Time-dependent self-assembly of magnetic particles tethered branched block copolymer for potential biomedical application

2020 ◽  
Vol 527 ◽  
pp. 146649
Author(s):  
Pijush Mandal ◽  
Sovan Lal Banerjee ◽  
Somnath Maji ◽  
Sanjoy Kumar Ghorai ◽  
Tapas Kumar Maiti ◽  
...  
2017 ◽  
Vol 2017 ◽  
pp. 1-5
Author(s):  
Hiroaki Wakayama ◽  
Hirotaka Yonekura

Magnetic recording media are composed of magnetic thin films consisting of magnetically isolated crystallites. For practical use of magnetic particles as recording media, it will be necessary to realize high coercivity by fabricating nanocrystalline grains and forming grain boundaries with the nonmagnetic phase. In this study, a high-coercivity FePt–Ag nanocomposite magnet was synthesized by means of block copolymer-templated self-assembly. Precursors of Fe, Pt, and Ag were introduced into a polymer block, and the resulting material was oxidized and then reduced to form a nanocomposite consisting of FePt nanoparticles surrounded by a matrix of Ag. X-ray diffraction analysis revealed that the introduction of Ag did not significantly affect the crystalline ordering of the FePt. The addition of Ag increased the coercivity by 53% (from 11.1 to 17.0 kOe). Our results suggest that the grain boundaries of the nonmagnetic Ag metal acted as pinning sites, disrupting magnetic coupling between individual FePt nanocrystallites and hindering domain wall motion at an external magnetic field.


2005 ◽  
Vol 42 (3) ◽  
pp. 180-183 ◽  
Author(s):  
S. G. Schulz ◽  
U. Frieske ◽  
H. Kuhn ◽  
G. Schmid ◽  
F. Müller ◽  
...  

2021 ◽  
Vol 13 (4) ◽  
pp. 5772-5781
Author(s):  
Dong Hyup Kim ◽  
Ahram Suh ◽  
Geonhyeong Park ◽  
Dong Ki Yoon ◽  
So Youn Kim

2021 ◽  
Author(s):  
Yanfen Jiang ◽  
Shuqi Dong ◽  
Guoyang Qin ◽  
Li Liu ◽  
Hanying Zhao

Alkylation of thioether-containing block copolymer simultaneously incorporated sulfoniums and phenylboronic acid moieties. The co-assembly of this cationic polymer and protein generated micelles with an H2O2-and ATP-responsive release profile.


Langmuir ◽  
2020 ◽  
Vol 36 (36) ◽  
pp. 10803-10810
Author(s):  
Yun Li ◽  
Raymond Horia ◽  
Wei Xin Tan ◽  
Nathawat Larbaram ◽  
Wardhana A. Sasangka ◽  
...  

2021 ◽  
Author(s):  
Wei Wen ◽  
Wangqi Ouyang ◽  
Song Guan ◽  
Aihua Chen

A facile synthesis of non-spherical photoresponsive azobenzene-containing liquid crystalline nanoparticles via polymerization-induced hierarchical self-assembly (PIHSA).


2013 ◽  
Vol 705 ◽  
pp. 115-119
Author(s):  
Bao Yong Tian ◽  
Er Jun Tang ◽  
Miao Yuan ◽  
Rui Xia Hao ◽  
Cun Man Li ◽  
...  

The well-defined block copolymer PMMA-b-PS was prepared by two-step ATRP in emulsion system. GPC results indicate that Mn increased linearly with conversion and polydispersity remained relatively narrow. It presents the characteristics of living polymerization in emulsion system. FT-IR demonstrated that block copolymer PMMA-b-PS could be successfully synthesized by ATRP with macroinitiator PMMA-Cl in emulsion system. The morphological characteristic of the self-assembly depends on the block copolymer concentration and transforms between spheres and rodlike micelles. The property indicates a perfect potential application in drug delivery materials.


2021 ◽  
pp. 2100522
Author(s):  
Guillaume Moriceau ◽  
Cédric Kilchoer ◽  
Kenza Djeghdi ◽  
Christoph Weder ◽  
Ullrich Steiner ◽  
...  

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