Wetting Angles and Surface Tension in the Crystallization of Thin Liquid Films

1983 ◽  
Vol 23 ◽  
Author(s):  
Eli Yablonovitch ◽  
T. Gmitter

ABSTRACTThe behaviour of thin liquid films is known to be dominated by surface tension forces. We show that the crystallization of thin liquid films requires that two wetting angle conditions be simultaneously satisfied: (i) relating to the liquid–vapour interface and (ii) relating to the crystal–liquid interface. The balance between capillary pressure and thermal gradient forces shows that the equilibrium freezing point of thin films is actually depressed below the bulk freezing point. The magnitude of the effect is 1°K in an 800 Å thick film. These observations suggest that small–scale thickness fluctuations may be responsible for the initiation of sub–grain boundaries in the growth of crystalline silicon films.

2015 ◽  
Vol 778 ◽  
pp. 1-4 ◽  
Author(s):  
J. Bico

The rupture of soap films is traditionally described by a law accounting for a balance between momentum and surface tension forces, derived independently by Taylor and Culick in the 1960s. This law is highly relevant to the dynamics of thin liquid films of jets when viscous effects are negligible. However, the minute amounts of surfactant molecules present in soap films play a major role in interfacial rheology, and may result in complex behaviour. Petit et al. (J. Fluid Mech., vol. 774, 2015, R3) challenge standard thin film dynamics via intriguing experiments conducted with highly elastic surfactants. Unexpected structures reminiscent of faults are observed.


2016 ◽  
Vol 792 ◽  
pp. 168-185 ◽  
Author(s):  
Andreas Hadjittofis ◽  
John R. Lister ◽  
Kiran Singh ◽  
Dominic Vella

We consider the effect of evaporation on the aggregation of a number of elastic objects due to a liquid’s surface tension. In particular, we consider an array of spring–block elements in which the gaps between blocks are filled by thin liquid films that evaporate during the course of an experiment. Using lubrication theory to account for the fluid flow within the gaps, we study the dynamics of aggregation. We find that a non-zero evaporation rate causes the elements to aggregate more quickly and, indeed, to contact within finite time. However, we also show that the final number of elements within each cluster decreases as the evaporation rate increases. We explain these results quantitatively by comparison with the corresponding two-body problem and discuss their relevance for controlling pattern formation in elastocapillary systems.


AIChE Journal ◽  
1971 ◽  
Vol 17 (5) ◽  
pp. 1166-1173 ◽  
Author(s):  
V. Ludviksson ◽  
E. N. Lightfoot

1980 ◽  
Vol 101 (1) ◽  
pp. 33-51 ◽  
Author(s):  
M. Foda ◽  
R. G. Cox

The spreading on a water–air interface of a thin liquid film is examined for the situation in which surface tension gradients drive the motion. A similarity solution is obtained numerically for unidirectional spreading when some general restrictions concerning the form of the liquid film constitutive relation is made. This solution gives the size of the film as a function of time and also the velocity and thickness distribution along the spreading film. Experiments are performed which show good agreement with the theory.


2019 ◽  
Vol 876 ◽  
pp. 1090-1107 ◽  
Author(s):  
Maulik S. Shah ◽  
Volkert van Steijn ◽  
Chris R. Kleijn ◽  
Michiel T. Kreutzer

Thermal fluctuations have been shown to influence the thinning dynamics of planar thin liquid films, bringing predicted rupture times closer to experiments. Most liquid films in nature and industry are, however, non-planar. Thinning of such films not just results from the interplay between stabilizing surface tension forces and destabilizing van der Waals forces, but also from drainage due to curvature differences. This work explores the influence of thermal fluctuations on the dynamics of thin non-planar films subjected to drainage, with their dynamics governed by two parameters: the strength of thermal fluctuations, $\unicode[STIX]{x1D703}$, and the strength of drainage, $\unicode[STIX]{x1D705}$. For strong drainage ($\unicode[STIX]{x1D705}\gg \unicode[STIX]{x1D705}_{tr}$), we find that the film ruptures due to the formation of a local depression called a dimple that appears at the connection between the curved and flat parts of the film. For this dimple-dominated regime, the rupture time, $t_{r}$, solely depends on $\unicode[STIX]{x1D705}$, according to the earlier reported scaling, $t_{r}\sim \unicode[STIX]{x1D705}^{-10/7}$. By contrast, for weak drainage ($\unicode[STIX]{x1D705}\ll \unicode[STIX]{x1D705}_{tr}$), the film ruptures at a random location due to the spontaneous growth of fluctuations originating from thermal fluctuations. In this fluctuations-dominated regime, the rupture time solely depends on $\unicode[STIX]{x1D703}$ as $t_{r}\sim -(1/\unicode[STIX]{x1D714}_{max})\ln (\sqrt{2\unicode[STIX]{x1D703}})^{\unicode[STIX]{x1D6FC}}$, with $\unicode[STIX]{x1D6FC}=1.15$. This scaling is rationalized using linear stability theory, which yields $\unicode[STIX]{x1D714}_{max}$ as the growth rate of the fastest-growing wave and $\unicode[STIX]{x1D6FC}=1$. These insights on if, when and how thermal fluctuations play a role are instrumental in predicting the dynamics and rupture time of non-flat draining thin films.


1991 ◽  
Vol 3 (5) ◽  
pp. 733-742 ◽  
Author(s):  
J. A. Moriarty ◽  
L. W. Schwartz ◽  
E. O. Tuck

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