Synthesis of silica-bound complexing agents containing 2,3-dihydroxybenzoyl and 3,4,5-trihydroxybenzoylamide functional groups and analytical studies of metal uptake

1984 ◽  
Vol 319 (4) ◽  
pp. 403-409 ◽  
Author(s):  
T. Seshadri ◽  
G. Dietz ◽  
H. -J. Haupt
2001 ◽  
Vol 17 (6) ◽  
pp. 793-795 ◽  
Author(s):  
Tohru SAITOH ◽  
Nobuhiko NAKAGAKI ◽  
Yoko UCHIDA ◽  
Masataka HIRAIDE ◽  
Chiyo MATSUBARA

2006 ◽  
Vol 153 (7) ◽  
pp. G650 ◽  
Author(s):  
Udaya B. Patri ◽  
Serdar Aksu ◽  
S. V. Babu

Friction ◽  
2020 ◽  
Author(s):  
Hanqiang Wu ◽  
Liang Jiang ◽  
Xia Zhong ◽  
Jinwei Liu ◽  
Na Qin ◽  
...  

AbstractEthylenediamine with two −NH2 functional groups was used as a critical complexing agent in chemical mechanical polishing (CMP) slurries for a high carbon chromium GCr15 bearing steel (equivalent to AISI 52100). The polishing performance and corresponding mechanism of −NH2 functional groups were thoroughly investigated as a function of pH. It is revealed that, when polished with ethylenediamine and H2O2-based slurries, the material removal rate (MRR) and surface roughness Ra of GCr15 steel gradually decrease as pH increases. Compared with acidic pH of 4.0, at alkaline pH of 10.0, the surface film of GCr15 steel has much higher corrosion resistance and wear resistance, and thus the material removal caused by the pure corrosion and corrosion-enhanced wear are greatly inhibited, resulting in much lower MRR and Ra. Moreover, it is confirmed that a more protective composite film, consisting of more Fe3+ hydroxides/oxyhydroxides and complex compounds with −NH2 functional groups of ethylenediamine, can be formed at pH of 10.0. Additionally, the polishing performance of pure iron and a medium carbon 45 steel exhibits a similar trend as GCr15 steel. The findings suggest that acidic pH could be feasible for amine groups-based complexing agents to achieve efficient CMP of iron-based metals.


2008 ◽  
Vol 86 (10) ◽  
pp. 958-969 ◽  
Author(s):  
Dorota Kołodyńska ◽  
Zbigniew Hubicki

This paper investigates the macroporous chelating ion exchangers with different functional groups for their sorption properties towards the copper(II) and zinc(II) ions. The investigations by the dynamic and static methods were carried out in the presence of traditional complexing agents. The differences in affinity of Cu(II) and Zn(II) complexes with these complexones result from the kind of functional groups of the chelating ion exchangers, such as thiourea, aminomethylphosphonate, iminodiacetate, and polyamine groups as well as from the pH value. The quantitative removal of studied heavy metal complexes using chelating ion exchangers is achieved in the case when resins compete successfully for the heavy metal ions against these chelators.Key words: chelating resins, heavy metals, EDTA, NTA.


2019 ◽  
Vol 25 (38) ◽  
pp. 55-63
Author(s):  
Yung Jun Kim ◽  
Jae Han Bae ◽  
Jae Jeong Kim

1995 ◽  
Vol 51 (1-2) ◽  
pp. 207-213 ◽  
Author(s):  
G. Zaray ◽  
D.D.T. Phuong ◽  
I. Varga ◽  
A. Varga ◽  
T. Kantor ◽  
...  

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