Quantitative application of principal component analysis and self-modeling spectral resolution to product analysis of tetraphenylethylene photochemical reactions

1993 ◽  
Vol 65 (23) ◽  
pp. 3460-3465 ◽  
Author(s):  
Christopher E. Bunker ◽  
Norwood B. Hamilton ◽  
Ya Ping. Sun
2019 ◽  
Vol 11 (22) ◽  
pp. 2710 ◽  
Author(s):  
Sihui Fan ◽  
Wei Han ◽  
Zhiqiu Gao ◽  
Ruoying Yin ◽  
Yu Zheng

The Geostationary Interferometric Infrared Sounder (GIIRS) is the first high-spectral resolution advanced infrared (IR) sounder onboard the new-generation Chinese geostationary meteorological satellite FengYun-4A (FY-4A). The GIIRS has 1650 channels, and its spectrum ranges from 700 to 2250 cm−1 with an unapodized spectral resolution of 0.625 cm−1. It represents a significant breakthrough for measurements with high temporal, spatial and spectral resolutions worldwide. Many GIIRS channels have quite similar spectral signal characteristics that are highly correlated with each other in content and have a high degree of information redundancy. Therefore, this paper applies a principal component analysis (PCA)-based denoising algorithm (PDA) to study simulation data with different noise levels and observation data to reduce noise. The results show that the channel reconstruction using inter-channel spatial dependency and spectral similarity can reduce the noise in the observation brightness temperature (BT). A comparison of the BT observed by the GIIRS (O) with the BT simulated by the radiative transfer model (B) shows that a deviation occurs in the observation channel depending on the observation array. The results show that the array features of the reconstructed observation BT (rrO) depending on the observation array are weakened and the effect of the array position on the observations in the sub-center of the field of regard (FOR) are partially eliminated after the PDA procedure is applied. The high observation and simulation differences (O-B) in the sub-center of the FOR array notably reduced after the PDA procedure is implemented. The improvement of the high O-B is more distinct, and the low O-B becomes smoother. In each scan line, the standard deviation of the reconstructed background departures (rrO-B) is lower than that of the background departures (O-B). The observation error calculated by posterior estimation based on variational assimilation also verifies the efficiency of the PDA. The typhoon experiment also shows that among the 29 selected assimilation channels, the observation error of 65% of the channels was reduced as calculated by the triangle method.


VASA ◽  
2012 ◽  
Vol 41 (5) ◽  
pp. 333-342 ◽  
Author(s):  
Kirchberger ◽  
Finger ◽  
Müller-Bühl

Background: The Intermittent Claudication Questionnaire (ICQ) is a short questionnaire for the assessment of health-related quality of life (HRQOL) in patients with intermittent claudication (IC). The objective of this study was to translate the ICQ into German and to investigate the psychometric properties of the German ICQ version in patients with IC. Patients and methods: The original English version was translated using a forward-backward method. The resulting German version was reviewed by the author of the original version and an experienced clinician. Finally, it was tested for clarity with 5 German patients with IC. A sample of 81 patients were administered the German ICQ. The sample consisted of 58.0 % male patients with a median age of 71 years and a median IC duration of 36 months. Test of feasibility included completeness of questionnaires, completion time, and ratings of clarity, length and relevance. Reliability was assessed through a retest in 13 patients at 14 days, and analysis of Cronbach’s alpha for internal consistency. Construct validity was investigated using principal component analysis. Concurrent validity was assessed by correlating the ICQ scores with the Short Form 36 Health Survey (SF-36) as well as clinical measures. Results: The ICQ was completely filled in by 73 subjects (90.1 %) with an average completion time of 6.3 minutes. Cronbach’s alpha coefficient reached 0.75. Intra-class correlation for test-retest reliability was r = 0.88. Principal component analysis resulted in a 3 factor solution. The first factor explained 51.5 of the total variation and all items had loadings of at least 0.65 on it. The ICQ was significantly associated with the SF-36 and treadmill-walking distances whereas no association was found for resting ABPI. Conclusions: The German version of the ICQ demonstrated good feasibility, satisfactory reliability and good validity. Responsiveness should be investigated in further validation studies.


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