scholarly journals Mineralogical Evidence of Galvanic Corrosion in Drinking Water Lead Pipe Joints

2018 ◽  
Vol 52 (6) ◽  
pp. 3365-3374 ◽  
Author(s):  
Michael K. DeSantis ◽  
Simoni Triantafyllidou ◽  
Michael R. Schock ◽  
Darren A. Lytle
2010 ◽  
Vol 8 (3) ◽  
pp. 532-542 ◽  
Author(s):  
Colin R. Hayes

Computational modelling methods have been used to predict the risks from lead in drinking water across a simulated supply zone, for a range of plumbosolvency conditions and a range of extents of occurrence of houses having a lead pipe, on the basis of five risk benchmarking methods. For the worst case modelled (very high plumbosolvency and 90% houses with a lead pipe) the percentage of houses at risk in the simulated zone ranged from 34.1 to 73.3%. In contrast, for a simulated phosphate-treated zone and 10% houses with a lead pipe, the percentage of houses at risk in the simulated zone ranged from 0 to 0.4%. Methods are proposed for using computational modelling for different levels of risk assessment, for both water supply zones and individual houses. These risk assessment methods will inform policy, help to set improvement priorities and facilitate a better understanding of corrective options.


2017 ◽  
Vol 51 (12) ◽  
pp. 6812-6820 ◽  
Author(s):  
Benjamin F. Trueman ◽  
Gregory A. Sweet ◽  
Matthew D. Harding ◽  
Hayden Estabrook ◽  
D. Paul Bishop ◽  
...  

CORROSION ◽  
10.5006/0616 ◽  
2012 ◽  
Vol 68 (11) ◽  
pp. 1037-1048 ◽  
Author(s):  
J. Hu ◽  
F. Gan ◽  
S. Triantafyllidou ◽  
C.K. Nguyen ◽  
M.A. Edwards

The effect of added cupric ions (0 mg/L to 5 mg/L Cu+2) on possible deposition corrosion of lead pipe was investigated in bench-scale experiments under flowing and stagnant water conditions. Under stagnation the presence of cupric ions in the water feeding lead pipes marginally increased lead release into the water, but under continuous recirculation it could increase lead release by orders of magnitude. Other bench-scale experiments investigated galvanic corrosion between lead and copper pipes under stagnation, confirming that water chemistry (particularly the chloride-to-sulfate mass ratio [CSMR]) is a controlling factor in either “strengthening” galvanic corrosion and increasing water lead contamination by orders of magnitude (high CSMR water) or “weakening” the galvanic effect with less but still significant contribution to water lead contamination (low CSMR water). Longitudinal water pH measurements along the length of the galvanic rigs revealed a significant pH drop close to the lead:copper junction at relatively short stagnation times in high CSMR water, which is consistent with the observations of higher lead leaching and higher galvanic current measured in that situation.


2000 ◽  
Vol 15 ◽  
pp. 59-63 ◽  
Author(s):  
Glen R. Boyd ◽  
Neil K. Tarbet ◽  
Roger J. Oliphant ◽  
Gregory J. Kirmeyer ◽  
Brian M. Murphy ◽  
...  

2012 ◽  
Vol 10 (3) ◽  
pp. 337-348 ◽  
Author(s):  
Colin R. Hayes ◽  
Owen D. Hydes

At the zonal scale (e.g. a city or town), random daytime (RDT) sampling succeeded in demonstrating both the need for corrective action and the benefits of optimised orthophosphate dosing for plumbosolvency control, despite initial concerns about sampling reproducibility. Stagnation sampling techniques were found to be less successful. Optimised treatment measures to minimise lead in drinking water, comprising orthophosphate at an optimum dose and at an appropriate pH, have succeeded in raising compliance with the future European Union (EU) lead standard of 10 μg/L from 80.4% in 1989–94 to 99.0% in 2010 across England and Wales, with compliance greater than 99.5% in some regions. There may be scope to achieve 99.8% compliance with 10 μg/L by further optimisation coupled to selective lead pipe removal, without widespread lead pipe removal. It is unlikely that optimised corrosion control, that includes the dosing of orthophosphate, will be capable of achieving a standard much lower than 10 μg/L for lead in drinking water. The experience gained in the UK provides an important reference for any other country or region that is considering its options for minimising lead in their drinking water supplies.


Impact ◽  
2020 ◽  
Vol 2020 (7) ◽  
pp. 50-52
Author(s):  
Ding-Quan Ng ◽  
Yi-Pin Lin

Lead contamination is an example of how elements that leach into drinking water can lead to considerable health problems in local communities. A research team led by Assistant Professor Ding-Quan Ng, from Chaoyang University of Technology, has been investigating the levels of lead found in drinking water in schools. They are also investigating lead release that occurs as a result of galvanic corrosion into potable water. Ng and his colleagues hope to shine a light on the dangers of lead contamination in drinking water supplies and seek to use their findings to promote the establishment of new regulations and policies to improve monitoring of water quality to local needs.


2016 ◽  
Vol 13 (4) ◽  
pp. 602 ◽  
Author(s):  
Ding-Quan Ng ◽  
Yi-Pin Lin

Environmental context Galvanic corrosion has been recently reported as the main cause of lead contamination in drinking water in urban cities. Conditions that can deter or promote galvanic corrosion, however, are not well understood. Fundamental investigations exploring the mechanisms and processes involved in galvanic corrosion in drinking water could help to implement proper corrective measures to safeguard public health from lead contamination. Abstract This study investigates the effects of pH value, chloride and sulfate concentrations on galvanic corrosion between lead and copper in drinking water. We hypothesised that galvanic corrosion would occur immediately when a lead–copper couple is first formed and that the release of lead would be suppressed by the subsequent formation of lead corrosion products. Therefore, unlike previous long-term studies using harvested lead pipes, batch experiments employing high-purity lead and copper (99.9%) wires under stagnant and completely mixed conditions were conducted for a 7-day period to test our hypotheses. It was found that enhanced lead release was indeed observed after the lead–copper couple was formed and the lead profiles after 48h were strongly influenced by lead corrosion products formed in the system. Under stagnant conditions, reducing pH and increasing either chloride or sulfate concentrations promoted lead release, leading to the formation of lead corrosion products such as cerussite and hydrocerussite as experiments proceeded. The effect of chloride concentration on total lead concentration measured in the aqueous phase was similar to that of sulfate at the same molar concentration, showing that the chloride-to-sulfate mass ratio may not provide a good indication for total lead concentration in water. This study provides essential information on fundamental mechanisms and processes involved in galvanic corrosion in drinking water and may be used to explain related phenomena observed in real drinking-water distribution systems.


2008 ◽  
Vol 6 (2) ◽  
pp. 177-185 ◽  
Author(s):  
C. R. Hayes ◽  
S. Incledion ◽  
M. Balch

Dwr Cymru Welsh Water supplies over three million people with drinking water throughout most of Wales (UK). Ortho-phosphate has increasingly been dosed at around 1 mg/L (P) to further reduce the corrosivity of supplies to the lead pipes which connect approximately 30% of houses to water mains in the company's area, additional to long-establish pH adjustment measures. The installation of new ortho-phosphate dosing schemes and the optimisation of these and existing dosing schemes, 29 schemes in total, were subject to a regulatory programme of work, agreed with the Drinking Water Inspectorate (DWI). Optimisation comprised (i) selection of appropriate ortho-phosphate doses by a procedure involving laboratory based plumbosolvency testing linked to zonal lead emission (compliance) modelling, (ii) tight dose control and (iii) extensive monitoring of lead in supply by random daytime (RDT) sampling and by the use of lead pipe test rigs. The successful outcome was confirmed by 99% of over 5,000 RDT samples complying with the future standard of 10 μg/L for lead in drinking water.


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