique advantages of different polaritons.


2019 ◽  
Author(s):  
Matěj Velický ◽  
Sheng Hu ◽  
Colin R. Woods ◽  
Peter S. Toth ◽  
Viktor Zólyomi ◽  
...  

Marcus-Hush theory of electron transfer is one of the pillars of modern electrochemistry with a large body of supporting experimental evidence presented to date. However, some predictions, such as the electrochemical behavior at microdisk electrodes, remain unverified. Herein, we present a study of electron tunneling across a hexagonal boron nitride barrier between a graphite electrode and redox levels in a liquid solution. This was achieved by the fabrication of microdisk electrodes with a typical diameter of 5 µm. Analysis of voltammetric measurements, using two common redox mediators, yielded several electrochemical parameters, including the electron transfer rate constant, limiting current, and transfer coefficient. They show a significant departure from the Butler-Volmer behavior in a clear manifestation of the Marcus-Hush theory of electron transfer. In addition, our system provides a novel experimental platform, which could be applied to address a number of scientific problems such as identification of reaction mechanisms, surface modification, or long-range electron transfer.


Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  

2021 ◽  
Vol 125 (6) ◽  
pp. 1325-1335 ◽  
Author(s):  
Cesar Jara ◽  
Tomáš Rauch ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Ariel Norambuena ◽  
...  

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