Solid state intermetallic compound growth between copper and high temperature, tin-rich solders—part II: Modeling

1994 ◽  
Vol 23 (8) ◽  
pp. 729-734 ◽  
Author(s):  
K. L. Erickson ◽  
P. L. Hopkins ◽  
P.T Vianco
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Intermetallic Compound ◽  
Intermetallic Compound Growth

Microstructural evolution and interfacial reactions of fluxless-bonded Au-20Sn/Cu solder joint during reflow and aging

2007 ◽  
Vol 22 (10) ◽  
pp. 2817-2824 ◽  
Author(s):  
Jeong-Won Yoon ◽  
Hyun-Suk Chun ◽  
Hoo-Jeong Lee ◽  
Seung-Boo Jung
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Intermetallic Compound ◽  
Solder Joint ◽  
Microstructural Evolution ◽  
Surface Finish ◽  
Solder Matrix ◽  
Interfacial Reactions ◽  
Cu Substrate ◽  
Study Results

The microstructural evolution and interfacial reactions of fluxless-bonded, Au-20wt%Sn/Cu solder joint were investigated during reflow and aging. After reflowing at 310 °C, only one thick and irregularly shaped ζ(Cu) layer was formed at the interface. After the prolonged reflow reaction, the AuCu layer was formed between the ζ(Cu) layer and the Cu substrate. During reflowing, the Cu substrate reacted primarily with the ζ-phase in the solder matrix. The solid-state interfacial reaction was much faster at 250 °C than at 150 °C. After aging at 250 °C for 100 h, thick ζ(Cu), AuCu and AuCu3 IMC layers were formed at the interface. The formation of the AuCu3 intermetallic compound (IMC) was caused by Cu enrichment at the AuCu/Cu layer interface. After aging for 500 h, cracks were observed inside the interfacial AuCu layer. The study results clearly demonstrate the need for an alternative surface finish on Cu, to ensure the high temperature reliability of the Au-20Sn/Cu solder joint.

Solid-state reaction of niobium with diamond carbon at high pressure and high temperature to form superconducting composite

2021 ◽  
Vol 31 (3) ◽  
pp. 415-418
Author(s):  
Vladimir Yu. Osipov ◽  
Fedor M. Shakhov ◽  
Nikolai M. Romanov ◽  
Kazuyuki Takai
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Solid State ◽  
Solid State Reaction

A safeguarding and high temperature tolerant organogel electrolyte for flexible solid-state supercapacitors

2021 ◽  
Vol 505 ◽  
pp. 230083
Author(s):  
Yuxuan Wu ◽  
Sheng Wang ◽  
Min Sang ◽  
Quan Shu ◽  
Junshuo Zhang ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

Photoluminescence Properties of Ca3Si2O7: Pr3+ Orange-Red Phosphors Prepared by High-Temperature Solid-State Method

2018 ◽  
Vol 73 (6) ◽  
pp. 555-558 ◽  
Author(s):  
Zhi-Qing Peng ◽  
Rong Chen ◽  
Wen-Lin Feng
Keyword(s):  
Crystal Structure ◽  
High Temperature ◽  
Solid State ◽  
Solid State Method ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Red Phosphors ◽  
Typical Sample ◽  
State Method ◽  
Xrd Patterns

AbstractNovel luminescent materials Ca3-xSi2O7: xPr3+ were successfully prepared by the high-temperature solid-state method. The crystal structure, morphology, and optical spectrum were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and spectroscopy, respectively. The XRD patterns of the samples indicate that the crystal structure is monoclinic symmetry. The SEM shows that the selected sample has good crystallinity although its appearance is irregular and scalelike. The peak of the excitation spectrum of the sample is located at around 449 nm, corresponding to 3H4→3P2 transition of Pr3+. The peak of the emission spectrum of the sample is situated at around 612 nm which is attributed to 3P0→3H6 transition of Pr3+, and the colour is orange-red. The optimum concentration for Pr3+ replaced Ca2+ sites in Ca3Si2O7: Pr3+ is 0.75 mol%. The lifetime (8.48 μs) of a typical sample (Ca2.9925Pr0.0075)Si2O7 is obtained. It reveals that orange-red phosphors Ca3-xSi2O7: xPr3+ possess remarkable optical properties and can be used in white light emitting devices.

scholarly journals Solid-state microcellular high temperature vulcanized (HTV) silicone rubber foam with carbon dioxide

2017 ◽  
Vol 134 (20) ◽  
Author(s):  
Qian Yang ◽  
Haitao Yu ◽  
Lixian Song ◽  
Yajie Lei ◽  
Fengshun Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Temperature ◽  
Solid State ◽  
Silicone Rubber

Research on High Temperature Anti-Abrasion Protection Technology of Thermocouple Cannula

2007 ◽  
Vol 353-358 ◽  
pp. 1765-1768
Author(s):  
Hong Fei Sun ◽  
Can Ming Wang ◽  
Qiang Song ◽  
Qiong Qiong Yan
Keyword(s):  
High Temperature ◽  
Intermetallic Compound ◽  
Service Life ◽  
New Technologies ◽  
Work Conditions ◽  
Protection Method ◽  
Metal Ceramic ◽  
Protection Technology ◽  
Compound Coating ◽  
Ceramic Compound

Abrasion mechanism of thermocouple cannula is studied in this article. For different working position and condition, different material should be selected to ensure the working characteristics of thermocouple cannula. Several protection methods were introduced to prolong the sevice life of thermocouple cannula. 1. M-Al series intermetallic compound coating protection method. 2. Metal/ceramic compound coating protection method. 3. Development of new abrasion-resisting material for high temperature according to some special work conditions of thermocouple cannula. With the adoption of those new technologies, thermocouple cannula’s service life can be prolonged to 3~5 times of that untreated.

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