Synthesis of graft copolymers onto styrenic polymer backbone via “grafting from” raft process

2012 ◽  
Vol 50 (22) ◽  
pp. 4772-4782 ◽  
Author(s):  
Prakash Babu Rajendran ◽  
Dhamodharan Raghavachari
Keyword(s):  
Graft Copolymers ◽  
Polymer Backbone ◽  
Styrenic Polymer ◽  
Grafting From

Graft copolymers containing poly(3-hydroxyalkanoates) — A review on their synthesis, properties, and applications

2008 ◽  
Vol 86 (6) ◽  
pp. 570-578 ◽  
Author(s):  
Sophie Nguyen
Keyword(s):  
Graft Copolymer ◽  
Main Chain ◽  
Graft Copolymers ◽  
Preparation Methods ◽  
Synthesis Properties ◽  
Grafting Through ◽  
Grafting From ◽  
Grafting Onto

The use of the poly(3-hydroxyalkanoates) in copolymer synthesis has received much interest, as the microbial polyester segments can bring interesting properties, such as biodegradability and biocompatibility. The synthesis, properties, and applications of graft copolymers containing poly(3-hydroxyalkanoates) as main chain or branches are reviewed here, with emphasis on the different preparation methods, which fit into the three main synthesis strategies of graft copolymers: “grafting onto”, “grafting from”, and “grafting through” or macromonomer methods.Key words: poly(3-hydroxyalkanoates), graft copolymer, synthesis, properties, applications.

PHEA-g-PDMAEA well-defined graft copolymers: SET-LRP synthesis, self-catalyzed hydrolysis, and quaternization

2016 ◽  
Vol 7 (45) ◽  
pp. 6973-6979 ◽  
Author(s):  
Fangxu Sun ◽  
Chun Feng ◽  
Haoyu Liu ◽  
Xiaoyu Huang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Grafting From

This article reports the synthesis of well-defined graft copolymers containing a PHEA backbone and degradable PDMAEA side chains, by the combination of RAFT polymerization, SET-LRP, and the grafting-from strategy.

Synthesis and Characterization of Thermoresponsive Graft Copolymers of NIPAAm and 2-Alkyl-2-oxazolines by the “Grafting from” Method

2005 ◽  
Vol 38 (17) ◽  
pp. 7330-7336 ◽  
Author(s):  
Juan Rueda ◽  
Stefan Zschoche ◽  
Hartmut Komber ◽  
Dirk Schmaljohann ◽  
Brigitte Voit
Keyword(s):  
Graft Copolymers ◽  
Synthesis And Characterization ◽  
Grafting From

scholarly journals First double hydrophilic graft copolymer bearing a poly(2-hydroxylethyl acrylate) backbone synthesized by sequential RAFT polymerization and SET-LRP

2016 ◽  
Vol 7 (18) ◽  
pp. 3156-3164 ◽  
Author(s):  
Yinan Cui ◽  
Xiuyu Jiang ◽  
Chun Feng ◽  
Guangxin Gu ◽  
Jie Xu ◽  
...  
Keyword(s):  
Graft Copolymer ◽  
Raft Polymerization ◽  
Graft Copolymers ◽  
Grafting From

This article reports the first synthesis of well-defined double hydrophilic graft copolymers with a PHEA backbone, by the combination of RAFT polymerization, SET-LRP, and a grafting-from strategy.

Synthesis of degradable poly(ε-caprolactone)-based graft copolymers via a “grafting-from” approach

2016 ◽  
Vol 7 (46) ◽  
pp. 7126-7134 ◽  
Author(s):  
Panagiotis Bexis ◽  
Anthony W. Thomas ◽  
Craig A. Bell ◽  
Andrew P. Dove
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Grafting From

The controlled ring-opening polymerisation (ROP) of α-bromo-ε-caprolactone (αBrCL), a derivative of ε-caprolactone (εCL), and its copolymerisation with εCL is reported.

Graft Copolymers with Polyamide Backbones via Combination of Passerini Multicomponent Polymerization and Controlled Chain-growth Polymerization

2014 ◽  
Vol 67 (4) ◽  
pp. 555 ◽  
Author(s):  
Xin-Xing Deng ◽  
Yang Cui ◽  
Yao-Zong Wang ◽  
Fu-Sheng Du ◽  
Zi-Chen Li
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Graft Copolymers ◽  
Chain Growth ◽  
Hydroxyl Groups ◽  
Side Chains ◽  
Atom Transfer ◽  
Polymer Backbone ◽  
Vinyl Polymer

We report a facile ‘grafting from’ approach to graft copolymers with polyamide backbones and controlled vinyl polymer or polyester side chains. Two polyamides with in situ-formed pendant bromide or hydroxyl groups were obtained by Passerini-based multicomponent polymerization. They were used respectively to initiate the atom-transfer radical polymerization of vinyl monomers or the ring-opening polymerization of lactones to generate two new types of graft copolymers. One of the important features of the method is that the pendant initiators are generated in situ from non-branching monomers, and they are linked to the polymer backbone by ester bonds. Therefore, the vinyl polymer side chains could be detached from the backbones, and their structures could thus be fully characterized. Moreover, multicomponent polymerization and atom-transfer radical polymerization can even be carried out in a one-pot manner.

Grafting‐from Afforded Cyclic Graft Copolymers from Cyclic Anionic Macroinitiator via Lithiation of Tolyl Groups

2019 ◽  
pp. 1900224
Author(s):  
Kaoru Adachi ◽  
Takayuki Kono ◽  
Suguru Nakano ◽  
Yusuke Hamaguchi ◽  
Yasuhisa Tsukahara
Keyword(s):  
Graft Copolymers ◽  
Grafting From

Synthesis of novel types of graft copolymers by a “grafting-from” method using ring-opening polymerization of lactones and lactides

2003 ◽  
Vol 57 (2-3) ◽  
pp. 137-146 ◽  
Author(s):  
Miroslav Janata ◽  
Bohumil Masař ◽  
Luděk Toman ◽  
Petr Vlček ◽  
Petra Látalová ◽  
...  
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Ring Opening Polymerization ◽  
Grafting From
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