A computational study of ion speciation in mixtures of protic ionic liquids with various molecular solvents: Insight into the solvent polarity and anion basicity

2016 ◽  
Vol 117 (3) ◽  
pp. 170-179 ◽  
Author(s):  
Jiayao Huang ◽  
Aiping Fu ◽  
Hongliang Li ◽  
Hao Li ◽  
Tianshu Chu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Computational Study ◽  
Solvent Polarity ◽  
Protic Ionic Liquids ◽  
Molecular Solvents ◽  
Insight Into

Equilibrium of Contact and Solvent-Separated Ion Pairs in Mixtures of Protic Ionic Liquids and Molecular Solvents Controlled by Polarity

2013 ◽  
Vol 52 (47) ◽  
pp. 12439-12442 ◽  
Author(s):  
Koichi Fumino ◽  
Peter Stange ◽  
Verlaine Fossog ◽  
Rolf Hempelmann ◽  
Ralf Ludwig
Keyword(s):  
Ionic Liquids ◽  
Ion Pairs ◽  
Protic Ionic Liquids ◽  
Molecular Solvents

Solvent-mediated molar conductivity of protic ionic liquids

2015 ◽  
Vol 17 (1) ◽  
pp. 475-482 ◽  
Author(s):  
Sachin Thawarkar ◽  
Nageshwar D. Khupse ◽  
Anil Kumar
Keyword(s):  
Ionic Liquids ◽  
Molar Conductivity ◽  
Protic Ionic Liquids ◽  
Molecular Solvents

The molar conductivity, Λm, of protic ionic liquids (PILs) in molecular solvents is measured at 298.15 K.

Pressure-induced mesoscopic disorder in protic ionic liquids: first computational study

2016 ◽  
Vol 18 (4) ◽  
pp. 2297-2302 ◽  
Author(s):  
A. Mariani ◽  
R. Caminiti ◽  
M. Campetella ◽  
L. Gontrani
Keyword(s):  
High Pressure ◽  
Ionic Liquids ◽  
Computational Study ◽  
Protic Ionic Liquids ◽  
Alkyl Chains

The application of high pressure to protic ionic liquids with short alkyl chains induces a progressive homogenization of the structure.

Ion Pairing in Protic Ionic Liquids Probed by Far-Infrared Spectroscopy: Effects of Solvent Polarity and Temperature

ChemPhysChem ◽  
2014 ◽  
Vol 15 (12) ◽  
pp. 2604-2609 ◽  
Author(s):  
Koichi Fumino ◽  
Verlaine Fossog ◽  
Peter Stange ◽  
Kai Wittler ◽  
Wigbert Polet ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Infrared Spectroscopy ◽  
Solvent Polarity ◽  
Far Infrared ◽  
Ion Pairing ◽  
Far Infrared Spectroscopy ◽  
Protic Ionic Liquids

Utilization of the dye N-methyl-6-oxyquinolone as an optical acidometer in molecular solvents and protic ionic liquids

2017 ◽  
Vol 53 (78) ◽  
pp. 10761-10764 ◽  
Author(s):  
Stella Schmode ◽  
Ralf Ludwig
Keyword(s):  
Ionic Liquids ◽  
Protic Ionic Liquids ◽  
Highly Sensitive ◽  
Molecular Solvents

We developed a procedure to use the highly sensitive dyeN-methyl-6-oxyquinolone as an acidity probe in molecular solvents and protic ionic liquids.

1,8-Diazabicyclo[5.4.0]-undec-7-ene based protic ionic liquids and their binary systems with molecular solvents catalyzed Michael addition reaction

2020 ◽  
Vol 44 (32) ◽  
pp. 13701-13706
Author(s):  
Gulshan Ara ◽  
Muhammed Shah Miran ◽  
Md. Mominul Islam ◽  
M. Yousuf A. Mollah ◽  
M. Muhibur Rahman ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Ionic Liquids ◽  
Michael Addition ◽  
Binary Systems ◽  
Addition Reaction ◽  
Michael Addition Reaction ◽  
Protic Ionic Liquids ◽  
Molecular Solvents

Michael addition reaction of acetylacetone and cyclohexenone has been studied using 1,8-diazabicyclo[5.4.0]-undec-7-ene (DBU) based protic ionic liquids and their binary systems with DBU, water and acetic acid as catalysts.

Solvation properties of protic ionic liquids and molecular solvents

2020 ◽  
Vol 22 (1) ◽  
pp. 114-128 ◽  
Author(s):  
Dilek Yalcin ◽  
Calum J. Drummond ◽  
Tamar L. Greaves
Keyword(s):  
Ionic Liquids ◽  
Protic Ionic Liquids ◽  
Potential Applications ◽  
Molecular Solvents

Ionic liquids (ILs) are highly tailorable solvents with many potential applications. Knowledge about their solvation properties is highly beneficial in the utilization of ILs for specific tasks, though for many ILs this is currently unknown.

scholarly journals Micelle formation of a non-ionic surfactant in non-aqueous molecular solvents and protic ionic liquids (PILs)

2016 ◽  
Vol 18 (35) ◽  
pp. 24377-24386 ◽  
Author(s):  
Emmy C. Wijaya ◽  
Frances Separovic ◽  
Calum J. Drummond ◽  
Tamar L. Greaves
Keyword(s):  
Free Energy ◽  
Ionic Liquids ◽  
Energy Density ◽  
Micelle Formation ◽  
Ionic Surfactant ◽  
Protic Ionic Liquids ◽  
Diverse Range ◽  
Cohesive Energy Density ◽  
Free Energy Of Micellization ◽  
Molecular Solvents

Micelle formation of a non-ionic amphiphile, C12E6, was investigated in a diverse range of molecular solvents and protic ionic liquids (PILs). A link between the solvent cohesive energy density and the free energy of micellization was discussed.

Solvation of Al3+ cations in bulk and confined protic ionic liquids: a computational study

2018 ◽  
Vol 20 (28) ◽  
pp. 19071-19081 ◽  
Author(s):  
Víctor Gómez-González ◽  
Borja Docampo-Álvarez ◽  
Hadrián Montes-Campos ◽  
Juan Carlos Otero ◽  
Elena López Lago ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Computational Study ◽  
Protic Ionic Liquids ◽  
Nitrate Anions

Nanostructured solvation of Al3+ in an EAN ionic liquid, forming octahedral complexes with nitrate anions.

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