Gas chromatographic determination of hydrogen, oxygen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia, water, and C1 through C5 saturated hydrocarbons in refinery gases

1967 ◽  
Vol 39 (14) ◽  
pp. 1858-1860 ◽  
Author(s):  
Caroline N. Jones
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Sulfide ◽  
Chromatographic Determination ◽  
Saturated Hydrocarbons ◽  
Ammonia Water ◽  
Refinery Gases

Gas-Solid Chromatographic Determination of Carbon Monoxide and Carbon Dioxide in Cigarette Smoke

1974 ◽  
Vol 57 (1) ◽  
pp. 1-7
Author(s):  
Arthur D Horton ◽  
Michael R Guerin
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Gas Phase ◽  
Confidence Intervals ◽  
Cigarette Smoke ◽  
Chromatographic Determination ◽  
Standard Errors ◽  
Sampling Techniques ◽  
Relative Standard

Abstract Gas-solid chromatographic methods are presented for the determination of carbon monoxide, carbon dioxide, or both simultaneously in the gas phase of cigarette smoke. The methods are optimized to allow quantitative determinations on the entire gas phase delivery of the cigarettes rather than single puffs and to allow the use of small numbers of cigarettes. Shortcomings of several sampling techniques are defined, and evidence is presented supporting the utility of Saran bag sampling and containment. Carbon monoxide and carbon dioxide analyses may be performed with relative standard errors of 2—3% and relative confidence intervals (95%) of 6—9% for determinations involving 4—6 cigarettes.

Conductimetric Gas Separation-Flow Injection Determination of Ammonia in Gaseous Process Streams

1997 ◽  
Vol 62 (4) ◽  
pp. 609-619 ◽  
Author(s):  
Vlastimil Kubáň
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Sulfide ◽  
Sulfur Dioxide ◽  
Hydrogen Cyanide ◽  
Separation Flow ◽  
Ammonia Content ◽  
Process Gas ◽  
Capillary Membrane

Ammonia (up to 0.3 vol.%) can be determined (RSDs < 2%) after separation from a process gas stream containing (vol.%): carbon dioxide (0.3-20), hydrogen sulfide (< 0.4), hydrogen cyanide (< 1.5 . 10-4), sulfur dioxide (1), carbon monoxide (< 3) in 50-90 vol.% nitrogen and hydrocarbons. The ammonia content in sample is determined through changes in the conductivity of an acceptor stream (3 mM boric acid) caused by absorption of the analyte passed through a Nafion capillary membrane.

RUMEN GAS ANALYSIS BY GAS-SOLID CHROMATOGRAPHY

1961 ◽  
Vol 41 (2) ◽  
pp. 187-196 ◽  
Author(s):  
J. M. McArthur ◽  
J. E. Miltimore
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Hydrogen Sulphide ◽  
Sample Volume ◽  
Gas Analysis ◽  
Complete Analysis ◽  
Thermal Detector ◽  
Thermal Detection ◽  
Methane Carbon

Methods are described for sampling and analysing rumen gases. The analysis requires less than 15 minutes for the determination of hydrogen, oxygen, nitrogen, methane, carbon monoxide, carbon dioxide, and hydrogen sulphide, i.e., for all gases occurring in the rumen. The method is sensitive and requires only a small quantity of sample, and the sample volume need not be known. The presence of water or other vapours in the sample does not influence the results. Relative thermal detector responses have been determined for gases which occur in the rumen. These eliminate the necessity for the calibration of gas chromatographs using thermal detection. The first complete analysis of rumen gas is presented.

scholarly journals The Use of Cryogenic Temperature Gas Chromatography for the Determination of Carbon Monoxide and Carbon Dioxide in Cigarette Smoke

1972 ◽  
Vol 6 (4) ◽  
Author(s):  
G.P. Morie ◽  
C.H. Sloan
Keyword(s):  
Carbon Dioxide ◽  
Gas Chromatography ◽  
Carbon Monoxide ◽  
Liquid Nitrogen ◽  
Cigarette Smoke ◽  
Cryogenic Temperature ◽  
Chromatographic Method ◽  
Porapak Q ◽  
Gas Chromatographic Method

AbstractA gas chromatographic method for the determination of carbon monoxide and carbon dioxide in cigarette smoke was developed. A column containing Porapak Q packing and a cryogenic temperature programmer which employed liquid nitrogen to cool the column to subambient temperatures was used. The separation of N

Gas-Solid Chromatographic Determination of Oxygen, Nitrogen, Carbon Dioxide, Ethylene, and Nitrous Oxide at Ambient Temperature

1973 ◽  
Vol 56 (1) ◽  
pp. 119-123
Author(s):  
Martin J Finkelson
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Ambient Temperature ◽  
Molecular Sieve ◽  
Internal Standard ◽  
Chromatographic Determination ◽  
Digital Integrator ◽  
In Series ◽  
Peak Areas

Abstract A gas-solid chromatographic method is described for the separation and determination of 5 medicinal gases at ambient temperature, using 2 gas chromatographic columns, Porapak Q and Molecular Sieve 13X, operated in series with a 6-port thermal conductivity detector and I recorder. An electronic digital integrator is used for calculating peak areas. Data on retention time, linearity, reproducibility of injection, and comparison with absorption methods are presented. Analytical results for oxygen, nitrogen, carbon dioxide, ethylene, and nitrous oxide are attainable within 1.0% without the use of an internal standard.

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