Combustion synthesis of Ni3Al and Ni3Al-matrix composites

1992 ◽  
Vol 23 (1) ◽  
pp. 69-76 ◽  
Author(s):  
J. P. Lebrat ◽  
A. Varma ◽  
A. E. Miller
2015 ◽  
Vol 68 ◽  
pp. 283-288 ◽  
Author(s):  
Heguo Zhu ◽  
Bo Hua ◽  
Tao Cui ◽  
Jiewen Huang ◽  
Jianliang Li ◽  
...  

1994 ◽  
Vol 350 ◽  
Author(s):  
C. R. Kachelmyer ◽  
A. Varma

AbstractCombustion synthesis of NbAl3-matrix composites with Al2O3 and B additions was studied using the thermal explosion mode. The addition of B to the reaction mixture resulted in the formation of NbB2, small amounts of NbB and unreacted Al. The Al2O3 addition did not affect the NbAl3-matrix reaction completion but the final product density increased with increasing Al2O3 loading. In both NbAl3-matrix composites, the reaction was initiated above the melting point of Al.


2007 ◽  
Vol 19 (5-6) ◽  
pp. 85-89 ◽  
Author(s):  
Roberto Orrù ◽  
Roberta Licheri ◽  
Antonio Mario Locci ◽  
Giacomo Cao ◽  
Jimmy De Wilde ◽  
...  

2001 ◽  
Vol 16 (6) ◽  
pp. 1614-1625 ◽  
Author(s):  
Cheryl Lau ◽  
Alexander Mukasyan ◽  
Aleksey Pelekh ◽  
Arvind Varma

Combustion synthesis (CS) of NiAl-based materials reinforced by TiB2 particles was investigated under both terrestrial and microgravity conditions. The synthesized metal matrix composites (MMC) are characterized by very fine (<1 μm) reinforced particulates, which have strong bonding along their entire surface with matrix (NiAl) and are distributed uniformly in it. It was found that microgravity leads to a decrease in the average TiB2 particle size, while higher volume fraction of NiAl component in the material leads to the formation of coarser reinforced particulates. The mechanism of structure formation of different MMCs during CS was identified by using the quenching technique. For example, it was shown that TiB2 grains appear due to crystallization from the complex (Ni–Al–Ti–B) liquid solution formed in the combustion front. An overall decrease of microstructural transformation rates was observed under microgravity.


2003 ◽  
Vol 800 ◽  
Author(s):  
Douglas E. Burkes ◽  
Guglielmo Gottoli ◽  
John J. Moore ◽  
Hu Chun Yi ◽  
Reed A. Ayers

ABSTRACTCombustion synthesis, or Self-propagating High- temperature Synthesis (SHS), is currently being used by the Center for Commercial Applications of Combustion in Space (CCACS) at the Colorado School of Mines to produce advanced porous materials for several important applications. These materials include ceramic, inter- metallic, and metal- matrix composites that can be used for orthopedic implants, heat exchanger and damping systems and micro-and macro-filter applications. Functionally graded materials, both in porosity and composition, can be produced using a range of combustion synthesis reactions systems. There are multiple factors that contribute to the final SHS product, e.g. reactant stoichiometry, initial relative density and pre-heat. The synthesis of nickel-titanium (NiTi) intermetallic compounds and composites is of considerable interest due to the ability to create a porous, shape memory and super-elastic alloy with high corrosion resistance. The synthesis effects of adding a carbon reactant so as to modify the reaction products and reaction exothermicity have been studied through the use of two different reaction stoichiometries involving elemental nickel, titanium and carbon. This paper outlines the synthesis of NiTi intermetallic composites based on the following SHS chemical reaction:The effect of the carbon reactant and the initial sample green density on the apparent porosity, bulk density, pore size and pore distribution of the final materials has been studied and is presented within this paper. A NiTi- TiC intermetallic ceramic composite has been synthesized that is functionally graded in both composition and porosity: the latter grading being due to buoyancy and gas evolution effects. Proposed kinetic mechanisms that drive this synthesis process and control the graded structure are discussed in detail.


1996 ◽  
Vol 34 (2) ◽  
pp. 175-181 ◽  
Author(s):  
A.O. Kunrath ◽  
T.R. Strohaecker ◽  
J.J. Moore

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