scholarly journals Thermal fluctuations in capillary thinning of thin liquid films

2019 ◽  
Vol 876 ◽  
pp. 1090-1107 ◽  
Author(s):  
Maulik S. Shah ◽  
Volkert van Steijn ◽  
Chris R. Kleijn ◽  
Michiel T. Kreutzer

Thermal fluctuations have been shown to influence the thinning dynamics of planar thin liquid films, bringing predicted rupture times closer to experiments. Most liquid films in nature and industry are, however, non-planar. Thinning of such films not just results from the interplay between stabilizing surface tension forces and destabilizing van der Waals forces, but also from drainage due to curvature differences. This work explores the influence of thermal fluctuations on the dynamics of thin non-planar films subjected to drainage, with their dynamics governed by two parameters: the strength of thermal fluctuations, $\unicode[STIX]{x1D703}$, and the strength of drainage, $\unicode[STIX]{x1D705}$. For strong drainage ($\unicode[STIX]{x1D705}\gg \unicode[STIX]{x1D705}_{tr}$), we find that the film ruptures due to the formation of a local depression called a dimple that appears at the connection between the curved and flat parts of the film. For this dimple-dominated regime, the rupture time, $t_{r}$, solely depends on $\unicode[STIX]{x1D705}$, according to the earlier reported scaling, $t_{r}\sim \unicode[STIX]{x1D705}^{-10/7}$. By contrast, for weak drainage ($\unicode[STIX]{x1D705}\ll \unicode[STIX]{x1D705}_{tr}$), the film ruptures at a random location due to the spontaneous growth of fluctuations originating from thermal fluctuations. In this fluctuations-dominated regime, the rupture time solely depends on $\unicode[STIX]{x1D703}$ as $t_{r}\sim -(1/\unicode[STIX]{x1D714}_{max})\ln (\sqrt{2\unicode[STIX]{x1D703}})^{\unicode[STIX]{x1D6FC}}$, with $\unicode[STIX]{x1D6FC}=1.15$. This scaling is rationalized using linear stability theory, which yields $\unicode[STIX]{x1D714}_{max}$ as the growth rate of the fastest-growing wave and $\unicode[STIX]{x1D6FC}=1$. These insights on if, when and how thermal fluctuations play a role are instrumental in predicting the dynamics and rupture time of non-flat draining thin films.

Author(s):  
Adam M. Willis ◽  
Jonathan B. Freund

It has been suggested that stochastic thermal fluctuations directly affect the dynamics and stability of thin liquid films. We investigate this by comparing atomistic simulations of spreading drops with predictions from stochastically forced lubrication equations. Initially the drops spread according to Tanner’s law, l ∼ t1/7, but then accelerate as predicted for cases where fluctuating thermal stresses govern the process.


2007 ◽  
Vol 571 ◽  
pp. 33-57 ◽  
Author(s):  
RICHARD D. LENZ ◽  
SATISH KUMAR

The behaviour of the interface between stratified thin liquid films bounded by parallel solid surfaces and subject to van der Waals forces which drive dewetting is studied in this work. Chemically homogeneous surfaces are considered first; this is followed by an investigation of chemically heterogeneous surfaces. The lubrication approximation is applied to obtain a single nonlinear evolution equation which describes the interfacial behaviour, and both the linear stability and nonlinear development of the interface are examined. The sensitivity of the interfacial rupture time to problem parameters such as the viscosity ratio, initial interfacial height, interfacial tension, and magnitude of the van der Waals forces is characterized in detail for the homogeneous case. This serves as a basis for a study of the heterogeneous case, where the strong dependence of the rupture time on the length scale of the heterogeneity is found to be relatively independent of changes in the remaining problem parameters. The mechanisms underlying the rupture-time behaviour are also explored in detail. The results suggest a route by which one liquid can become emulsified in the other, and may be beneficial to industrial processes such as lithographic printing which are based on wettability phenomena.


1983 ◽  
Vol 23 ◽  
Author(s):  
Eli Yablonovitch ◽  
T. Gmitter

ABSTRACTThe behaviour of thin liquid films is known to be dominated by surface tension forces. We show that the crystallization of thin liquid films requires that two wetting angle conditions be simultaneously satisfied: (i) relating to the liquid–vapour interface and (ii) relating to the crystal–liquid interface. The balance between capillary pressure and thermal gradient forces shows that the equilibrium freezing point of thin films is actually depressed below the bulk freezing point. The magnitude of the effect is 1°K in an 800 Å thick film. These observations suggest that small–scale thickness fluctuations may be responsible for the initiation of sub–grain boundaries in the growth of crystalline silicon films.


2015 ◽  
Vol 778 ◽  
pp. 1-4 ◽  
Author(s):  
J. Bico

The rupture of soap films is traditionally described by a law accounting for a balance between momentum and surface tension forces, derived independently by Taylor and Culick in the 1960s. This law is highly relevant to the dynamics of thin liquid films of jets when viscous effects are negligible. However, the minute amounts of surfactant molecules present in soap films play a major role in interfacial rheology, and may result in complex behaviour. Petit et al. (J. Fluid Mech., vol. 774, 2015, R3) challenge standard thin film dynamics via intriguing experiments conducted with highly elastic surfactants. Unexpected structures reminiscent of faults are observed.


Author(s):  
Hongyi Yu ◽  
Karsten Loffler ◽  
Tatiana Gambaryan-Roisman ◽  
Peter Stephan

2019 ◽  
Vol 4 (3) ◽  
Author(s):  
Mariana Rodríguez-Hakim ◽  
Joseph M. Barakat ◽  
Xingyi Shi ◽  
Eric S. G. Shaqfeh ◽  
Gerald G. Fuller

AIP Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 045317
Author(s):  
Ali Mohammadtabar ◽  
Hadi Nazaripoor ◽  
Adham Riad ◽  
Arman Hemmati ◽  
Mohtada Sadrzadeh

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