Fundamental Considerations of Packed-Capillary GC, SFC, and LC Using Nonporous Silica Particles

1997 ◽  
Vol 69 (4) ◽  
pp. 628-635 ◽  
Author(s):  
Yufeng Shen ◽  
Ying J. Yang ◽  
Milton L. Lee
Keyword(s):  
Silica Particles ◽  
Capillary Gc

Quantification of Silica Uptake by Alveolar Macrophages - An Emperical Scanning Electron Microprobe Method

1982 ◽  
Vol 40 ◽  
pp. 332-333
Author(s):  
V. V. Damiano ◽  
R. P. Daniele ◽  
H. T. Tucker ◽  
J. H. Dauber
Keyword(s):  
Quantitative Analysis ◽  
Alveolar Macrophages ◽  
Bulk Sample ◽  
Silica Particles ◽  
Empirical Method ◽  
Phagocytic Cells ◽  
Calibration Standards ◽  
X Ray ◽  
Accurate Quantitative Analysis ◽  
Scanning Electron

An important example of intracellular particles is encountered in silicosis where alveolar macrophages ingest inspired silica particles. The quantitation of the silica uptake by these cells may be a potentially useful method for monitoring silica exposure. Accurate quantitative analysis of ingested silica by phagocytic cells is difficult because the particles are frequently small, irregularly shaped and cannot be visualized within the cells. Semiquantitative methods which make use of particles of known size, shape and composition as calibration standards may be the most direct and simplest approach to undertake. The present paper describes an empirical method in which glass microspheres were used as a model to show how the ratio of the silicon Kα peak X-ray intensity from the microspheres to that of a bulk sample of the same composition correlated to the mass of the microsphere contained within the cell. Irregular shaped silica particles were also analyzed and a calibration curve was generated from these data.

Presence of Phenolic Compounds in Sewage, Effluent and Sludge from Municipal Sewage Treatment Plants

1982 ◽  
Vol 14 (4-5) ◽  
pp. 143-150 ◽  
Author(s):  
F B DeWalle ◽  
D A Kalman ◽  
R Dills ◽  
D Norman ◽  
E S K Chian ◽  
...  
Keyword(s):  
Sewage Treatment ◽  
Municipal Sewage ◽  
Sewage Effluent ◽  
Capillary Gc ◽  
Digested Sludge ◽  
Calculated Concentration ◽  
Sewage Treatment Plants ◽  
Anaerobically Digested Sludge ◽  
Final Effluent ◽  
Dimethyl Phenol

A total of 25 municipal sewage treatment plants were sampled, 10 of which were resampled, to determine the quantity of phenolics in the sewage, final effluent and the anaerobically digested sludge using capillary GC/MS/DS/techniques. The study noted in decreasing order of frequency in raw sewage: phenol, pentachloro-phenol, dimethyl phenol, 3-methyl, 4-chlorophenol, 2,4,6-trichloro-phenol, 2,4-dichlorophenol, 2-nitrophenol, 2-chlorophenol, 2,4-dinitro-6-methylphenol and 2,4-dinitrophenol. The maximum concentration of phenol in sewage and sludge was 2800 ppb and 4460 respectively, while similar values for pentachlorophenol were 58 and 1200 ppb. Statistically calculated concentration reductions for phenol and dimethyl phenol were generally greater than noted for tri- and pentachlorophenol. Low decreases or increases were noted for monochlorophenol and especially for dichlorophenol as a result of the chloronation of the final effluent.

Simulation of production of hollow silica particles in a plasma flow. Part 2. Hollow particle production dynamics

2020 ◽  
Vol 27 (4) ◽  
pp. 595-605
Author(s):  
V. A. Arkhipov ◽  
V. D. Goldin ◽  
V. V. Shekhovtsov ◽  
O. G. Volokitin ◽  
A. S. Anshakov ◽  
...  
Keyword(s):  
Plasma Flow ◽  
Particle Production ◽  
Silica Particles ◽  
Hollow Particle ◽  
Hollow Silica ◽  
Flow Part ◽  
Production Dynamics ◽  
Hollow Silica Particles

Screening and quantification of hypnotic sedatives in serum by capillary gas chromatography with a nitrogen-phosphorus detector, and confirmation by capillary gas chromatography-mass spectrometry.

1986 ◽  
Vol 32 (2) ◽  
pp. 325-328 ◽  
Author(s):  
V A Soo ◽  
R J Bergert ◽  
D G Deutsch
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Capillary Gas Chromatography ◽  
Gas Chromatography Mass Spectrometry ◽  
Detector Response ◽  
Capillary Gc ◽  
Chromatography Mass Spectrometry ◽  
Nitrogen Phosphorus Detector ◽  
Sedative Drugs ◽  
Nitrogen Phosphorus

Abstract We describe a quantitative screen for hypnotic-sedative drugs in which we use capillary gas chromatography with a nitrogen-phosphorus detector (GC/NPD) as the primary method and capillary gas chromatography-mass spectrometry (GC-MS) for confirmation. GC retention times of the acid-extracted underivatized drugs were stable (CVs less than 1%), and the detector response varied linearly over a 20-fold concentration range with a mean correlation coefficient for 11 drugs of 0.989. The limits of detection were satisfactory (0.5 mg/L in a 0.5-mL serum sample and 1-microL injection volume), as were precision (average CV 5.2% within day, 6.4% between day). The complementary use of capillary GC-MS not only unambiguously confirms presumptive peaks identified by GC, but also prevents reports of false positives and identifies compounds not included in the quantitative GC screen that may be listed in the GC-MS library.

Mechanical Property Improvement of Poly(Butylene Succinate) by Reinforcing with Modified Fumed Silica

2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Fumed Silica ◽  
Tensile Modulus ◽  
Silica Particles ◽  
Melt Mixing ◽  
Butylene Succinate ◽  
Ir Spectrophotometry

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.

scholarly journals Design, synthesis, and catalytic performance of modified graphene oxide based on a cobalt complex as a heterogenous catalyst for the preparation of aminonaphthoquinone derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (28) ◽  
pp. 17108-17115
Author(s):  
Mahnaz Mirheidari ◽  
Javad Safaei-Ghomi
Keyword(s):  
Graphene Oxide ◽  
Cobalt Complex ◽  
Catalytic Performance ◽  
Silica Particles ◽  
Design Synthesis ◽  
Spherical Silica ◽  
Modified Graphene Oxide ◽  
Spherical Silica Particles ◽  
Heterogenous Catalyst ◽  
Modified Graphene

GO@f-SiO2@Co is a heterogenous catalyst composed of spherical silica particles grafted on the surface of graphene oxide with ethylenediamine ligands and coordination with Co(ii). We assessed the activity of the catalyst for the synthesis of aminonaphthoquinones.

Sign in / Sign up

Export Citation Format

Share Document