Direct electro-deposition of metallic chromium from K2CrO4 in the equimolar CaCl2-KCl molten salt and its reduction mechanism

2016 ◽  
Vol 212 ◽  
pp. 162-170 ◽  
Author(s):  
Wei Weng ◽  
Mingyong Wang ◽  
Xuzhong Gong ◽  
Zhi Wang ◽  
Dong Wang ◽  
...  
Keyword(s):  
Molten Salt ◽  
Reduction Mechanism ◽  
Electro Deposition ◽  
Metallic Chromium

scholarly journals Electrochemical Study on the Reduction Mechanism of Uranium Oxide in a LiCl-Li2O Molten Salt

2006 ◽  
Vol 43 (5) ◽  
pp. 587-595 ◽  
Author(s):  
Chung Seok SEO ◽  
Sung Bin PARK ◽  
Byung Heung PARK ◽  
Ki Jung JUNG ◽  
Seong Won PARK ◽  
...  
Keyword(s):  
Molten Salt ◽  
Uranium Oxide ◽  
Electrochemical Study ◽  
Reduction Mechanism

The Influence of Electro-Deposition Time to the Distribution of Silicon in Ferrosilicon Alloy

2013 ◽  
Vol 734-737 ◽  
pp. 1536-1539
Author(s):  
Jing Long Liang ◽  
Hui Li ◽  
Yun Gang Li
Keyword(s):  
Production Process ◽  
Molten Salt ◽  
Deposition Time ◽  
Magnetic Energy ◽  
Silicon Steel ◽  
Magnetic Alloy ◽  
Electro Deposition ◽  
Soft Magnetic Alloy ◽  
Deposit Surface ◽  
Traditional Production

As soft magnetic alloy, Si steel has been brought to the attention of the people. When the content of Si is about 6.5%, the magnetic induction intensity is highest, and the wastage of the iron is lowest, with good magnetic energy. Due to the brittleness and poor process-ability of the 6.5% Si silicon, the traditional production process is very difficult to be used for the production. With traditional production process, the content of Si in silicon steel is commonly 0.1% ~ 4.0%, which makes the property of the silicon steel limited. Use molten salt electro-position method to product silicon steel on the basis of silicon steel surface, to lay the foundation for producing 6.5% Si silicon steel. The influence of the process parameters of molten salt electro-position method to the deposit surface morphology and the silicon content distribution from surface to inside shows that along with the increase of the electro-position time, the size of sediment particle on the deposit surface gradually increases. The sedimentary thickness is proportional to the electro-deposition time.

Preparation of tungsten coatings on graphite by electro-deposition via Na 2 WO 4 –WO 3 molten salt system

2014 ◽  
Vol 89 (11) ◽  
pp. 2529-2533 ◽  
Author(s):  
Ning-bo Sun ◽  
Ying-chun Zhang ◽  
Fan Jiang ◽  
Shao-ting Lang ◽  
Min Xia
Keyword(s):  
Molten Salt ◽  
Salt System ◽  
Electro Deposition ◽  
Molten Salt System

scholarly journals The Electrochemical Mechanism of Preparing Mn from LiMn2O4 in Waste Batteries in Molten Salt

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1066
Author(s):  
Jinglong Liang ◽  
Rui Zhang ◽  
Hui Li ◽  
Le Wang ◽  
Zongying Cai ◽  
...  
Keyword(s):  
Molten Salt ◽  
Electrochemical Reduction ◽  
Deionized Water ◽  
Reduction Mechanism ◽  
Constant Voltage ◽  
Intermediate Products ◽  
Electrochemical Mechanism

The electrochemical reduction mechanism of Mn in LiMn2O4 in molten salt was studied. The results show that in the NaCl-CaCl2 molten salt, the process of reducing from Mn (IV) to manganese is: Mn (IV)→Mn (III)→Mn (II)→Mn. LiMn2O4 reacts with molten salt to form CaMn2O4 after being placed in molten salt for 1 h. The reaction of reducing CaMn2O4 to Mn is divided into two steps: Mn (III)→Mn (II)→Mn. The results of constant voltage deoxidation experiments under different conditions show that the intermediate products of LiMn2O4 reduction to Mn are CaMn2O4, MnO, and (MnO)x(CaO)(1−x). As the reaction progresses, x gradually decreases, and finally the Mn element is completely reduced under the conditions of 3 V for 9 h. The CaO in the product can be removed by washing the sample with deionized water at 0 °C.

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