Combustion Synthesis of NiTi – TiC Composites with Controlled Porosity for Biomedical Applications

2003 ◽  
Vol 800 ◽  
Author(s):  
Douglas E. Burkes ◽  
Guglielmo Gottoli ◽  
John J. Moore ◽  
Hu Chun Yi ◽  
Reed A. Ayers
Keyword(s):  
Combustion Synthesis ◽  
Orthopedic Implants ◽  
Functionally Graded ◽  
Nickel Titanium ◽  
Synthesis Process ◽  
Matrix Composites ◽  
Reaction Products ◽  
High Temperature Synthesis ◽  
Commercial Applications ◽  
Image Position

ABSTRACTCombustion synthesis, or Self-propagating High- temperature Synthesis (SHS), is currently being used by the Center for Commercial Applications of Combustion in Space (CCACS) at the Colorado School of Mines to produce advanced porous materials for several important applications. These materials include ceramic, inter- metallic, and metal- matrix composites that can be used for orthopedic implants, heat exchanger and damping systems and micro-and macro-filter applications. Functionally graded materials, both in porosity and composition, can be produced using a range of combustion synthesis reactions systems. There are multiple factors that contribute to the final SHS product, e.g. reactant stoichiometry, initial relative density and pre-heat. The synthesis of nickel-titanium (NiTi) intermetallic compounds and composites is of considerable interest due to the ability to create a porous, shape memory and super-elastic alloy with high corrosion resistance. The synthesis effects of adding a carbon reactant so as to modify the reaction products and reaction exothermicity have been studied through the use of two different reaction stoichiometries involving elemental nickel, titanium and carbon. This paper outlines the synthesis of NiTi intermetallic composites based on the following SHS chemical reaction:The effect of the carbon reactant and the initial sample green density on the apparent porosity, bulk density, pore size and pore distribution of the final materials has been studied and is presented within this paper. A NiTi- TiC intermetallic ceramic composite has been synthesized that is functionally graded in both composition and porosity: the latter grading being due to buoyancy and gas evolution effects. Proposed kinetic mechanisms that drive this synthesis process and control the graded structure are discussed in detail.

scholarly journals Carbon Nanotube Sheet-Synthesis and Applications

Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 2023
Author(s):  
Megha Chitranshi ◽  
Anuptha Pujari ◽  
Vianessa Ng ◽  
Daniel Chen ◽  
Devika Chauhan ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Large Scale ◽  
Hydrogen Gas ◽  
Synthesis Process ◽  
Temperature Synthesis ◽  
High Temperature Synthesis ◽  
Metal Ceramic ◽  
Commercial Applications ◽  
Manufacturing Problems

Decades of extensive research have matured the development of carbon nanotubes (CNTs). Still, the properties of macroscale assemblages, such as sheets of carbon nanotubes, are not good enough to satisfy many applications. This paper gives an overview of different approaches to synthesize CNTs and then focuses on the floating catalyst method to form CNT sheets. A method is also described in this paper to modify the properties of macroscale carbon nanotube sheets produced by the floating catalyst method. The CNT sheet is modified to form a carbon nanotube hybrid (CNTH) sheet by incorporating metal, ceramic, or other types of nanoparticles into the high-temperature synthesis process to improve and customize the properties of the traditional nanotube sheet. This paper also discusses manufacturing obstacles and the possible commercial applications of the CNT sheet and CNTH sheet. Manufacturing problems include the difficulty of injecting dry nanoparticles uniformly, increasing the output of the process to reduce cost, and safely handling the hydrogen gas generated in the process. Applications for CNT sheet include air and water filtering, energy storage applications, and compositing CNTH sheets to produce apparel with anti-microbial properties to protect the population from infectious diseases. The paper also provides an outlook towards large scale commercialization of CNT material.

FGM Fabrication by Combustion Synthesis

MRS Bulletin ◽  
1995 ◽  
Vol 20 (1) ◽  
pp. 52-53 ◽  
Author(s):  
Gregory C. Stangle ◽  
Yoshinari Miyamoto
Keyword(s):  
High Temperature ◽  
Combustion Synthesis ◽  
Volume Fraction ◽  
Synthesis Process ◽  
Composition Gradient ◽  
Synthesis Methods ◽  
High Temperature Synthesis ◽  
Exothermic Chemical Reaction ◽  
Reactant Powder ◽  
Refractory Ceramics

FGMs have been fabricated using the combustion synthesis (or self-propagating high-temperature synthesis (SHS)) process by exploiting a rapid and exothermic chemical reaction, in order to synthesize some (or all) of the constituents in an FGM to simultaneously increase its density. The thermal energy required to drive the process is derived from this internal, chemical source, rather than from an external and usually expensive source (e.g., a furnace). The combustion synthesis process is a powder-based process that has been used to synthesize over 300 compounds, and is particularly useful in preparing materials such as highly refractory ceramics and high-temperature intermetallics that are difficult to prepare by other synthesis methods. In addition, the process can be used to prepare ceramic-metal and ceramic-intermetallic composite materials. As a result, only slight modifications of the combustion synthesis are required to prepare functionally gradient materials from these same combinations of materials.Sample preparation begins by the creation of a series of mixtures from the powders that will react to form the constituent materials of the FGM sample. Each of these mixtures contains a slightly different percentage of reactants, so that each mixture will yield its own (predetermined) volume fraction of each of its constituents, following the combustion synthesis process. Prior to the combustion step, the samples are assembled by stacking layers of each of the reactant powder mixtures in appropriate amounts, in such a way that the multilayered powder mixture will faithfully produce the composition gradient that is required in the resultant FGM.

Functionally Graded TiC-Based Cermets via Combustion Synthesis and Quasi-Isostatic Pressing

2005 ◽  
Vol 492-493 ◽  
pp. 63-68 ◽  
Author(s):  
M. Martinez Pacheco ◽  
Marianne Stuivinga ◽  
Eric Carton ◽  
Laurens Katgerman
Keyword(s):  
Combustion Synthesis ◽  
Functionally Graded ◽  
X Ray Diffraction ◽  
Temperature Synthesis ◽  
Powder Mixtures ◽  
X Ray ◽  
High Temperature Synthesis ◽  
Graded Material ◽  
Granulate Medium ◽  
Scanning Electron

Experimental results on the preparation of functionally graded TiC-based cermets obtained by combustion synthesis (also known as Self-Propagating High-Temperature Synthesis, SHS) followed by quasi-isostatic (QIP) pressing in a granulate medium are presented. Pellets of TiC-Fe graded cermets are produced by stacking layers of Ti and C powder mixtures in which the content of a NiFe alloy (50 wt% Ni and 50 wt% Fe) is varied from 5 up to 25 vol %. X-ray diffraction showed that the NiFe alloy did not react with the TiC, thus preserving its special properties. Scanning electron microscopy results show a graded material with pores increasing in size towards the side with the highest ceramic fraction.

scholarly journals Combustion synthesis of metal carbides: Part I. Model development

2005 ◽  
Vol 20 (5) ◽  
pp. 1257-1268 ◽  
Author(s):  
A.M. Locci ◽  
A. Cincotti ◽  
F. Delogu ◽  
R. Orrù ◽  
G. Cao
Keyword(s):  
Mathematical Model ◽  
Combustion Synthesis ◽  
Model Development ◽  
Pure Metal ◽  
Metal Carbides ◽  
Reaction Products ◽  
High Temperature Synthesis ◽  
Suitable Combination ◽  
Definition Of ◽  
Population Balances

The definition of a rigorous theoretical framework for the appropriate physico-chemical description of self-propagating high-temperature synthesis (SHS) processes represents the main goal of this work which is presented in two sequential articles. In this article, a novel mathematical model to simulate SHS processes is proposed. By adopting a heterogeneous approach for the description of mass transfer phenomena, the model is based on appropriate mass and energy conservation equations for each phase present during the system evolution. In particular, it takes microstructural evolution into account using suitable population balances and properly evaluating the differentdriving forces from the relevant phase diagram. The occurrence of phase transitionsis treated on the basis of the so-called enthalpy approach, while a conventional nucleation-and-growth mechanistic scenario is adopted to describe quantitatively the formation of reaction products. The proposed mathematical model may be applied to the case of combustion synthesis processes involving a low melting point reactant and a refractory one, as for the synthesis of transition metal carbides from pure metal and graphite. Thus, the model can be profitably used to gain a deeper insight into the microscopic elementary phenomena involved in combustion synthesis processes through a suitable combination of experimental and modeling investigations, as it may be seen in Part II of this work [J. Mater. Res. 20, 1269 (2005)].

Mechanistic studies in combustion synthesis of Ni3Al and Ni3Al-matrix composites

1994 ◽  
Vol 9 (5) ◽  
pp. 1184-1192 ◽  
Author(s):  
Jean-Pascal Lebrat ◽  
Arvind Varma ◽  
Paul J. McGinn
Keyword(s):  
Combustion Synthesis ◽  
Heat Sinks ◽  
Matrix Composites ◽  
Matrix Synthesis ◽  
High Temperature Synthesis ◽  
The Matrix ◽  
Sic Whiskers ◽  
Mixture Prior ◽  
Al Matrix Composites ◽  
Al Matrix

Nickel aluminides exhibit limited ductility and toughness at room temperature. One way to improve these characteristics is by adding ceramic reinforcements to the matrix. In this paper, we have studied the combustion synthesis of Ni3Al and Ni3Al-matrix composites, using the self-propagating high-temperature synthesis (SHS) mode. First, studies of the Ni3Al synthesis were carried out by quenching the reaction during its progress, which revealed the mechanism of the synthesis. The influence of Al2O3 and SiC whiskers or particulates, and B4C particulates added to the reaction mixture prior to combustion synthesis, was investigated next. It was found that, in general, reinforcements are heat sinks and limit the propagation of the reaction. Also, whiskers impede the flow of formed liquid to a larger extent than do particulates. Al2O3 is inert and matrices reinforced with up to 2 wt. % Al2O3 are composed essentially of Ni3Al grains. However, both B4C and SiC react with the Ni-Al matrix and lead to complex phases. In particular, B4C readily forms a Ni-Al-B liquid phase and disrupts dramatically the progress of the Ni3Al matrix synthesis.

The mechanism and kinetics of the niobium-carbon reaction under self-propagating high-temperature synthesis-like conditions

1995 ◽  
Vol 10 (11) ◽  
pp. 2829-2841 ◽  
Author(s):  
Cheng He ◽  
Gregory C. Stangle
Keyword(s):  
High Temperature ◽  
Combustion Synthesis ◽  
Niobium Carbide ◽  
Solid Material ◽  
Temperature History ◽  
Synthesis Process ◽  
Temperature Synthesis ◽  
High Temperature Synthesis ◽  
Mechanism And Kinetics ◽  
Kinetics Of

The mechanism and kinetics of the chemical reaction between Nb(s) and C(s) under self-propagating high-temperature synthesis (SHS)-like (or combustion synthesis-like) conditions have been studied. Experiments were designed and conducted in order to produce a transport-resistance-free reaction between Nb and C under time-temperature conditions that are characteristic of the combustion synthesis process. To do so, a reaction couple, consisting of carbon and either a thin niobium foil or a fine niobium wire, was used. The effects of the temperature history and the formation of a liquid phase on the reaction were studied. In addition, theoretical experiments of the reaction were also conducted. The results showed that at high temperatures, layered niobium carbide phases formed in a direction that was parallel to the original carbon-niobium interface. As might be expected, local melting played a very significant role in the reactions. The mechanism and kinetics of these reactions provide a fundamental understanding of the manner and rate by which a powder-based Nb/C SHS process takes place, and, by extension, to a large, general class of solid-solid material synthesis processes that are based on the SHS (or combustion synthesis) process.

scholarly journals High-Temperature Synthesis of Metal–Matrix Composites (Ni-Ti)-TiB2

2021 ◽  
Vol 11 (5) ◽  
pp. 2426
Author(s):  
Vladimir Promakhov ◽  
Alexey Matveev ◽  
Nikita Schulz ◽  
Mikhail Grigoriev ◽  
Andrey Olisov ◽  
...  
Keyword(s):  
High Temperature ◽  
Composite Materials ◽  
Metal Matrix Composite ◽  
Matrix Composite ◽  
Metal Matrix ◽  
Average Particle Size ◽  
Synthesis Process ◽  
Average Particle ◽  
Temperature Synthesis ◽  
High Temperature Synthesis

Currently, metal–matrix composite materials are some of the most promising types of materials, and they combine the advantages of a metal matrix and reinforcing particles/fibres. Within the framework of this article, the high-temperature synthesis of metal–matrix composite materials based on the (Ni-Ti)-TiB2 system was studied. The selected approaches make it possible to obtain composite materials of various compositions without contamination and with a high degree of energy efficiency during production processes. Combustion processes in the samples of a 63.5 wt.% NiB + 36.5 wt.% Ti mixture and the phase composition and structure of the synthesis products were researched. It has been established that the synthesis process in the samples proceeds via the spin combustion mechanism. It has been shown that self-propagating high-temperature synthesis (SHS) powder particles have a composite structure and consist of a Ni-Ti matrix and TiB2 reinforcement inclusions that are uniformly distributed inside it. The inclusion size lies in the range between 0.1 and 4 µm, and the average particle size is 0.57 µm. The obtained metal-matrix composite materials can be used in additive manufacturing technologies as ligatures for heat-resistant alloys, as well as for the synthesis of composites using traditional methods of powder metallurgy.

A Convenient Method for Preparing Well-Dispersed Er2Zr2O7 Nanocrystals

2010 ◽  
Vol 123-125 ◽  
pp. 611-614 ◽  
Author(s):  
Yu Ping Tong ◽  
Rui Zhu Zhang ◽  
Shun Bo Zhao ◽  
Chang Yong Li
Keyword(s):  
Particle Size ◽  
Combustion Synthesis ◽  
Crystal Size ◽  
Lattice Distortion ◽  
Combustion Method ◽  
Treatment Temperature ◽  
Synthesis Process ◽  
Thermal Treatment Temperature ◽  
Average Size ◽  
Xrd And Tem

Well-dispersed fluorite Er2Zr2O7 nanocrystals have been successfully prepared by a convenient salt-assistant combustion method. The effects of calcinations temperature and salt category on the characteristics of the products were investigated by XRD and TEM. The thermal treatment temperature has an important effect on crystal size and lattice distortion of the nanocrystals. The experiment showed that the introduction of salt in the combustion synthesis process resulted in the formation of well-dispersed Er2Zr2O7 nanocrystals. The average size was 30 nm and was in agreement with the XRD result, which indicated that the nanocrystals were uniform in particle size distribution. Moreover, the possible formation process in the salt-assisted combustion synthesis was also analyzed.

Shape memory alloy based NiTi reinforced functionally graded material for vibration damping

2021 ◽  
pp. 146442072110355
Author(s):  
Namrata Gangil ◽  
Arshad Noor Siddiquee ◽  
Sameera Mufazzal ◽  
SM Muzakkir ◽  
Sachin Maheshwari
Keyword(s):  
Titanium Alloy ◽  
Shape Memory ◽  
Functionally Graded Material ◽  
Friction Stir Processing ◽  
Vibration Damping ◽  
Functionally Graded ◽  
Nickel Titanium ◽  
Friction Stir ◽  
Alloy Particles ◽  
Graded Material

Shape memory based high performance nickel-titanium alloy particles were embedded by friction stir processing in graded concentration on the surface of light weight commercially pure magnesium cast plates. The novel functionally graded material so developed was analyzed for microhardness evolution and vibration damping effect. The nickel-titanium alloy particles were filled in a 2.5 wide × 3 mm deep slot and embedded on the surface by friction stir processing. A shallower slot 2.5 wide × 1.5 mm deep was milled over the previously embedded surface in which nickel-titanium alloy powder was again filled and embedded on the surface by second pass friction stir processing. This sequence of pass created the graded variation in nickel-titanium alloy concentration. The so fabricated functionally graded material was cut out from the plate and it was hot-forged to 2/3 thickness and subsequently quenched. The microstructural examination confirmed homogeneous dispersion of nickel-titanium alloy particles and clear interface between high and low concentration regions. The microhardness confirmed a uniform graded variation in hardness. The vibration damping tests confirm considerable improvement in the damping capacity of the fabricated functionally graded material.

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