Highly Selective Synthesis of Polyalkylated Naphthalenes Catalyzed by Ionic Liquids and Their Tribological Properties as Lubricant Base Oil

2019 ◽  
Vol 4 (18) ◽  
pp. 5284-5290
Author(s):  
Lei Li ◽  
Xinrui Zhao ◽  
Chen Chen ◽  
Hong Xu ◽  
Lei Liu ◽  
...  
2015 ◽  
Vol 58 (4) ◽  
pp. 686-690 ◽  
Author(s):  
Xiangyu Ge ◽  
Yanqiu Xia ◽  
Zongying Shu

2020 ◽  
Vol 72 (7) ◽  
pp. 851-856
Author(s):  
Zhengfeng Cao ◽  
Yanqiu Xia ◽  
Chuan Chen ◽  
Kai Zheng ◽  
Yi Zhang

Purpose This paper aims to explore polyaniline (PANI) as a lubricant additive to improve the anti-corrosion and tribological properties of ionic liquids (ILs) for actual applications. Design/methodology/approach ILs were synthesized by dissolving lithium salts in synthetic oil and were used as a base oil to prepare ILs-based greases. PANI was used as an additive. The tribological properties were investigated in detail and the anti-corrosion ability was also assessed via salt spray test. After friction test, the worn surfaces were characterized by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy to analyze the lubrication mechanisms. Findings PANI not only reduces the corrosion but also improves the friction reduction and anti-wear abilities of the ILs-based greases. The analysis indicates that the protective films generated on the worn surfaces were responsible for the preferable anti-corrosion and tribological properties. Originality/value This paper provides an effective approach to improve the anti-corrosion and tribological properties of ILs for actual applications. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2019-0469/


RSC Advances ◽  
2017 ◽  
Vol 7 (8) ◽  
pp. 4312-4319 ◽  
Author(s):  
Maoquan Xue ◽  
Zhiping Wang ◽  
Feng Yuan ◽  
Xianghua Zhang ◽  
Wei Wei ◽  
...  

TiO2/Ti3C2Tx hybrid nanocomposites were successfully prepared by a liquid phase synthesis technology. The hybrid nanocomposites improve the tribological properties of base oil by mending the surface and formation a uniform tribofilm on the surface.


Author(s):  
Aswani K Singh ◽  
Varun Sharma

During machining, the cutting fluids play an essential role in cooling and lubrication. In order to reduce the friction forces, the excessive amount of the cutting fluids are generally used. This, in turn, leads to wastage of the cutting fluids which results in a serious impact on the environment, health and cost of production. Therefore, the judicious use of lubricants is the foremost concern in the manufacturing industry. In order to mitigate these drawbacks, various alternatives have been developed in the last decade. In the present paper, ionic liquids have been proved as favourable sustainable alternative additives in the base oil. The effect of alkyl chain length of ionic liquids with base oil on the thermo-physical and tribological characteristics of cutting fluids including viscosity, wettability, anticorrosion behaviour, thermal stability, and coefficient of friction have been analysed. In the present study, pyrrolidinium and hexafluoro-phosphate (PF6) have been used as cation and anion, respectively, with rice bran oil as base oil. The five different ionic liquids have been dispersed in base oil by 1.0 wt%. It has been found that longer alkyl chain length showed the favourable results as compared to the shorter one. Results indicated that ionic liquid based cutting fluid attained ample enhanced thermophysical and tribological properties as compared to the neat rice bran oil. There has been 5.08% and 4.29% improvement in viscosity and thermal conductivity for IL4 + RBO in comparison to neat RBO. In addition, the wettability, coefficient of friction, and wear volume have been reduced by 20.34%, 53.79% and 57.87% correspondingly.


2016 ◽  
Vol 721 ◽  
pp. 451-455
Author(s):  
Armands Leitans ◽  
Eriks Palcevskis

In work investigated effects of zirconium oxide (ZrO2), spinel (MgAl2O4) and mullite (Al6Si2O13) nanosized powders on the base oil tribological properties. The nanosized (30-40nm) powders manufactured by plasma chemical synthesis method. Tribological experiments used on ball-on-disc type tribometer, measured coefficient of friction and determined metalic disc wear. Base oil used selectively purified mineral oil (conform SAE-20 viscosity) without any functional additives. Nanosized powders dispersed in base oil at 0.5; 1.0; 2.0; wt.%. At work cocluded, that the adition nanoparticles in base oil, possible reduced friction pair wear and friction coefficient. As the main results include spinel (MgAl2O4) nanoparticles 0.5 and 1.0 wt. % concentration ability reduced friction coeffiecient value.


2009 ◽  
Vol 11 (9) ◽  
pp. 1391 ◽  
Author(s):  
Eric J. Amigues ◽  
Christopher Hardacre ◽  
Gillian Keane ◽  
Marie E. Migaud ◽  
Sarah E. Norman ◽  
...  

2008 ◽  
Vol 130 (3) ◽  
Author(s):  
Wang Li-jun ◽  
Guo Chu-wen ◽  
Ryuichiro Yamane

The synthesis and application of nanometer-sized particles have received considerable attention in recent years because of their different physical and chemical properties from those of the bulk materials or individual molecules; however, few experimental investigations on the tribological properties of lubricating oils with and without nanoferromagnetic particles have been performed. This work investigates the tribological properties of Mn0.78Zn0.22Fe2O4 nanoferromagnetic as additive in 46# turbine oil using a four-ball friction and wear tester. It is shown that the 46# turbine oil containing Mn0.78Zn0.22Fe2O4 nanoparticles has much better friction reduction and antiwear abilities than the base oil. The 46# turbine oil doped with 6wt%Mn0.78Zn0.22Fe2O4 nanoparticles show the best tribological properties among the tested oil samples, and PB value is increased by 26%, and the decreasing percentage of wear scar diameter is 25.45% compared to base oil.


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