Properties of low power spark ablation in aqueous solution for dissolution of precious metals and alloys

2006 ◽  
Vol 61 (7) ◽  
pp. 817-823 ◽  
Author(s):  
Douglas Goltz ◽  
Michael Boileau ◽  
Ian Plews ◽  
Kimberly Charleton ◽  
Michael W. Hinds
2021 ◽  
Vol 445 ◽  
pp. 214072
Author(s):  
Ziyong Chang ◽  
Liang Zeng ◽  
Chunbao Sun ◽  
Peng Zhao ◽  
Jiayu Wang ◽  
...  

2020 ◽  
Vol 4 (1) ◽  
pp. 8 ◽  
Author(s):  
Shunya Yamamoto ◽  
Hiroshi Koshikawa ◽  
Tomitsugu Taguchi ◽  
Tetsuya Yamaki

Ion-track-etched capillaries containing nanoparticles of precious metals (e.g., Pt, Au, and Ag) can be applied to plasmonic absorber materials. The precipitation of homogeneous and highly dispersed precious metal nanoparticles inside capillaries represents a key process. Ion-track-etched capillaries (diameter: ~500 nm, length: ~25 μm) were created in polyimide film by 350 MeV Xe irradiation (3 × 107 ions/cm2) and chemical etching (using a sodium hypochlorite solution). The films with capillaries were immersed in an aqueous solution containing 0.1–10 mmol/L H2PtCl6 and 0.5 vol% C2H5OH, and then irradiated with a 2 MeV electron beam up to a fluence of 1.4 × 1016 e/cm2. The Pt particles inside the capillaries were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The precipitation of Pt nanoparticles and isolated aggregates inside the capillaries was confirmed by TEM. The Pt nanoparticles tended to aggregate under increasing concentrations of H2PtCl6 in the aqueous solution; meanwhile, no changes in nanoparticle size were noted under increasing electron beam fluence. The results suggest that the proposed method can be used to form metal nanoparticles in nanosized capillaries with a high aspect ratio.


2015 ◽  
Vol 276 ◽  
pp. 186-194 ◽  
Author(s):  
Alexandre Ma ◽  
Frédéric Rousseau ◽  
Frédérique Donsanti ◽  
Daniel Lincot ◽  
Daniel Morvan

RSC Advances ◽  
2016 ◽  
Vol 6 (110) ◽  
pp. 108689-108696 ◽  
Author(s):  
Huseyin Akbulut ◽  
Shuhei Yamada ◽  
Takeshi Endo

l-Cysteine-grafted polystyrene was synthesized from a cysteine-styrene monomer (Cys-Sty) in aqueous solution and used as a facile and selective high-recovery material for palladium(ii), platinum(iv), and gold(iii) ions from aqueous media.


2020 ◽  
Vol 21 (1) ◽  
pp. 251
Author(s):  
Mellia Harumi ◽  
Rian Kurniawan ◽  
Agustiwandina Saputri ◽  
Dian Hanna Saraswati ◽  
Meissha Ayu Ardini ◽  
...  

Electronic waste (e-waste) has been confirmed containing some precious metals such as gold and silver. Mangosteen peel waste as eco-friendly adsorbent has been studied to recover Au(III) and Ag(I) successfully. Recovery was started through adsorbent preparation, consisting of soxhlet extraction and maceration. About 100 mg of adsorbent was dispersed into Au(III) and Ag(I) solutions in various pH conditions (2–6). The result proves that the optimum adsorptions of Au(III) and Ag(I) are at pH 2 and pH 6, respectively. Au(III) adsorption follows the isotherm model of Langmuir with a maximum capacity of 0.580 mmol/g (114.27 mg/g). Ag(I) adsorption follows the isotherm model of Freundlich with a maximum capacity of 0.511 mmol/g (55.10 mg/g).


1982 ◽  
Vol 47 (1) ◽  
pp. 3-30 ◽  
Author(s):  
Heather Lechtman ◽  
Antonieta Erlij ◽  
Edward J. Barry

The metal objects found in 1969 at the north Peruvian site of Loma Negra, in the region of Cerro Vicús, form one of the largest and most important single groups of Moche metal artifacts known. Since the objects were looted from burials at the site, they are without context, seriously compounding the problems of their relative chronology within the Moche sequence and of their relations with Moche material from the coast farther to the south. Metallurgical studies of a group of gilt copper objects from Loma Negra have shown that the gilding was achieved by an electrochemical replacement plating process in which gold and silver are dissolved in an aqueous solution of corrosive minerals. The precious metals are then plated from solution onto the copper objects. Moche metal craftsmen can now be credited with having developed the two most sophisticated of Andean gilding procedures: depletion gilding and electrochemical replacement plating.


Sign in / Sign up

Export Citation Format

Share Document