Impact of annealing temperature on the microstructure, microhardness, tribological properties and corrosion resistance of Ni–Mo/diamond composites

2020 ◽  
pp. 148367
Author(s):  
J.H. Liu ◽  
J.X. Yan ◽  
Y.D. Liu ◽  
W.H. Li ◽  
W.S. Gu ◽  
...  
Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1194
Author(s):  
Philipp Kiryukhantsev-Korneev ◽  
Alina Sytchenko ◽  
Yuriy Kaplanskii ◽  
Alexander Sheveyko ◽  
Stepan Vorotilo ◽  
...  

The coatings ZrB2 and Zr-B-N were deposited by magnetron sputtering of ZrB2 target in Ar and Ar–15%N2 atmospheres. The structure and properties of the coatings were investigated via scanning and transmission electron microscopy, energy dispersion analysis, optical profilometry, glowing discharge optical emission spectroscopy and X-ray diffraction analysis. Mechanical and tribological properties of the coatings were investigated using nanoindentation, “pin-on-disc” tribological testing and “ball-on-plate” impact testing. Free corrosion potential and corrosion current density were measured by electrochemical testing in 1N H2SO4 and 3.5%NaCl solutions. The oxidation resistance of the coatings was investigated in the 600–800 °С temperature interval. The coatings deposited in Ar contained 4–11 nm grains of the h-ZrB2 phase along with free boron. Nitrogen-containing coatings consisted of finer crystals (1–4 nm) of h-ZrB2, separated by interlayers of amorphous a-BN. Both types of coatings featured hardness of 22–23 GPa; however, the introduction of nitrogen decreased the coating’s elastic modulus from 342 to 266 GPa and increased the elastic recovery from 62 to 72%, which enhanced the wear resistance of the coatings. N-doped coatings demonstrated a relatively low friction coefficient of 0.4 and a specific wear rate of ~1.3 × 10−6 mm3N−1m−1. Electrochemical investigations revealed that the introduction of nitrogen into the coatings resulted in the decrease of corrosion current density in 3.5% NaCl and 1N H2SO4 solution up to 3.5 and 5 times, correspondingly. The superior corrosion resistance of Zr-В-N coatings was related to the finer grains size and increased volume of the BN phase. The samples ZrB2 and Zr-B-N resisted oxidation at 600 °C. N-free coatings resisted oxidation (up to 800 °С) and the diffusion of metallic elements from the substrate better. In contrast, Zr-B-N coatings experienced total oxidation and formed loose oxide layers, which could be easily removed from the substrate.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Ihsan-ul-Haq Toor

The corrosion behavior of two specially designed austenitic stainless steels (SSs) having different Nickel (Ni) and Manganese (Mn) contents was investigated. Prior to electrochemical tests, SS alloys were solution-annealed at two different temperatures, that is, at 1030°C for 2 h and 1050°C for 0.5 h. Potentiodynamic polarization (PD) tests were carried out in chloride and acidic chloride, whereas linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) was performed in 0.5 M NaCl solution at room temperature. SEM/EDS investigations were carried out to study the microstructure and types of inclusions present in these alloys. Experimental results suggested that the alloy with highest Ni content and annealed at 1050°C/0.5 hr has the highest corrosion resistance.


Author(s):  
Prasanna Gadhari ◽  
Prasanta Sahoo

Electroless nickel composite coatings possess excellent mechanical and tribological properties such as, hardness, wear and corrosion resistance. Composite coatings can easily be coated not only on electrically conductive materials but also on non-conductive materials like as fabrics, plastics, rubber, etc. This review emphasizes on the development of electroless nickel composite coatings by incorporating different types of hard/soft particles (micro/nano size) in the electroless Ni-P matrix to improve the mechanical and tribological properties of the coatings. The preparation of electroless bath for nickel-phosphorus composite coating, methods to incorporate hard and/or soft particles in the bath, factors affecting the particle incorporation in the coating and its effect on coating structure, hardness, wear resistance, friction behavior, corrosion resistance, and mechanical properties are discussed thoroughly.


2021 ◽  
Vol 45 (1) ◽  
pp. 69-74
Author(s):  
Tassi Hocine ◽  
Zidelmel Sami ◽  
Allaoui Omar

In the present investigation, some electrochemical properties of dual phase X70 steels with different martensite morphologies which have undergone boriding were studied. To obtain a variety of martensite morphologies, Direct Quenching (DQ), Intermediate Quenching (IQ) and Step Quenching (SQ) heat treatments were applied at an intercritical annealing temperature (IAT) of 760℃. The treatment (DQ) allowed the formation of fine martensite evenly distributed in the ferrite matrix. (IQ) treatment showed the formation of martensite along the ferrite / ferrite grain boundaries. In contrast, treatment (SQ) induced the formation of a banded morphology of martensite and ferrite. The realization of borides on X70 (DP) steel was carried out in a powder mixture containing 5% of B4C as source of boron, 5% of NaBF4 as activator and 90% of SiC as diluent at 950℃ for a period of time from 4 h. The corrosion behavior of X70 (DP) steel has been explored by the Tafel extrapolation method in a 5 wt. % H2SO4 solution. The corrosion resistance of steel which has undergone boriding (BDP) is higher than that of steel which has not undergone it (DP).


2015 ◽  
Vol 278 ◽  
pp. 99-107 ◽  
Author(s):  
A. Castellanos ◽  
A. Altube ◽  
J.M. Vega ◽  
E. García-Lecina ◽  
J.A. Díez ◽  
...  

2017 ◽  
pp. 1303-1326
Author(s):  
Prasanna Gadhari ◽  
Prasanta Sahoo

Electroless nickel coatings are widely popular in various industrial sectors due to their excellent tribological properties. The present study considers optimization of coating parameters along with annealing temperature to improve microhardness and corrosion resistance of Ni-P-TiO2 composite coatings. Grey relational analysis is used to find out the optimal combination of coating parameters. From the analysis, it is confirmed that annealing temperature of the coating has the most significant effect and amount of titanium particles in the coating has some significant effect on corrosion properties of the coating. The same trend is observed in case of combined study of corrosion behavior and microhardness. The surface morphology, phase transformation and the chemical composition are examined using scanning electron microscopy, X-ray diffraction analysis and energy dispersive analysis respectively. The Ni-P-TiO2 composite coating revealed nodular structure with almost uniform distribution of titanium particles and it turns in to crystalline structure after heat treatment.


Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 294
Author(s):  
Shuang Liu ◽  
Chaohua Yue ◽  
Xi Chen ◽  
Qiuhua Zhu ◽  
Yiyou Tu

The pitting corrosion resistance of S32750 super duplex stainless steel, annealing treated at temperatures of 950–1200 °C for 20–60 min, was investigated using potentiodynamic polarization tests. The results show that the volume fractions of ferrite in the S32750 duplex stainless steel increased from 48.9% to 68.4% as annealing temperatures increased from 950 to 1200 °C. The pitting potential of the sample increased first and then decreased from an annealing temperature of 950 to 1050 °C, and the highest pitting potential was observed after annealing at 1050 °C for 35 min. The pitting corrosion resistance of S32750 stainless steel is due to the combination of pitting resistance equivalent number (PREN) value, phase fraction and grain boundary area fraction, and the imbalance of corrosion potential.


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