Changes in the shapes of self-organized PbSe quantum dots during PbEuTe overgrowth investigated by anomalous X-ray diffraction

2006 ◽  
Vol 253 (1) ◽  
pp. 177-181 ◽  
Author(s):  
V. Holý ◽  
T.U. Schülli ◽  
R.T. Lechner ◽  
G. Springholz ◽  
G. Bauer
1997 ◽  
Vol 70 (8) ◽  
pp. 955-957 ◽  
Author(s):  
A. A. Darhuber ◽  
V. Holy ◽  
J. Stangl ◽  
G. Bauer ◽  
A. Krost ◽  
...  

1997 ◽  
Vol 36 (Part 1, No. 6B) ◽  
pp. 4084-4087 ◽  
Author(s):  
Anton A. Darhuber ◽  
Vaclav Holy ◽  
Julian Stangl ◽  
Günther Bauer ◽  
Alois Krost ◽  
...  

2001 ◽  
Vol 63 (3) ◽  
Author(s):  
I. Kegel ◽  
T. H. Metzger ◽  
A. Lorke ◽  
J. Peisl ◽  
J. Stangl ◽  
...  

1998 ◽  
Vol 41 (2) ◽  
pp. 172-176 ◽  
Author(s):  
Yutian Wang ◽  
Yan Zhuang ◽  
Wenquan Ma ◽  
Wei Wang ◽  
Xiaoping Yang ◽  
...  

1996 ◽  
Author(s):  
Yan Zhuang ◽  
Y.T. Wang ◽  
W.Q. Ma ◽  
W. Wang ◽  
X.P Yang ◽  
...  

2000 ◽  
Vol 618 ◽  
Author(s):  
V. Holý ◽  
J. Stangl ◽  
G. Springholz ◽  
M. Pinczolits ◽  
G. Bauer

ABSTRACTThe shape and the positions of self-organized PbSe quantum dots embedded in PbEuTe are studied by means of grazing-incidence small angle x-ray scattering and x-ray diffraction. Using a detailed numerical analysis of the measured x-ray data, we have determined a truncated pyramidal shape of the free-standing dots. The type of the lateral dot ordering depends substantially on the period of the PbSe/PbEuTe superlattice. In the case of smaller periods, the lateral ordering of the dots obeys a short-range order model and we have determined the statistical properties of the dot arrangement. For intermediate spacer thicknesses the dots form a hexagonal lattice. For larger periods, the dots are completely uncorrelated and their distribution can be described as a two-dimensional ideal gas. From coplanar x-ray diffraction we have determined additionally the vertical correlation of the dot positions changes from a mere vertical correlation for small superlattice periods, to a distorted trigonal lattice for the intermediate periods. For the largest period, no vertical correlation of dot positions is observed.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jason J. Calvin ◽  
Tierni M. Kaufman ◽  
Adam B. Sedlak ◽  
Michelle F. Crook ◽  
A. Paul Alivisatos

AbstractPowder X-ray diffraction is one of the key techniques used to characterize the inorganic structure of colloidal nanocrystals. The comparatively low scattering factor of nuclei of the organic capping ligands and their propensity to be disordered has led investigators to typically consider them effectively invisible to this technique. In this report, we demonstrate that a commonly observed powder X-ray diffraction peak around $$q=1.4{\AA}^{-1}$$ q = 1.4 Å − 1 observed in many small, colloidal quantum dots can be assigned to well-ordered aliphatic ligands bound to and capping the nanocrystals. This conclusion differs from a variety of explanations ascribed by previous sources, the majority of which propose an excess of organic material. Additionally, we demonstrate that the observed ligand peak is a sensitive probe of ligand shell ordering. Changes as a function of ligand length, geometry, and temperature can all be readily observed by X-ray diffraction and manipulated to achieve desired outcomes for the final colloidal system.


1998 ◽  
Vol 58 (12) ◽  
pp. 7934-7943 ◽  
Author(s):  
V. Holý ◽  
A. A. Darhuber ◽  
J. Stangl ◽  
S. Zerlauth ◽  
F. Schäffler ◽  
...  

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