Efficient Models for Predicting Temperature-Dependent Henry’s Constants and Adsorption Selectivities for Diverse Collections of Molecules in Metal–Organic Frameworks

2021 ◽  
Author(s):  
Xiaohan Yu ◽  
Sihoon Choi ◽  
Dai Tang ◽  
Andrew J. Medford ◽  
David S. Sholl
Keyword(s):  
Metal Organic Frameworks ◽  
Temperature Dependent ◽  
Henry's Constants ◽  
Metal Organic

Temperature-Dependent Synthesis of Metal-Organic Frameworks Based on a Flexible Tetradentate Ligand with Bidirectional Coordination Donors

2007 ◽  
Vol 129 (15) ◽  
pp. 4520-4521 ◽  
Author(s):  
Yu-Bin Dong ◽  
You-Yun Jiang ◽  
Jie Li ◽  
Jian-Ping Ma ◽  
Feng-Ling Liu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Tetradentate Ligand ◽  
Temperature Dependent ◽  
Metal Organic

scholarly journals Efficient identification of hydrophobic MOFs: application in the capture of toxic industrial chemicals

2016 ◽  
Vol 4 (2) ◽  
pp. 529-536 ◽  
Author(s):  
Peyman Z. Moghadam ◽  
David Fairen-Jimenez ◽  
Randall Q. Snurr
Keyword(s):  
Metal Organic Frameworks ◽  
Large Database ◽  
Industrial Chemicals ◽  
Toxic Industrial Chemicals ◽  
Hydrophobic Materials ◽  
Henry's Constants ◽  
Metal Organic ◽  
Different Levels ◽  
Computational Strategy

A novel and quick computational strategy is developed based on water Henry's constants to distinguish different levels of hydrophobicity among metal–organic frameworks. The technique is applied to a large database of MOFs to identify hydrophobic materials.

Bright blue emissions with temperature-dependent quantum yields from microporous metal–organic frameworks

2012 ◽  
Vol 48 (4) ◽  
pp. 531-533 ◽  
Author(s):  
Qilong Zhu ◽  
Chaojun Shen ◽  
Chunhong Tan ◽  
Tianlu Sheng ◽  
Shengmin Hu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Quantum Yields ◽  
Temperature Dependent ◽  
Metal Organic ◽  
Bright Blue

Temperature-Dependent Structures of Lanthanide Metal–Organic Frameworks Based on Furan-2,5-Dicarboxylate and Oxalate

2012 ◽  
Vol 12 (6) ◽  
pp. 3263-3270 ◽  
Author(s):  
Hao Wang ◽  
Sui-Jun Liu ◽  
Dan Tian ◽  
Ji-Min Jia ◽  
Tong-Liang Hu
Keyword(s):  
Metal Organic Frameworks ◽  
Temperature Dependent ◽  
Metal Organic ◽  
Lanthanide Metal

Thermo-sensitive luminescence of lanthanide complexes, clusters, coordination polymers and metal–organic frameworks with organic photosensitizers

2019 ◽  
Vol 7 (25) ◽  
pp. 7494-7511 ◽  
Author(s):  
Yasuchika Hasegawa ◽  
Yuichi Kitagawa
Keyword(s):  
Coordination Polymers ◽  
Lanthanide Complexes ◽  
Metal Organic Frameworks ◽  
Temperature Dependent ◽  
Mononuclear Complexes ◽  
Recent Advances ◽  
Metal Organic ◽  
Polynuclear Clusters

Historical and recent advances of lanthanide mononuclear complexes, polynuclear clusters, coordination polymers (CPs) and metal–organic frameworks (MOFs) with temperature-dependent luminescence are reviewed for future thermo-sensitive paints.

scholarly journals Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal–organic framework

IUCrJ ◽  
2019 ◽  
Vol 6 (1) ◽  
pp. 85-95 ◽  
Author(s):  
Sujuan Wang ◽  
Zhang-Wen Wei ◽  
Jianyong Zhang ◽  
Long Jiang ◽  
Dingxin Liu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structural Disorder ◽  
Gas Sorption ◽  
Temperature Dependent ◽  
Disordered Structure ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Metal–organic frameworks with highly ordered porosity have been studied extensively. In this paper, the effect of framework (pore) disorder on the gas sorption of azole-based isoreticular Cu(II) MOFs with rtl topology and characteristic 1D tubular pore channels is investigated for the first time. In contrast to other isoreticular rtl metal–organic frameworks, the Cu(II) metal–organic framework based on 5-(1H-imidazol-1-yl)isophthalate acid has a crystallographically identifiable disordered framework without open N-donor sites. The framework provides a unique example for investigating the effect of pore disorder on gas sorption that can be systematically evaluated. It exhibits remarkable temperature-dependent hysteretic CO2 sorption up to room temperature, and shows selectivity of CO2 over H2, CH4 and N2 at ambient temperature. The unique property of the framework is its disordered structure featuring distorted 1D tubular channels and DMF-guest-remediated defects. The results imply that structural disorder (defects) may play an important role in the modification of the performance of the material.

Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks

2015 ◽  
Vol 44 (20) ◽  
pp. 9588-9595 ◽  
Author(s):  
Shanghua Xing ◽  
Guang Zeng ◽  
Xiaomin Liu ◽  
Fen Yang ◽  
Zhiqiang Hao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescent Materials ◽  
Temperature Dependent ◽  
Light Emitting ◽  
Co Doping ◽  
Wide Range ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Co Doped ◽  
Luminescence Behavior

Multifunctional luminescent materials of six Ln-MOFs have been designed and synthesized by the co-doping strategy. Thus a wide range of light emitting spectra and different temperature-dependent luminescence behavior were displayed.

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