Development of a fluorescent chelating ligand for scandium ion having a Schiff base moiety

2012 ◽  
Vol 90 ◽  
pp. 72-77 ◽  
Author(s):  
Hiroshi Yamada ◽  
Masahito Kojo ◽  
Tomomi Nakahara ◽  
Kumi Murakami ◽  
Takashi Kakima ◽  
...  
Keyword(s):  
Schiff Base ◽  
Chelating Ligand ◽  
Base Moiety

Synthesis, Characterization and Biological Activity of Nitrogen­ Oxygen-Sulfur (NOS) Transition Metal Complexes Derived from Novel S-2,4-dichlorobenzyldithiocarbazate with 5-fluoroisatin

2010 ◽  
Vol 7 (2) ◽  
pp. 67
Author(s):  
Mohd Abdul Fatah Abdul Manan ◽  
Hadariah Bahron ◽  
Karimah Kassim ◽  
Mohd Asrul Hafaz Mohamad ◽  
Syed Nazmi Sayed Mohamad
Keyword(s):  
Bacillus Subtilis ◽  
Schiff Base ◽  
Metal Complexes ◽  
Condensation Reaction ◽  
Schiff Base Complex ◽  
Inhibition Zone ◽  
Azomethine Nitrogen ◽  
Strong Activity ◽  
Chelating Ligand ◽  
Physico Chemical

A novel Schiff base containing nitrogen-oxygen-sulfur (NOS) donor atoms formed from the condensation reaction of S-2,4-dichlorobenzyldithiocarbazate (S-2,4BDTC) with 5-fluroisatin has been synthesized. Complexes of cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) with this Schiff base have been prepared and characterized using elemental analysis and various physico-chemical techniques. In the cobalt(II) and nickel(II) complexes the Schiff base behaves as a uninegatively charged tridentate nitrogen-oxygen-sulfur (NOS) chelating ligand, bonding through the azomethine nitrogen, thiolate sulfur and carbonylic oxygen of the isatin moiety. However, in the copper(II), zinc(II) and cadmium(II) complexes the Schiff base behaves as a nitrogen-sulfur (NS) bidentate chelating ligand, bonding through the azomethine nitrogen and thiolate sulfur. The Schiff base and the metal complexes were evaluated with respect to antimicrobial activity, which was performed in relation to two selected pathogenic microbials (Bacillus subtilis and Pseudomonas aeruginosa). It was observed that only the zinc Schiff base complex exhibited strong activity against the Bacillus subtilis bacteria with an inhibition zone of 25 mm. 

Synthesis, Characterization and Biological Activity of NitrogenOxygen-Sulfur (NOS) Transition Metal Complexes Derived from Novel S-2,4-dichlorobenzyldithiocarbazate with 5-fluoroisatin

2010 ◽  
Vol 7 (2) ◽  
pp. 67
Author(s):  
Mohd Abdul Fatah Abdul Manan ◽  
Hadariah Bahron ◽  
Karimah Kassim ◽  
Mohd Asrul Hafiz Muhamad ◽  
Syed Nazmi Sayed Mohamad
Keyword(s):  
Bacillus Subtilis ◽  
Schiff Base ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Condensation Reaction ◽  
Inhibition Zone ◽  
Azomethine Nitrogen ◽  
Strong Activity ◽  
Chelating Ligand ◽  
Physico Chemical

A novel Schiff base containing nitrogen-oxygen-sulfur (NOS) donor atoms formed from the condensation reaction of S-2,4- dichlorobenzyldithiocarbazate (S-2.4BDTC) with 5-fluroisatin has been synthesized. Complexes of cobalt(ll), nickel(ll), copper(ll), zinc(ll) and cadmium(ll) with this Schiff base have been prepared and characterized using elemental analysis and various physico-chemical techniques. In the cobalt(ll) and nickel(II) complexes the SchifJbase behaves as a uninegatively charged tridentate nitrogen-oxygen-sulfur (NOS) chelating ligand, bonding through the azomethine nitrogen, thiolate sulfur and carbonylic oxygen of the isatin moiety. However. in the copper(ll), zinc(II) and cadmium(II) complexes the Schiff base behaves as a nitrogen-sulfur (NS) bidentate chelating ligand, bonding through the azomethine nitrogen and thiolate sulfur. The Schiff base and the metal complexes were evaluated with respect to antimicrobial activity, which was performed in reallion to two selected pathogenic microbials (Bacillus subtilis and Pseudomonas aeruginosa). It was observed that only the zinc Schiffbase complex exhibited strong activity against the Bacillus subtilis bacteria with an inhibition zone of25 mm.

scholarly journals Synthesis, Characterization, and Electrochemical Behaviour of Cobalt(II) and Nickel(II) Complexes with N2O2 Chelating Ligand 4,4′-(Biphenyl-4,4′-diyldinitrilo)dipentan-2-one

2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
Lakhdar Sibous ◽  
Embarek Bentouhami ◽  
Mustayeen Ahmed Khan
Keyword(s):  
Schiff Base ◽  
Mass Spectroscopy ◽  
Elemental Analysis ◽  
Electrochemical Behaviour ◽  
Absolute Ethanol ◽  
Molar Ratio ◽  
H Nmr ◽  
Chelating Ligand ◽  
Metal Ligand

4,4′-Diaminobiphenyl reacts with 2,4-pentanedione in absolute ethanol in a molar ratio 1 : 2 to form mainly the product of [1 + 2] condensation, 4,4′-(biphenyl-4,4′-diyldinitrilo)dipentan-2-one (H2L). The Schiff base was used as tetradentate chelating ligand to coordinate CoII and NiII chlorides leading to complexes where the ratio of metal ligand was found to be 2 : 1 or 2 : 2. All the synthesized products were characterized by elemental analysis, infrared, electronic, and mass spectroscopy, 1H NMR, and DSC. The electrochemical behaviour of the ligand and its complexes in DMF is also investigated.

scholarly journals Structure and photochromic properties of a novel diarylethene containing a 9-fluorenone hydrazone Schiff base moiety

2019 ◽  
Vol 44 (3-4) ◽  
pp. 137-141
Author(s):  
Yuexia Zhuge ◽  
Chunhong Zheng ◽  
Guanming Liao ◽  
Shouzhi Pu
Keyword(s):  
Schiff Base ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Fatigue Resistance ◽  
Crystalline Phase ◽  
Photochromic Properties ◽  
Single Crystal Diffraction ◽  
Fluorescence Modulation ◽  
High Fluorescence ◽  
Base Moiety

A novel diarylethene containing a 9-fluorenone hydrazone Schiff base moiety is designed and synthesized. The structure is characterized by single-crystal diffraction analysis and it shows excellent photochromism in the single crystalline phase. Moreover, the diarylethene product shows relatively high fluorescence modulation efficiency and good fatigue resistance.

scholarly journals pH Dependence of the Aggregation of a Bilayer Membrane Containing Schiff Base Moiety

1992 ◽  
Vol 8 (03) ◽  
pp. 304-306
Author(s):  
Wu Li-Xin ◽  
◽  
Tian Yong-Chi ◽  
Liang Ying-Qiu
Keyword(s):  
Schiff Base ◽  
Ph Dependence ◽  
Bilayer Membrane ◽  
Base Moiety

Synthesis and antitumor activities of novel hybrid molecules containing 1,3,4-oxadiazole and 1,3,4-thiadiazole bearing Schiff base moiety

2014 ◽  
Vol 24 (22) ◽  
pp. 5154-5156 ◽  
Author(s):  
Kai Zhang ◽  
Peng Wang ◽  
Li-Na Xuan ◽  
Xiao-Yun Fu ◽  
Fen Jing ◽  
...  
Keyword(s):  
Schiff Base ◽  
Antitumor Activities ◽  
Hybrid Molecules ◽  
Base Moiety
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