Synthesis, Crystal Structure, and Catalytic Properties of Porous 3d-4f Heterometallic Coordination Polymers Constructed from Pyrazine-2,3-dicarboxylic Acid

2017 ◽  
Vol 643 (22) ◽  
pp. 1801-1808 ◽  
Author(s):  
Ting-Hai Yang ◽  
Ana Rosa Silva ◽  
Lianshe Fu ◽  
Fa-Nian Shi
CrystEngComm ◽  
2015 ◽  
Vol 17 (20) ◽  
pp. 3852-3858 ◽  
Author(s):  
Ting-Hai Yang ◽  
Ana Rosa Silva ◽  
Fa-Nian Shi

Four porous CoIIILnIII 3d–4f heterometallic coordination polymers constructed by the pydcH2 ligand were hydrothermally synthesized and characterized. The adsorption and catalytic properties of compound CoIIIDyIII were investigated.


2015 ◽  
Vol 44 (30) ◽  
pp. 13745-13751 ◽  
Author(s):  
Ting-Hai Yang ◽  
Ana Rosa Silva ◽  
Lianshe Fu ◽  
Fa-Nian Shi

Four FeLn heterometallic coordination polymers with the H4pmida ligand were ionothermally synthesized and characterized. Their catalytic properties in the Knöevenagel condensation reaction were investigated.


RSC Advances ◽  
2015 ◽  
Vol 5 (22) ◽  
pp. 17343-17353 ◽  
Author(s):  
Yang Song ◽  
Rui-Qing Fan ◽  
Hui-Jie Zhang ◽  
Zhi-Wei Liu ◽  
Xue-Tao Wang ◽  
...  

Preparation, characterization, crystal structure and different luminescent properties of Ag(i)/Cu(i) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material.


Author(s):  
Xianyu Huang ◽  
Daoliang Chen ◽  
Mingrui He ◽  
Jianfeng Li ◽  
Jiawei Huang ◽  
...  

Four novel coordination polymers (CPs) assembled with [2,2′-bifuran]-5,5′-dicarboxylic acid (H2L) and metal ions ZnII, CdIIor CoIIhave been successfully synthesized. Their molecular structures have been determined to be Zn(L)(H2O)2(1), [Zn(L)(DMF)]2(2), [Cd(L)(EtOH)(DMF)2]2(3) and Co(L)(H2O)4·(H2O)2(4) by crystallographic analysis. It is found that (2) exhibits a two-dimensional infinite framework, whereas the others exhibit a one-dimensional framework. Both (2) and (3) exhibit ligand-based emission which is blue-shifted compared with the emission from the H2Lligand. Time-resolved spectroscopic measurement reveals that the complexes exhibit a similar lifetime with that of the ligand, which confirms that the emission of the complexes originates from the ligand.


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